Lead-copper

Gobalt occurs in the minerals cobaltite, smaltite, and erythrite, and is often associated with nickel, silver, lead, copper, and iron ores, from which it is most frequently obtained as a by-product. It is also present in meteorites. 

The most important ores are bismuthinite or bismuth glance and bismite. Peru, Japan, Mexico, Bolivia, and Canada are major bismuth producers. Much of the bismuth produced in the U.S. is obtained as a by-product in refining lead, copper, tin, silver, and gold ores. 

Lead-copper alloys Lead corrosion Lead crystal Lead cyanide... 

Lead copper litharge (contains high bismuth)... 

Wrought lead—calcium—tin alloys contain more tin, have higher mechanical strength, exhibit greater stabiUty, and are more creep resistant than the cast alloys. RoUed lead—calcium—tin alloy strip is used to produce automotive battery grids in a continuous process (13). Table 5 Hsts the mechanical properties of roUed lead—calcium—tin alloys, compared with lead—copper and roUed lead—antimony (6 wt %) alloys. 

The lead—copper phase diagram (1) is shown in Figure 9. Copper is an alloying element as well as an impurity in lead. The lead—copper system has a eutectic point at 0.06% copper and 326°C. In lead refining, the copper content can thus be reduced to about 0.08% merely by cooling. Further refining requites chemical treatment. The solubiUty of copper in lead decreases to about 0.005% at 0°C. 

Only lead alloys containing copper below 0.08% have practical appHcations. Lead sheet, pipe, cable sheathing, wine, and fabricated products are produced from lead—copper alloys having copper contents near the eutectic composition. Lead—copper alloys in the range 0.03—0.08 wt % copper are covered by many specifications ASTM B29-92 (7), QQL 171 (United States), BS 334, HP2 Type 11 (Canada), DIN 1719 (Germany), and AS 1812 (Austraha). 

Lead—copper alloys are specified because of superior mechanical properties, creep resistance, corrosion resistance, and high temperature stabiUty compared to pure lead. The mechanical properties of lead—copper alloys are compared to pure lead, and to lead—antimony and lead—calcium alloys in Tables 4 and 5. 

Lead—copper alloys are the primary material used in the continuous extmsion of cable coverings for the electrical power cable industry in the United States. Other alloys, containing tin and arsenic as well as copper, have also been developed for cable sheathing in the United States to provide higher fatigue strength. 

Extmded or roUed lead—copper alloys contain a uniform dispersion of copper particles in a lead matrix. Because the soHd solubiUty of copper in lead is very low, copper particles in the matrix remain stable up to near the melting point of lead, maintaining uniform grain size even at elevated temperature. 

Lead—copper alloys are also used as tank linings, tubes for acid mist precipitators, steam heating pipes for sulfuric acid or chromate plating baths, and flashing and sheeting (see Tanks AND pressure vessels). 

The most important body of primary silver ore in the United States in the 1990s is located in Silver Valley, the Coeur d Alene Mining District of Shoshone County, Idaho, which produces >200 t/yr of silver. The main ore mineral is tetrahedrite [12054-35-2] associated with sulfides of lead, copper, iron, and 2inc. 

Solvent for Electrolytic Reactions. Dimethyl sulfoxide has been widely used as a solvent for polarographic studies and a more negative cathode potential can be used in it than in water. In DMSO, cations can be successfully reduced to metals that react with water. Thus, the following metals have been electrodeposited from their salts in DMSO cerium, actinides, iron, nickel, cobalt, and manganese as amorphous deposits zinc, cadmium, tin, and bismuth as crystalline deposits and chromium, silver, lead, copper, and titanium (96—103). Generally, no metal less noble than zinc can be deposited from DMSO. 

Hazards of Production. In most zinc mines, zinc is present as the sulfide and coexists with other minerals, especiaHy lead, copper, and cadmium. Therefore, the escape of zinc from mines and mills is accompanied by these other often more toxic materials. Mining and concentrating, usuaHy by flotations, does not present any unusual hazards to personnel. Atmospheric poHution is of Httle consequence at mine sites, but considerable effort is required to flocculate and settle fine ore particles, which would find their way into receiving waters. 

Montana. These deposits consist of stibnite and other sulfide minerals containing base metals and silver or gold. Ores of the complex deposits are mined primarily for lead, copper, 2inc, or precious metals antimony is a by-product of the treatment of these ores. 

The metal salts of neodecanoic acid have found wide usage as driers for paints and inks (95,96). Metal neodecanoates that are used include silver (80), cobalt (82), and zirconium (79), along with lead, copper, manganese, and 2inc (see Driers and metallic soaps). 

Table 2. Leading Copper-Producing Mines in the United States in 1989 ...

Viburnum Vo. 28 Fletcher Iron, Mo. The Doe Run Co. lead—copper ore, concentrated ... 

Many investigations are reported on azides of barium, calcium, strontium, lead, copper, and silver in the range 100 to 200°C (212 to 392°F). Time exponents were 6 to 8 and activation energies of 30 to 50 kcal/g mol (54,000 to 90,000 Btu/lb mol) or so. Some difficulties with reproducibility were encountered with these hazardous materials. 

When using soft metals such as lead, copper and their alloys, avoid sudden changes in the flow direction, such as sharp bends. 

Analyses (%) Chemical Lead Acid Lead Copper Lead... 

The most efficient processes in Table I are for steel and alumintim, mainly because these metals are produced in large amounts, and much technological development has been lavished on them. Magnesium and titanium require chloride intermediates, decreasing their efficiencies of production lead, copper, and nickel require extra processing to remove unwanted impurities. Sulfide ores produce sulfur dioxide (SO2), a pollutant, which must be removed from smokestack gases. For example, in copper production the removal of SO, and its conversion to sulfuric acid adds up to 8(10) JA g of additional process energy consumption. In aluminum production disposal of waste ciyolite must be controlled because of possible fiuoride contamination. 

Heavy metals the total of chromium, lead, copper and other toxic metals expressed in mg/l. 

The most important non-ferrous metals for handling water are lead, copper and zinc the last, however, is used chiefly as a protective coating on steel or alloyed with copper to form brass. 

Cathodes may be made of carbon, lead, copper or stainless steel. 

Determination of silver as chloride Discussion. The theory of the process is given under Chloride (Section 11.57). Lead, copper(I), palladium)II), mercury)I), and thallium)I) ions interfere, as do cyanides and thiosulphates. If a mercury(I) [or copper(I) or thallium(I)] salt is present, it must be oxidised with concentrated nitric acid before the precipitation of silver this process also destroys cyanides and thiosulphates. If lead is present, the solution must be diluted so that it contains not more than 0.25 g of the substance in 200 mL, and the hydrochloric acid must be added very slowly. Compounds of bismuth and antimony that hydrolyse in the dilute acid medium used for the complete precipitation of silver must be absent. For possible errors in the weight of silver chloride due to the action of light, see Section 11.57. 

Modification of the burning rates, pressure exponents, and temp coefficients of burning rate of the fluorocarbon composites has been accomplished with copper, lead, tin, sodium, ammonium and potassium fluoborates sodium, potassium, lithium, lead, copper and calcium fluorides potassium and ammonium dichromate lead and zinc stearate cesium carbonate potassium and ammonium sulfate copper chromite oxides of magnesium, copper and manganese boron zinc dust and carbon black (Ref 75)... 

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