Coatings, surfactants

Surfactant-coated surfaces may also rearrange on contact with a liquid as shown by Israelachvili and co-workers [77]. This mechanism helps to explain hysteresis occurring on otherwise smooth and homogeneous surfaces. 

When surfactant-coated glass fibers are included to improve product flexibility and reduce thermal expansion, these semibatch processes are termed reinforced reaction injection mol ding (RRIM). 

The most effective of these include immobilization [80], lipid coating [81], surfactant coating [82], use of cross-linked enzyme crystals [83], cross-linked enzyme aggregates [84], and membrane reactors [85]. 

BAM showed bright regions due to the Ag particles and dark regions occupied primarily by oleic acid (Fig. 10b). TEM showed monolayer domains of surfactant-coated silver particles within regions of oleic acid. Vertical transfer onto quartz plates of up to eight layers with good linearity was reported. 

By performing in situ the polymerization of acrylamide in water/AOT/toluene microemulsions, clear and stable inverse latexes of water-swollen polyacrylamide particles stabilized by AOT and dispersed in toluene have been found [192-194], It was shown that the final dispersions consist of two species of particles in equilibrium, surfactant-coated polymer particles (size about 400 A) with narrow size distribution and small AOT micelles (size about 30 A). 

The longtime stabihty of surfactant-coated Pd nanoparticles in w/o microemulsions has been investigated. It has been proven that under suitable conditions, the use of the functionalized surfactant Pd(AOT)2 allows very stable nanosize Pd particles to be obtained and to finely control their average size [229],... 

In the flotation process, surfactant-coated mineral particles float to the surface of the mixture, where they become trapped in the froth. The gangue settles to the bottom. 

C20-0108. Draw a moiecuiar picture of a surfactant coating a minerai particie in a fiotation process. (See Chapter 12 for a review of surfactants.)... 

Towns, J. K. and Regnier, F. E., Capillary electrophoretic separations of proteins using nonionic surfactant coatings, Anal. Chem., 63, 1126, 1991. 

Enzyme activity for the polymerization of lactones was improved by the immobilization on Celite [93]. Immobilized lipase PF adsorbed on a Celite showed much higher catalytic activity than that before the immobilization. The catalytic activity was further enhanced by the addition of a sugar or poly(ethylene glycol) in the immobilization. Surfactant-coated lipase efficiently polymerized the ring-opening polymerization of lactones in organic solvents [94]. 

The effect that hydrophobic organic substances can become sorbed to organic coatings can be used to make sorbents by coating inorganic colloids such as ferri-hydrite with surfactants. Such surfactant-coated surfaces contain films of hemicelles (see 4.5) which are able to remove hydrophobic solutes, such as toluene or chloro-hydrocarbons, from solution (Holsen, et al., 1991). 

Holsom, T. M., E. R. Taylor, Y.-C. Seo, and P. R. Anderson (1991), "Removal of Sparingly Soluble Organic Chemicals from Aqueous Solutions with Surfactant-Coated Terrihydrite", Environ, Sci. Technol. 25, 1585-1589. 

Additional contact angles were measured at 0.001 M SDS concentration. The hematite disk was conditioned in the SDS solution before adding polymer to the solution. The contact angle was measured after adding sufficient quantities of polymer for concentrations of 1, 3, and 5 ppm. For both PAA and PAM, the contact angle remained constant and identical to the value obtained in the absence of polymer. No polymer was able to adsorb on the surfactant-coated disk. It can be concluded that whichever species, surfactant or polymer, adsorbed first was not... 

In case of lipases, one of the simplest methods to combine an enzyme with an organic solvent is to coat the lipase with a lipid or surfactant layer before lyophilisation. It is estimated that about 150 surfactant molecules are sufficient for encapsulating one lipase molecule. Following this route the surfactant coated lipase forms reverse micelles with a minimum of water concentration. The modified lipases are soluble in most organic solvents, and the reaction rates are increased compared to the suspended hpases due to the interfacial activation [59,60]. 

Figure 8.10 Schematic diagram of the forces acting on a beam separating a pure water surface from a surfactant coated surface.

Surfactants adsorb reversibly during the making of foams and emulsions, and the resulting surfactant-coated interface remains fluid-like (in... 

N. E. Baryla, J. E. Melanson, M. T. McDermott, and C. A. Lucy, Characterization of Surfactant Coatings in Capillary Electrophoresis by Atomic Force Microscopy, Anal. Chem. 2001, 73, 4558 M. M. Yassine and C. A. Lucy, Enhanced Stability Self-Assembled Coatings for Protein Separations by Capillary Zone Electrophoresis Through the Use of Long-Chained Surfactants, Anal. Chem. 2005, 77, 62. 

For the collection of monolayers, the microbubble surfactant mixture was spread (see above) and compressed to at least 24 dyne/cm. Thereafter, a rectangular piece of stainless steel mesh (4 cm x 1 cm, 30 mesh) was introduced vertically through the surface of the subphase, by means of a small handle, and alternately raised and lowered so that the air/water interface remained within the area of the mesh. This slow, vertical oscillation was coupled with a horizontal movement of the mesh along the surface of the subphase. The procedure resulted in a continual drop in the measured surface pressure (see above) as monolayer material gradually accumulated over the surface of the mesh. The surfactant-coated mesh was then transferred to and shaken in a glass vial containing high-purity ethanol. Once rinsed, the... 

Earlier studies (ref. 440-442) with ordinary air microbubbles (without any synthetic surfactant coating) have already shown that echocardiographic contrast produced by microbubbles is useful in the qualitative analysis of blood flow and valvular regurgitation. In addition, quantitative studies (ref. 440) have shown a correlation between individual contrast trajectories on M-mode echocardiography and invasive velocity measurements in human beings. Meltzer et al. (ref. 441) have shown that velocities derived from the slopes of contrast trajectories seen on M-mode echocardiography correlate with simultaneous velocities obtained by Doppler techniques. (This correlation is expected because both measures represent the same projection of the microbubble velocity vector, that is, in the direction of the sound beam.) More detailed studies (ref. 442) confirmed that microbubble velocity obtained from either Doppler echocardiography or M-mode contrast trajectory slope analysis correlates well with actual (Doppler-measured) red blood cell velocity. Thus, these early studies have shown that microbubbles travel with intracardiac velocities similar to those of red blood cells. 

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