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Nitrogen ligands

Nitrogen (N), 17 270-289. See also N2 oxidation N-donating ligands Nitrogen compounds Nitrogen fixation Titanium-nitrogen compounds... [Pg.625]

The geometry about a ligand nitrogen coordinated to a metal ion is assumed to be planar with bond directions defined in Fig. 28. The hybridizations of the nitrogen orbitals for different angles between the bonds in the plane can be written as ... [Pg.56]

Osmium-mediated c/5-addition of nitrogen and oxygen to olefins. Regioselectiv-ity may be controlled by ligand. Nitrogen sources (X-NClNa) include ... [Pg.531]

Complexes of stoichiometry ZnLX2 (X = N02 or N03) have been isolated from the reaction of zinc nitrite or nitrate with 1,2-dimorpholinoethane and 1,2-dipiperidinoethane.647 The complexes contain zinc in a distorted octahedron of two ligand nitrogens and two bidentate O-bonded nitrite or nitrate anions. The nitrite complexes show greater stability than the... [Pg.962]

Fig. 25. Interactions of the 3dyz (3dxz) atomic orbital of the heme iron with the ji-orbitals of the ligand nitrogen atoms. The arrows indicate likely pathways for electron spin delocalization from the iron to the ligands... Fig. 25. Interactions of the 3dyz (3dxz) atomic orbital of the heme iron with the ji-orbitals of the ligand nitrogen atoms. The arrows indicate likely pathways for electron spin delocalization from the iron to the ligands...
The photostability of Os(II) bipyridyl complexes with covalently attached hydro quinone was investigated by Keyes and coworkers. In the complex [Os(bpy)2(bbhq)]+ (Scheme 1) the Os(II) center is coordinated to one ligand nitrogen and one of the oxygens of the central hydro quinone. The complex has an Os to bpy MLCT absorption with a maximum of 493 nm, but is non-luminescent. Photolysis in acetonitrile in the presence of excess Cl" did not yield any measurable photodegradation [32]. [Pg.109]

The simultaneous formation of 8 and 9 results in a situation in which all copper(I) ions are tetracoordinate and all of the ligands nitrogen atoms are bound to copper centers. Any other structures formed from this mixture of subcomponents would either contain more than one metal center (entropically disfavored) or have unsatisfied valences at either metal or ligand (enthalpically disfavored). [Pg.13]

Using the results obtained for complexes II, III, and V, the sequence of reactions occurring in deoxygenated aqueous-methanol solutions was proposed (for simplicity, only one ligand nitrogen atom is given) ... [Pg.358]

Another interesting result is that the EPR line widths show marked anisotropy we interpret this to mean that these widths result from unresolved hyperfine interactions between the unpaired electron and the ligand nitrogen atoms. Details of the nature of this dipolar interaction must await further, more elaborate analysis. [Pg.96]

Average values as well as lower and upper limits of M. .. N distances (M being alkali metal, N ligand nitrogen atom) in each structure, are given in Table 1. There is a linear relation between the observed average distances and the ionic radius of the cation (Fig. 1). [Pg.156]


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See also in sourсe #XX -- [ Pg.637 ]

See also in sourсe #XX -- [ Pg.227 , Pg.229 ]




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Actinide complexes nitrogen ligands

Alkyne complexes nitrogen donor ligands

Anionic nitrogen ligands

Antimony complexes nitrogen ligands

Aromatic nitrogen ligands

Aromatic nitrogen ligands with metal

Aromatic nitrogenous ligands

Aromatic nitrogenous ligands phenanthroline

Arsenic complexes nitrogen ligands

Atom transfer radical addition nitrogen based ligands

Bidentate nitrogen ligands

Bidentates nitrogen-oxygen ligands

Bidentates nitrogen-sulfur ligands

Bidentates selenium-nitrogen ligands

Catenated Nitrogen Ligands Part

Catenated Nitrogen Ligands Part David S. Moore and Stephen D. Robinson

Catenated Nitrogen Ligands Part Hexazine

Catenated Nitrogen Ligands Part Transition Metal Derivatives

Catenated Nitrogen Ligands Part Triazenes, Tetrazenes

Chelating nitrogen ligands

Chiral ligands nitrogen-containing

Chloride compounds nitrogen ligands

Clusters nitrogen ligands

Complexes containing nitrogen ligands

Complexes with Nitrogen Ligands

Complexes with nitrogen-coordinating ligands

Copper complexes nitrogen ligands

Cumulative Subject nitrogen donor ligands

Dioxygen nitrogen donor ligands

Dithiocarbamate complexes nitrogen-based ligands

Dithiolato complexes nitrogen ligands

Divalent nitrogen ligands

Gold complexes anionic nitrogen donor ligands

Gold complexes nitrogen donor ligands

Gold(lll) Complexes with Nitrogen and Oxygen Ligands

Hafnium complexes nitrogen ligands

Heterocyclic ligands, nitrogen

Heterocyclic nitrogen donor ligands

Hydridocobalt Complexes with Nitrogen Ligands

Indium complexes nitrogen ligands

Inversion nitrogen ligands

Iridium complexes nitrogen ligands

Iron complexes nitrogen ligands

Iron complexes with nitrogen ligands

Iron(II) complexes with nitrogen ligands

Isocyanide ligands with metal-nitrogen bonds

Lanthanide complexes nitrogen donor ligands

Ligands nitrogen compounds

Ligands nitrogen donor

Ligands nitrogen-based

Ligands saturated nitrogen

Ligands with Three-nitrogen Donor Sets

Macrocyclic nitrogen ligands

Manganese complexes nitrogen ligands

Mercury complexes nitrogen ligands

Mercury(l) with Nitrogen-Donor Ligands

Metals nitrogen donor ligands

Mixed nitrogen-oxygen ligands

Mixed nitrogen-sulfur ligands

Molecular nitrogen ligands

Molybdenum complexes nitrogen donor ligands

Molybdenum complexes nitrogen ligands

Multi-nitrogen-based ligand

Neutral nitrogen donor ligands

Niobium nitrogen donor ligands

Niobium nitrogen ligands

Nitrogen Schiff base ligands

Nitrogen and Oxygen Donor Ligands

Nitrogen as ligand

Nitrogen based ligands for

Nitrogen based ligands, copper

Nitrogen based ligands, copper addition

Nitrogen complexes metal-ligand multiple bonds

Nitrogen compounds amino alcohol ligands

Nitrogen compounds donor ligands

Nitrogen compounds imine-based ligands

Nitrogen donor ligands compounds containing

Nitrogen donor ligands containing

Nitrogen ligand complexes

Nitrogen ligands palladium complexes

Nitrogen ligands prochiral

Nitrogen ligands technetium complexes

Nitrogen ligands, catenated

Nitrogen ligands, transition metal

Nitrogen ligands, transition metal characterization

Nitrogen ligands, transition metal dithiocarbamate complexes

Nitrogen oxide ligands

Nitrogen-Based Delocalized and Heterocyclic Ligands

Nitrogen-Coordinating Ligands

Nitrogen-bound Ligands

Nitrogen-carbon ligands

Nitrogen-containing ligands

Nitrogen-containing ligands azide

Nitrogen-containing ligands catalysts

Nitrogen-containing ligands nitriles

Nitrogen-containing ligands pyridines

Nitrogen-containing ligands pyrroles

Nitrogen-containing phosphine ligands

Nitrogen-oxygen ligands

Nitrogen-oxygen ligands bidentate

Nitrogen-rich ligands

Nitrogen-sulfur ligands

Nitrogen-sulfur-containing ligands

Organochromium Complexes with Nitrogen-Containing Ligands for Ethylene Polymerization

Osmium nitrogen donor ligands

Other nitrogen donor ligands

Palladium and Chelating Nitrogen Ligands

Phosphines nitrogen donor ligands

Phosphines phosphorus-nitrogen ligands

Phosphorus-nitrogen donor ligands

Phosphorus-palladium complexes, nitrogen ligands

Platinum carrier-bound complexes, nitrogen donor ligands

Platinum complexes aromatic nitrogen ligands

Poly dentate Nitrogen Donor Ligands

Polydentate nitrogen donor ligands

Polydentate nitrogen ligands

Polymeric nitrogen donor ligands

Polymeric oxygen/nitrogen donor ligands

Preparation of RMgX, where X is an oxygen, nitrogen or sulfur ligand

Rhenium complexes with nitrogen ligands

Ruthenium complexes nitrogen donor ligands

Ruthenium complexes nitrogen ligands

Ruthenium complexes nitrogen-sulfur ligands

Ruthenium complexes with nitrogen ligands

Ruthenium nitrogen donor ligands

Separation nitrogen donor ligands

Silver nitrogen ligands

Subject nitrogen donor ligands

Technetium Schiff base and other nitrogen ligands

Technetium nitrogen ligands

Tertiary phosphine ligands with nitrogen-containing substituents

Tetrapodal pentadentate nitrogen ligands

Thallium complexes nitrogen ligands

Titanium complexes nitrogen ligands

Tridentate nitrogen ligands

Tungsten , halocarbonyl complexes nitrogen donor ligands

Xenon complexes nitrogen ligands

Zirconium complexes nitrogen ligands

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