Synthesis hydrides

H.G. Kuivii.a, Reduction of Organic Compounds by Organotin Hydrides, Synthesis 1970, 499. 

Safety considerations are paramount in any boron hydride synthesis. The energy yield from the oxidations of boron hydrides is too high for any cavalier treatment of boron hydrides. Exclusion of air is the critical consideration in diborane reactions. Decaborane(14) is less reactive, generally, in a kinetic sense, but the thermodynamic potential is comparable. In addition, all volatile boron hydrides are toxic. The procedures described in the latter two preparations are within our experience non-hazardous. These procedures should be followed in every detail improvisation is not recommended. 

Crotchet, R. A. Blanton, C. D. TV-Monoalkylation of Primary Aromatic and Heteroaromatic Amines with Trialkyl Orthocarboxylates and Sodium Boro-hydride, Synthesis 1974, 55. 

Methylthio)thiophene, with trinuclear Os clusters, 6, 744 Methyltin hydride, synthesis, 3, 844 Methyltitanation, alkynes, 10, 256 Methylzirconocene ester enolates, preparation, 4, 923 Methylzirconocene pyrazolyl compounds, preparation,... 

B.P. Tarasov, V.N. Fokin, A.P. Moravsky, Yu.M. Shul ga, V.A. Yartys , and D.V. Schur, Promotion of Mlerene hydride synthesis by intermetallic compounds, I roc. of 12th World Hydrogen Energy Conference, Buenos Aires, Argentina 2, 1221-1230 (1998). 

Tarasov B.P., Fokin V.N., Moravsky A.P., Shulga Yu.M., Yartys V.A., Schur D.V. Promotion of fullerene hydride synthesis by intermetallic compounds // Proceed. 12th World Hydrogen Energy Conf. Buenos Aires. Argentine. 1998. Vol. 2. P. 1221. 

Figure 2.26 Hydride synthesis via Rieke-activated metals...

Figure 2.29 Metal hydride synthesis (a) employing borohydride reagents, (b) via tetrahydroborate ligands and (c) via formyl intermediates...

Other methods of organoantimony hydride synthesis are reactions of R2SbLi with (Me3NH)Cl or methanolysis of silylstibines RSb(SiMc3)2 or R2SbSiMc3. Vinyl stibine H2C=C(H)-SbH2 is obtained from vinyl tributylstaimane on successive reactions (equation 8) with SbCb and BusSnH. ... 

Hydride synthesis by metal-carbonyl hydrolysis is used widely, and mechanistic details are emerging. The reaction begins with nucleophilic attack by H O or [OH] on a carbonyl ligand ... 

The cooled dispersion is either poured from the creased flask into a suitable container for further use or utilized directly in the dispersion flask (sodium hydride, synthesis 3). 

Magnesium hydride synthesis goes back almost 100 years with the pyrolysis of ethylmagnesium halides (Jolibois, 1912) to give a mixture of magnesium hydride, magnesium halide and ethylene ... 

Keywords Hydride/Hydrogen Accumulator/High Pressure/Hydride Synthesis/... 

Tsuji J, Mandai T (1996) Palladium-catalyzed Hydrogenolysis of Allylic and Propargylic Compounds with Various Hydrides. Synthesis 1... 

CpJTiH, a Thermally Stable Paramagnetic Titanium (III) Hydride Synthesis and Characterization... 

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