Layered solids classes

ABC dry chemical extinguishers work like BC, except that the powder used is also selected so that it forms a sticky solid layer on solid (Class A) materials. This layer prevents oxygen from attacking the fuel, even though it may still be hot enough to bum (see Figure 2.1.2.4). 

Boundary layer flows are a special class of flows in which the flow far from the surface of an object is inviscid, and the effects of viscosity are manifest only in a thin region near the surface where steep velocity gradients occur to satisfy the no-slip condition at the solid surface. The thin layer where the velocity decreases from the inviscid, potential flow velocity to zero (relative velocity) at the sohd surface is called the boundary layer The thickness of the boundary layer is indefinite because the velocity asymptotically approaches the free-stream velocity at the outer edge. The boundaiy layer thickness is conventionally t en to be the distance for which the velocity equals 0.99 times the free-stream velocity. The boundary layer may be either laminar or turbulent. Particularly in the former case, the equations of motion may be simphfied by scaling arguments. Schhchting Boundary Layer Theory, 8th ed., McGraw-HiU, New York, 1987) is the most comprehensive source for information on boundary layer flows. 

This account of the kinetics of reactions between (inorganic) solids commences with a consideration of the reactant mixture (Sect. 1), since composition, particle sizes, method of mixing and other pretreatments exert important influences on rate characteristics. Some comments on experimental methods are included here. Section 2 is concerned with reaction mechanisms formulated to account for observed behaviour, including references to rate processes which involve diffusion across a barrier layer. This section also includes a consideration of the application of mechanistic criteria to the classification of the kinetic characteristics of solid-solid reactions. Section 3 surveys rate processes identified as the decomposition of a solid catalyzed by a solid. Section 4 reviews other types of solid + solid reactions, which may be conveniently subdivided further into the classes... 

Separations based upon differences in the chemical properties of the components. Thus a mixture of toluene and aniline may be separated by extraction with dilute hydrochloric acid the aniline passes into the aqueous layer in the form of the salt, aniline hydrochloride, and may be recovered by neutralisation. Similarly, a mixture of phenol and toluene may be separated by treatment with dilute sodium hydroxide. The above examples are, of course, simple apphcations of the fact that the various components fall into different solubility groups (compare Section XI,5). Another example is the separation of a mixture of di-n-butyl ether and chlorobenzene concentrated sulphuric acid dissolves only the n-butyl other and it may be recovered from solution by dilution with water. With some classes of compounds, e.g., unsaturated com-poimds, concentrated sulphuric acid leads to polymerisation, sulphona-tion, etc., so that the original component cannot be recovered unchanged this solvent, therefore, possesses hmited apph cation. Phenols may be separated from acids (for example, o-cresol from benzoic acid) by a c ute solution of sodium bicarbonate the weakly acidic phenols (and also enols) are not converted into salts by this reagent and may be removed by ether extraction or by other means the acids pass into solution as the sodium salts and may be recovered after acidification. Aldehydes, e.g., benzaldehyde, may be separated from liquid hydrocarbons and other neutral, water-insoluble liquid compounds by shal g with a solution of sodium bisulphite the iddehyde forms a solid bisulphite compound, which may be filtered off and decomposed with dilute acid or with sodium bicarbonate solution in order to recover the aldehyde. 

The mature vitreous contains a class of mononuclear phagocytic cells called hyalocytes (Balzas and Delinger, 1984). These cells are generally embedded in the vitreous humour 20-50 /tM away from the basal lamina, forming a single layer of scattered cells. In the developing eye they are located more centrally and are capable of synthesizing the main solid constituents of the vitreous gel. 

Mooney et al. [70] investigated the effect of pH on the solubility and dissolution of ionizable drugs based on a film model with total component material balances for reactive species, proposed by Olander. McNamara and Amidon [71] developed a convective diffusion model that included the effects of ionization at the solid-liquid surface and irreversible reaction of the dissolved species in the hydrodynamic boundary layer. Jinno et al. [72], and Kasim et al. [73] investigated the combined effects of pH and surfactants on the dissolution of the ionizable, poorly water-soluble BCS Class II weak acid NSAIDs piroxicam and ketoprofen, respectively. 

Five aspects of the preparation of solids can be distinguished (i) preparation of a series of compounds in order to investigate a specific property, as exemplified by a series of perovskite oxides to examine their electrical properties or by a series of spinel ferrites to screen their magnetic properties (ii) preparation of unknown members of a structurally related class of solids to extend (or extrapolate) structure-property relations, as exemplified by the synthesis of layered chalcogenides and their intercalates or derivatives of TTF-TCNQ to study their superconductivity (iii) synthesis of a new class of compounds (e.g. sialons, (Si, Al)3(0, N)4, or doped polyacetylenes), with novel structural properties (iv) preparation of known solids of prescribed specifications (crystallinity, shape, purity, etc.) as in the case of crystals of Si, III-V compounds and... 

Two categories of mesoporous solids are of special interest M41S type materials and pillared or delaminated derivatives of layered zeolite precursors (pillared zeolites in short). The M41S family, first reported in early 1990 s [1], has been extensively studied [2,3]. These materials exhibit broad structural and compositional diversity coupled with relative ease of preparation, which provides new opportunities for applications as catalysts, sorption and support media. The second class owes its existence to the discovery that some zeolite crystallizations can produce a lamellar intermediate phase, structurally resembling zeolites but lacking complete 3-dimensional connectivity in the as-synthesized form [4]. The complete zeolite framework is obtained from such layered zeolite precursor as the layers become fused, e.g. upon calcination. The layers posses zeolitic characteristics such as strong acidity and microporosity. Consequently, mesoporous solids derived from layered zeolite precursors have potentially attractive characteristics different from M41S and the zeolite species... 

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