Industrial activities processes

The spin coated samples were activated in a quartz reactor, under a 30 ml/min flow of dry air (99.98 %, Indugas) purified over molecular sieves (3 A, Alltech). The temperature was increased by steps of 100°C, at a rate of 10°C/min. Thermal equilibration of the reactor was ensured by holding each plateau for 1 h. The final activation step was at 650°C during 6 h, reflecting the industrial activation process. The activated wafer was then used in a polymerization reaction. This was carried out in 2 bar ethylene (30 ml/min), purified over molecular sieves, at 160°C during approximatively 30 min. These reaction conditions were chosen to reduce the induction period prior to polymerization. The reaction was then stopped by switching to purified He flow (30 ml/min) at 160°C for 2 h, before cooling the reactor to room temperature. 

The review of Section 5.9.5 was published in 1989, this 1991 review being presented to an international conference held in France and published as a Conference proceedings (Rodriguez-Reinoso, 1991). This review discusses the activation of carbons by carbon dioxide and steam and the development of porosities. In addition, the review considers the relevance of the reaction with oxygen in industrial activation processes. 

The purpose of chemical processes is not to make chemicals The purpose is to make money. However, the profit must he made as part of a sustainable industrial activity which retains the capacity of ecosystems to support industrial activity and life. This means that process waste must be taken to its practical and economic minimum. Relying on methods of waste treatment is usually not adequate, since waste treatment processes tend not so much to solve the waste problem but simply to move it from one place to another. Sustainable industrial activity also means that energy consumption must be taken to its practical and economic minimum. Chemical processes also must not present significant short-term or long-term hazards, either to the operating personnel or to the community. 

Chemical processes will in the future need to be designed as part of a sustainable industrial development which retains the capacity of ecosystems to support industrial activity and life. This book therefore places a high emphasis on waste minimization and energy efficiency in the context of good economic performance and good health and safety practices. 

Commercial production and consumption of glycerol has generaHy been considered a fair barometer of industrial activity, as it enters into such a large number of industrial processes. It generaHy tends to rise in periods of prosperity and faH in recession times. 

Catalytic Oxidization. A principal technology for control of exhaust gas pollutants is the catalyzed conversion of these substances into innocuous chemical species, such as water and carbon dioxide. This is typically a thermally activated process commonly called catalytic oxidation, and is a proven method for reducing VOC concentrations to the levels mandated by the CAAA (see Catalysis). Catalytic oxidation is also used for treatment of industrial exhausts containing halogenated compounds. 

Contamination of waters with ai senic occurs as a result of a number of industrial activities such as treatment of industrial wastes, fertilizers, pesticides production, mining, metal smelting etc. and natural processes (e.g. weathering of minerals, volcanic and biological activities). 

The process related to the paint shop does not impose a significant pollution load on the environment compared to many other industrial activities. It is, however, essential that all possible aspects of environmental pollution by wastewater, environmental hydrology, environmental hydraulics and pneumatics, air, solid waste, noise and hazardous wastes etc. are reviewed to control any kind of pollution within the prescribed limits. Otherwise subsequent tragedies, if caused by environmental negligence in the industrial processes, may lead to the formation of stricter environmental laws. 

The advantages of such biotransformation processes are (1) the relatively high yields which can be achieved with specific enzymes, (2) the formation of chiral compounds suitable for biopharmaceuticals, and (3) the relatively mild reaction conditions. Key issues in industrial-scale process development are achieving high product concentrations, yields and productivities by maintaining enzyme activity and stability under reaction conditions while reducing enzyme production costs. 

The BiodeNOx process is a novel process concept to reduce NO emissions from flue gases of stationary sources like power plants and other industrial activities [1]. The concept combines a wet chemicd absorption process with a novel biotechnological regeneration method. In the wet chemical absorption step, flue gas components are absorbed into an aqueous solution of Fe"(EDTA) (EDTA= ethylme-diamino-tetraacetic acid). The following reactions take place ... 

Since many years, pectolytic enzymes have been widely used in industrial beverage processing to improve either the quality and the yields in fruit juice extraction or the characteristics of the final product [1,2]. To this purpose, complex enzymatic mixtures, containing several pectolytic enzymes and often also cellulose, hemicellulose and ligninolytic activities, are usually employed in the free form. The interactions among enzymes, substrates and other components of fruit juice make the system very difficult to be investigated and only few publications are devoted to the study of enzymatic pools [3-5], An effective alternative way to carry out the depectinisation process is represented by the use of immobilized enzymes. This approach allows for a facile and efficient enzymatic reaction control to be achieved. In fact, it is possible to avoid or at least to reduce the level of extraneous substances originating from the raw pectinases in the final product. In addition, continuous processes can be set up. 

The high specific activity of enzymes and tfie tfieoretical possibility of using them to conduct electrochemical reactions are topics of great scientific interest. However, it is difficult to envisage prospects for a practical nse of enzymes for an acceleration and intensification of industrial electrode processes. The difficulty resides in the fact that enzymes are rather large molecnles, and on the surface of an enzyme electrode, fewer active sites are available than on other electrodes. Per unit snrface area, therefore, the effect expected from the nse of enzymes is somewhat rednced. 

Chemical processes should be designed as part of a sustainable industrial activity that retains the capacity of ecosystems to support both life and industrial activity into the future. Sustainable industrial activity must meet the needs of the present, without compromising the needs of future generations. For chemical process design, this means that processes should use raw materials as efficiently as is economic and practicable, both to prevent the production of waste that can be environmentally harmful and to preserve the reserves of raw materials as much as possible. Processes should use as little energy as is economic and practicable, both to prevent the build-up of carbon dioxide in the atmosphere from burning fossil fuels and to preserve the reserves of fossil fuels. Water must also be consumed in... 

The following natural precursors have been selected for KOH activation coal (C), coal semi-coke (CS), pitch semi-coke (PS) and pitch mesophase (PM). An industrial activated carbon (AC) was also used. Activation was performed at 800°C in KOH with 4 1 (C KOH) weight ratio, for 5 hours, followed by a careful washing of the samples with 10% HC1 and distilled water. The activation process supplied highly microporous carbons with BET specific surface areas from 1900 to 3150 m2/g. The BET surface area together with the micro and the total pore volume of the KOH-activated carbons are presented in Table 1. The mean micropore width calculated from the Dubinin equation is designed as LD. 

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