Layer ferroelectric devices

Multilayer Capacitors. Multilayer capacitors (MLC), at greater than 30 biUion units per year, outnumber any other ferroelectric device in production. Multilayer capacitors consist of alternating layers of dielectric material and metal electrodes, as shown in Figure 7. The reason for this configuration is miniaturization of the capacitor. Capacitance is given by... 

Both CdS and a-Si have been successfully used as the photocondoctor 45°-twisted nematic layers and, on an experimental basis, ferroelectric layers have been used for the liquid crystal. CCD structures and silicon vidicon microdiode arrays have been used in place of the photocon-ductive layer. The device is useful both when the write beam is coherent (for example, a scanned laser) and when it is incoherent (for example, a CRT). In the latter case, the SLM can be used as an incoherent-to-coherent converter. The CRT-written device has also found application as a projection display. There exists a very large potential market for optically addressed SLMs in a variety of optical processing applications and for projection displays. 

Chiral Smectic. In much the same way as a chiral compound forms the chiral nematic phase instead of the nematic phase, a compound with a chiral center forms a chiral smectic C phase rather than a smectic C phase. In a chiral smectic CHquid crystal, the angle the director is tilted away from the normal to the layers is constant, but the direction of the tilt rotates around the layer normal in going from one layer to the next. This is shown in Figure 10. The distance over which the director rotates completely around the layer normal is called the pitch, and can be as small as 250 nm and as large as desired. If the molecule contains a permanent dipole moment transverse to the long molecular axis, then the chiral smectic phase is ferroelectric. Therefore a device utilizing this phase can be intrinsically bistable, paving the way for important appHcations. 

It has recently been shown that organic photoconductor-liquid crystal sandwich cells can in theory act as dynamic scattering devices 164> and the technical possibilities ought to be tested. In this context, it should be noted that dyes can be used in two-layer photocondensers (consisting e.g. of phthalocyanine and a ferroelectric ceramic), which are very sensitive to light and have a response time of lO-4 to 10-3 Sec 165). 

The use of bulk ferroelectrics in pyroelectric devices inevitably leads to a situation where the material must be cut, lapped and polished to make a thin, thermally-sensitive layer. If an array of detectors is required for thermal imaging, this must be metallized on both faces,... 

Since the early suggestion that ferroelectric thin film materials could be the high dielectric layer in the capacitor of the ultra large scale integrated dynamic random access memory devices (ULSI DRAMS) made by Parker and Tasch, there has been a great deal of research effort to deposit multi-component ferroelectric oxide thin films as well as more recent industrial activity. The term ferroelectric indicates the property of certain materials that have remnant... 

Even though some ferroelectric materials, especially the relaxor ferroelectrics, have an extremely large dielectric constant, which is a very desirable property for the dielectric layer of capacitors in ULSI DRAMS, the usually large dielectric loss prevents the materials from being used in the DRAMS. Furthermore, the quite large number of component cations of the relaxor ferroelectric materials makes it almost impossible to deposit thin films using chemical vapor deposition (CVD) which is believed to be the method of choice for mass production of the devices. 

Perovskite-related Oxides.—The perovskite-related oxides have been studied extensively in recent years because of the large variety of device applications for which these materials are suited. The interaction between structure, properties, and stoicheiometry is significant at all levels, but here we will discuss only the narrow areas where intergrowth is a dominant structural feature. We will not, therefore, consider solid solutions typified by the Pb(Zr Tii )03 ferroelectrics, and neither will we discuss the structurally complex but stoicheiometric phases related to hexagonal BaTiOj, which includes BaNiOj, which has a simple two-layer repeat in the c-direc-tion, the nine layer BaRuOj, the twelve layer Ba4Re2CoOj2, and the twenty-four layer Sr5Re20ig phase. The crystal chemistry of these phases is treated in detail by Muller and Roy. The materials we shall discuss are the two series of phases A B 0 +2 and A + B 02n+, and the bismuth titanates. Some of the anion deficient perovskites, ABO -x, will be considered in Section 5. 

A method to obtain nano-particles at air/water interfaces has been described in [287]. Spreading of surfactant-coated metallic, semi-conducting, magnetic and ferroelectric nanoparticles on water surfaces results in the formation of monoparticulate thick films which then can be transferred, layer by layer, to solid substrates. These films can find potential applications in advanced electronic and electro-optical devices. Here and further, we give only typical examples of using surfactants in novel technologies. A more detailed description can be found in a new edition of Surfactants Science Series [288]. 

Flexible spacers in the semirigid-rod molecule allow the molecule to orient with order parameter greater than 0.8 when coated and cured upon a rubbed polyimide layer. Kinetics of the photo-polymerization [62,63] and surface-induced orientation [49] as well as mechanical [64,65], optical [59,66,67], and ferroelectric properties [68-70] of the anisotropic networks were thoroughly examined. These investigations were mainly carried out by the Philip s research group and were applied to develop liquid crystalline display devices [58,69]. 

In recent years, with the development of small-size fabrication techniques, new types and classes of high performance ceramic materials, consisting of, e.g., nano-composite structures and devices, layered structured ferroelectrics, multilayered functional devices, etc., have attracted considerable attention because of their improved mechanical/functional properties. Concurrent to processing developments, multiple complementary metrology tools are required for the evaluation of nano-scale mechanical and functional characteristics of the materials [1-3]. 

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