Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Thallium complexes nitrogen ligands

Cyanamides are pseudo-halide nitrogen ligands that are readily coordinated to metals. A novel compound is 2-cyanaminofluoren-9-one (HL4)24. Its thallium salt T1+(L4)-(Scheme 7) is useful as a transmetallating agent in a reaction with trimethyltin chloride to produce the corresponding tin cyanamide complex [SnMe3L4] (Scheme 8). [Pg.474]

Complex supramolecular architectures have been established for dimethyl-thallium(III) derivatives of polyfunctional nitrogen ligands, e.g. the cyanide, the azide, the cyanate, the thiocyanate [177], the dicyanamide, and the tricyanomethide [178], The cyanide, Me2TlCN, 53, contains layers of nearly coplanar CN groups... [Pg.224]

A tris(imidazolyl)borate (138) complex of thallium(I) has been synthesized.The solid-state structure of hydrotris(imidazolyl)boratothallium(I) consists of one-dimensional, twisted, ladderlike strands, and three-coordinate thallium centers. Due to the position of the nitrogen donors, the tris(imidazolyl)borate ligand is not capable of forming metal chelates as are observed in tris(pyrazolyl)borates. Poly(benzotriazolyl)borate ligands have some features of both tris(pyrazo-lyl)borate and tris(imidazolyl)borate systems. Thallium(I) complexes of bis-, tris-, and tetrakis (benzotriazolyl)borates are reported. These adducts have been synthesized by treating the corresponding potassium derivative with an equimolar quantity of thallium(I) formate. ... [Pg.444]

See other pages where Thallium complexes nitrogen ligands is mentioned: [Pg.232]    [Pg.433]    [Pg.435]    [Pg.444]    [Pg.5306]    [Pg.468]    [Pg.218]    [Pg.60]    [Pg.394]    [Pg.395]    [Pg.290]    [Pg.66]    [Pg.468]    [Pg.205]    [Pg.209]    [Pg.216]    [Pg.216]    [Pg.250]    [Pg.250]    [Pg.250]    [Pg.251]    [Pg.111]    [Pg.168]    [Pg.174]    [Pg.528]    [Pg.126]    [Pg.417]    [Pg.426]    [Pg.427]    [Pg.442]    [Pg.489]    [Pg.29]    [Pg.229]    [Pg.210]    [Pg.751]    [Pg.268]    [Pg.543]    [Pg.1950]    [Pg.2007]    [Pg.2013]    [Pg.129]    [Pg.665]    [Pg.225]    [Pg.219]   
See also in sourсe #XX -- [ Pg.168 ]

See also in sourсe #XX -- [ Pg.3 , Pg.168 ]



SEARCH



Complexes thallium

Ligands nitrogen

Nitrogen complexes

Nitrogen ligand complexes

© 2024 chempedia.info