Dithiocarbamate complexes nitrogen-based ligands

Transition metal atoms coordinated by dithiocarbamate ligands through four sulfur atoms have both electronic (free d-orbitals) and steric (free octahedral sites) propensity to form adducts with nitrogen bases, since nitrogen atoms have one sp -hybrid orbital, which is occupied by the lone pair of stereochem-ically active electrons. To characterize newly prepared adducts of dimethyl-, diethyl- and morpholinedithiocarbamate zinc(II) complexes with cyclic N-donor bases, such as pyridine, piperidine, hexamethyleneimine and morpholine, compounds 28-35 have been prepared and studied by and CP/MAS... 

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