Isopropanolamine, oxidation

Etliyleiie oxide [75-21-8] propylene oxide [75-56-9] or butylene oxide [106-88-7] react widi aminonia to produce alkanolainines (Table 1). Etlianolainines, (n = 1, 2,3, mono-, di-, and tri-), are derived from the reaction of ammonia witli ethylene oxide. Isopropanolamines,... 

Ammonia, and Amines. Isopropanolamine is the product of propylene oxide and ammonia ia the presence of water (see Alkanolamines). Propylene oxide reacts with isopropanolamine or other primary or secondary amines to produce A/- and A/,A/-disubstituted isopropanolamines. Propylene oxide further reacts with the hydroxyl group of the alkanolamines to form polyether polyol derivatives of tertiary amines (50), or of secondary amines ia the presence of a strong base catalyst (51). 

Isopropa.nola.mines. Reaction of propylene oxide with ammonia yields mono-, di-, and triisopropanolamines. These products find use as soluble oils and solvents, emulsifiers, waterless hand cleaners, cosmetics, cleaners, and detergents. In industrial apphcations isopropanolamines are used in adhesives, agricultural products, corrosion inhibitors, coatings, epoxy resins, metalworking, and others (51). 

Propylene oxide (PO) is an important intermediate in the manufacture of a wide range of valuable products propylene glycol, ethers, isopropanolamines, and various propoxylated products for polyurethanes (1). The current processes for the large scale synthesis of PO include (i) the chlorohydrin process and (ii) the peroxide process (1, 2). 

Isopropanolamines, NH3 (CH2CHOHCH3), result from the reaction of ammonia with propylene oxide. Secondary butanolamines, NH3 (CH2CHOHCH2CH3), are the result of the reaction of ammonia with butylene oxide. Mixed alkanolamines can be produced from a mix-... 

The proportions of the various isopropanolamines formed as functions of NH3 propylene oxide ratio are shown graphically in Fig. 8-9. 

Mineral spirits Type I. See Stoddard solvent Mineral wax. See Ceresin Ozokerite Mineral white. See Calcium sulfate dihydrate Minium. See Lead oxide, red MIPA. See Isopropanolamine MIT MITC. See Methyl isothiocyanate Mixed cresols. See Cresylic acid... 

Isooctyl alcohol Isophthalic acid, Isopropanolamine, Isostearic acid, Itaconic acid, Jayflex DHP Jayflex DINA Jayflex DIOP Jonrez IC-2805 Kenplast G Lanolin alcohol Maleic acid Maleic anhydride, Mekon White 2-Mercaptoethanol 3-Methoxybutanol Methoxyethanol Methoxyethyl acrylate. Methyl acetyl ricinoleate Methyl caprate. Methyl laurate. Methyl linoleate Methyl oleate Methylpropanediol Neopentyl glycol Nonanolc acid, Nopalcol 4-0 Nomlacresin, Octoxynol 2-Octyi-l-decanol Octyl palmitate. Oleic acid. Oxidized soybean oil Paroll 142 ... 

Isobutylene/isoprene copolymer, brominated 2-lsocyanatoethyl methacrylate Isopropanolamine Lactic acid Lead oxide, yellow... 

Guanidine carbonate Hydrochloric acid Isobutyric acid Isopropylamine Lactic acid Lithium hydroxide Magnesium carbonate hydroxide Magnesium hydroxide Magnesium oxide Maleic acid Metaphosphoric acid Mixed isopropanolamines Pentasodium triphosphate Phosphoric acid Potassium bicarbonate... 

Isostearamidopropylamine oxide Isostearamidopropyl morpholine lactate Lapyrium chloride Lauramidopropylamine oxide Lauramidopropyl betaine Laureth-2 Lauryl hydroxysultaine Methyl morpholine oxide Minkamidopropalkonium chloride Minkamidopropylamine oxide Minkamidopropyl betaine Mixed isopropanolamines lauryl sulfate Mixed isopropanolamines myristate Myristoyl sarcosine Octoxynol-50 Oleamide MIPA Oleyl betaine... 

Mixed isopropanolamines lauryl sulfate wetting agent, circuit board cleaners CIO-12 pareth-5 C12-14 pareth-9 wetting agent, clay soils Deceth-4 Deceth-6 Deceth-9 wetting agent, cleaners Alcohol Ammonium decyl sulfate Cocamidopropylamine oxide lsodeceth-9 lsolaureth-10... 

Alkanolamines are prepared from ammonia and EO, PO, or butylene oxide. The second series, the isopropanolamines, were first produced on a commercial scale in the United States in 1937. The three products obtained from the reaction of ammonia and PO are mono-, di-, and tri-isopropanol-amine, (CHjCHOHCHj) NHj.n, where, n = 1, 2, or 3 (Figure 26.13). 

Propylene oxide Propylene glycol, glycol ethers, poly(propylene glycols) non-ionic tensides isopropanolamine 6 in 2005 (see Section 6.12)... 

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