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In sulfonation

Of the higher alkyinaphthalenes, those of importance are the amyl-, diamyl-, polyamyl-, nonyl-, and dinonylnaphthalenes. These alkyinaphthalenes are used in sulfonated form as surfactants and detergent products. [Pg.487]

Catalytic reduction of secondary functionaUties in sulfonates, in which the sulfonate moiety is unchanged, is accompHshed using standard hydrogenation techniques (21). Sulfonic acids may be converted to the corresponding silyl esters in very high yields (22). [Pg.97]

Sulfur dioxide is usefiil as a solvent for sulfur trioxide in sulfonation reactions for example, in the large-scale production of alkylbenzenesulfonate surfactant (329). A newer use for sulfur dioxide is in cyanide detoxification in connection with cyanide leaching of precious metals from mine dumps. [Pg.148]

Dispersion Technology. Substantial advancements in dispersion technology have been made since the initial introduction in 1923 of disperse dyes in paste form for cellulose acetate. Dyes were dissolved in sulfonated fatty acids such as sulforicinoleic acid [36634-48-7] (SRA),... [Pg.449]

Substituents in the indazole ring may direct a given reaction towards another position either by their R and I electronic properties or simply by protecting the most reactive position. Examples of both types are found in sulfonation studies (67HC(22)l). As indicated before (Section 4.04.2.3.2(i)), sulfonation takes place at position 7. However, the presence of an amino group at positions 5 or 7 directs the attack towards the 4-position (Scheme 40). To obtain the indazole-5-sulfonic acid a more complicated procedure has been used but it is still based on the same ideas. [Pg.259]

Materials that are corrosion resistant to the expected cathodic polarization qualify as impressed current cathodes. Austenitic CrNi steels are used with strong acids. The oleum (i.e., fuming sulfuric acid) and concentrated sulfuric acid tanks used in sulfonating alkanes and in the neutralization of sulfonic acids are anodi-cally protected using platinized brass as cathodes [15]. Lead cathodes are used to protect titanium heat exchangers in rayon spinning baths [16]. [Pg.477]

The relative stability of the intermediates determines the position of substitution under kinetically controlled conditions. For naphthalene, the preferred site for electrophilic attack is the 1-position. Two factors can result in substitution at the 2-position. If the electrophile is very bulky, the hydrogen on the adjacent ring may cause a steric preference for attack at C-2. Under conditions of reversible substitution, where relative thermodynamic stability is the controlling factor, 2-substitution is frequently preferred. An example of this behavior is in sulfonation, where low-temperature reaction gives the 1-isomer but at elevated temperatures the 2-isomer is formed. ... [Pg.568]

Verify, by making molecular models, that the bonds to sulfur are arranged in a trigonal pyramidal geometry in sulfoxides and in a tetrahedral geometry in sulfones. Is phenyl vinyl sulfoxide chiral What about phenyl vinyl sulfone ... [Pg.686]

Table 14. Kinetics of quasi-diffusion of oxytetracycline ions in sulfonated cation exchangers... Table 14. Kinetics of quasi-diffusion of oxytetracycline ions in sulfonated cation exchangers...
Two-component methods represent the most widely applied principles in sulfone syntheses, including C—S bond formation between carbon and RSOz species of nucleophilic, radical or electrophilic character as well as oxidations of thioethers or sulfoxides, and cheletropic reactions of sulfur dioxide. Three-component methods use sulfur dioxide as a binding link in order to connect two carbons by a radical or polar route, or use sulfur trioxide as an electrophilic condensation agent to combine two hydrocarbon moieties by a sulfonyl bridge with elimination of water. [Pg.166]

The advance of sulfur trioxide as sulfating agent largely depended on advances in sulfonation/sulfation reactor development and changes in raw material quality. Undiluted sulfur trioxide cannot be used as a sulfating agent except in special cases where suitable equipment is used because of its violent nature. Sulfur trioxide diluted in an inert gas, usually air, when used in batch processes can cause excessive dehydration and dark-colored products. However, batch processes were used years ago and inert liquid solvents were often suggested or used to moderate the reaction. Inadequate reaction conditions lead to a finished product that can contain dialkyl sulfate, dialkyl ether, isomeric alcohols, and olefins whereas inadequate neutralization conditions can increase the content of the parent alcohol due to hydrolysis of the unstable acid sulfate accompanied by an increase of mineral sulfate. [Pg.231]

The difference in sulfonation behavior between a-olefins (AO) and internal olefins (IO) has been a longstanding problem [14] and the literature is replete with earlier explanations [14,15] and practical solutions [16-20] to the problem of IO sulfonation. In their studies of IO sulfonation chemistry, Stapersma and colleagues [4], Radici et al. [21], Yoshimura et al. [22,23], and Roberts and Jackson [24] identified the origins of the poor sulfonatability of IO, and the process modifications required to produce good-quality IO sulfonate. [Pg.367]

Analysis of sulfonic acid species in sulfonated olefins. Kupfer and Kuenzler [108] reported the determination of acid species following partition between a 6.5% hydrochloric acid solution in 40% ethanol and a 1 1 (v/v) propan-2-ol-hexane mixture. The organic fraction contains alkenesulfonic and hydroxy-alkanesulfonic acids and the aqueous phase disulfonic acids and sulfato-sulfonates. The monosulfonic acids were converted to methyl esters and separated by column chromatography. To determine sulfatosulfonates the aqueous fraction was hydrolyzed and then partitioned and chromatographed. The separation is controlled using IR spectroscopy. [Pg.435]


See other pages where In sulfonation is mentioned: [Pg.467]    [Pg.686]    [Pg.244]    [Pg.255]    [Pg.255]    [Pg.289]    [Pg.419]    [Pg.514]    [Pg.560]    [Pg.579]    [Pg.721]    [Pg.897]    [Pg.897]    [Pg.980]    [Pg.74]    [Pg.81]    [Pg.81]    [Pg.83]    [Pg.84]    [Pg.424]    [Pg.200]    [Pg.36]    [Pg.51]    [Pg.51]    [Pg.393]    [Pg.404]    [Pg.487]    [Pg.523]    [Pg.531]    [Pg.912]    [Pg.1070]    [Pg.104]    [Pg.229]    [Pg.300]    [Pg.434]    [Pg.452]    [Pg.129]   
See also in sourсe #XX -- [ Pg.563 ]

See also in sourсe #XX -- [ Pg.563 ]




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Recent trends in sulfone polymer applications and some application-specific grades

SULFONES IN SOLID-PHASE HETEROCYCLE SYNTHESIS

Sulfonate Esters as Substrates in Nucleophilic Substitution

Sulfonated Poly(Arylene Ether Ketone)s in DMFC

Sulfonates, S- dithioiminium salts generation in situ

Sulfonation by sulfuric acid and oleum in the presence of catalysts

Sulfonation in general

Sulfonation in synthesis of polymer supported reagent

Sulfone Linkers in Oligosaccharide Synthesis

Sulfone base labile group in crosslinkers

Sulfones use in synthesis

Sulfoxides, 1-Sulfones, and 1-Telluroglycosides in Glycosylation Reactions

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