Hydrated production

In general, the production of fused materials is much more energy intensive than that of hydrated products, and this difference is reflected in their prices. The primary producers are the United States Borax Chemical Corp. and the North American Chemical Co. Yearly fusion capacities for the two companies ate reported to be 86,000 and 36,000 metric tons B2O2, respectively (6). There is a plant in Turkey designed for the production of 60,000 t/yr of refined anhydrous borax from tincal ore (102). Small quantities of anhydrous borax have been produced in Argentina. 

Calcium Silicates. Cements aie hydiated at elevated tempeiatuies foi the commercial manufacture of concrete products. Using low pressure steam curing or hydrothermal treatment above 100°C at pressures above atmospheric, the products formed from calcium siUcates are often the same as the hydrates formed from their oxide constituents. Hence lime and siUca ate ftequendy used in various proportions with or without Portland cement in the manufacture of calcium siUcate hydrate products. Some of these compounds are Hsted in Table 6. 

Significant improvements over the PPG process involve reaction of lime with concentrated HOCl (50%) and drying of the resultant slurry in a spray grainer or fluidized-bed spray dryer to produce hydrated product with av CI2 as high as 82% (126,127,129,210,211). 

Calcium Hypochlorite. High assay calcium hypochlorite [7778-54-3] was first commercialized in the United States in 1928 by Mathieson Alkali Works, Inc. (now Olin Corp.) under the trade name HTH. It is now produced by two additional manufacturers in North America (Table 5). Historically, it usually contained about 1% water and 70—74% av CI2, so-called anhydrous product, but in 1970, a hydrated product was introduced (234). It is similar in composition to anhydrous Ca(OCl)2 except for its higher water content of about 6—12% and a slightly lower available chlorine content. This product has improved resistance to accidental initiation of self-sustained decomposition by a Ht match, a Ht cigarette, or a small amount of organic contamination. U.S. production in the 1990s consists primarily of partially hydrated Ca(OCl)2, which is sold as a 65% av CI2 product mainly for swimming pool use. Calcium hypochlorite is also sold as a 50% av CI2 product as a sanitizer used by dairy and food industries and in the home, and as a 32% product for mildew control. 

The formation of cotar none from cotar nine methine methiodide by the action of potash (IX—X) led Roser to represent cotarnine and its salts by the following formulae, the loss of a molecule of water in the formation of cotarnine salts being explained by the production of a partially reduced pyridine ring, which is fully hydrogenated in the reduction of cotarnine to hydrocotarnine. In the reverse process, oxidation of liydrocotarnine to cotarnine, Roser assumed the scission of the ring at the point indicated, with the formation of a hydration product, and oxidation of the latter to cotarnine thus —... 

The study of structure and reactivity of tertiary heterocyclic enamines is associated with the problem of equilibrium of the cyclic enamine form (70) and the tautomeric hydration products 173,174) quaternary hydroxide (71), pseudo base (so-called carbinolamine) (72) and an opened form of amino aldehyde or amino ketone (73). 

Abdelrazig, Sharp El-Jazairi (1988, 1989) prepared a series of mortars based on a powder blend of MgO and ADP with a quartz sand filler. They were hydrated by mixing with water. A mortar I (MgO ADP silica water = 17T 12-9 70-0 12-5), with a water/solid ratio of 1 8, formed a workable paste which set in 7 minutes with evolution of ammonia. The main hydration product, struvite, was formed in appreciable amounts within 5 minutes and continued to increase. Schertelite also appeared, but only in minor amounts, within the first 5 minutes and persisted only during the first hour of the reaction. Dittmarite appeared in minor amounts after 15 minutes, and persisted. 

The addition of STPP (1-7%) acted as a retarder and increased compressive strength (mortar II). Less heat and ammonia were evolved and the cement set more slowly in 10 minutes. The paste hardened in 30 to 60 minutes. Traces of ADP persisted for 30 minutes but no STPP was detected in the reaction products. Struvite, the main hydration product, schertelite and dittmarite all appeared within 5 minutes. Struvite continued to increase in amount as the cement aged schertelite disappeared after 3 hours and dittmarite after a week. Stercorite was found only during the first 7 hours. 

Hydroboration, the addition of a boron-hydrogen bond across an unsaturated moiety, was first discovered by H. C. Brown in 1956. Usually, the reaction does not require a catalyst, and the borane reagent, most commonly diborane (B2H6) or a borane adduct (BH3-THF), reacts rapidly at room temperature to afford, after oxidation, the /AMarkovnikov alkene hydration product. However, when the boron of the hydroborating agent is bonded to heteroatoms which lower the electron deficiency, as is the case in catecholborane (1,3,2-benzodioxaborole) 1 (Scheme 1), elevated temperatures are needed for hydroboration to occur.4 5... 

Majorowicz Osadetz (2001) reported that the Mallik gas hydrate-bearing deposit in permafrost regions tends to occur at depths of 700 m to 1400 m where the permafrost is 100 m to 900 m thick. The Mallik 2002 Gas Hydrate Production Research Well Program conducted scientifically constrained production tests of the natural gas from the Mallik gas hydrate deposit, which is situated in the Mackenzie Delta on the coast of the Beaufort Sea, Northwest Territories, Canada (Dallimore et al. 2005a Satoh et al. 2005). Gas hydrate production tests demonstrated the potential for possible commercial production. Japan intends to establish commercial production from gas hydrates within the time frame of conventional natural gas production from the Mackenzie Delta (Yonezawa 2003). 

Dallimore, S.R., Collet, T.S., Uchida, T., Weber, M. 2005a. Overview of the science program for the Mallik 2002 Gas Hydrate Production Research Well Program., In Dallimore, S.R. T.S. Collett, T.S. (eds.),Scientific Results from the Mallik 2002 Gas Hydrate Production Research Well Program, Mackenzie Delta, Northwest Territories, Canada. Geological Survey of Canada, Bulletin 585. 

Wright, J.F., Dallimore, S.R., Nixon, F.M., Duchesne, C. 2005. In situ stability of gas hydrate in reservoir sediments of the JAPEX/JNOC/GSC et al. Mallik 5L-38 gas hydrate production research well. Geological Survey of Canada, Bulletin 585. 

The key to establishing gas hydrates as a significant energy resource is whether the methane gas will ever be economically and safely producible. The current state of knowledge is still too limited to allow reliable estimates on the start of an economic gas hydrate production. The BGR (2003) estimates gas hydrate resources at 500 Tm3. 

Dihydro-1,2-dihydroxybenzene (10.13) is oxidized by dihydrodiol dehydrogenase (EC 1.3.1.20) to catechol (10.15) (Chapt. 4 in [la]) [76], In a typical experiment in which 10.13 is incubated with phenobarbital-induced rabbit liver microsomes, phenol (10.14), catechol (10.15), and hydroquinone (10.16) represent 54, 39, and 1%, respectively, of the total metabolites detected [75]. In other words, neither benzene oxide (10.1) nor its hydration product l,2-dihydro-l,2-dihydroxybenzene (10.13) was detected. 

Wei, L.Y. Gas chromatographic and mass spectrometric characterization of terbufos sulfoxide and its hydration product, J. Environ. Sci Health, B25(5) 607-613, 1990. 

Seventeen people exposed to phosphorus trichloride liquid and its hydration products after a tanker accident were evaluated. Those closest to the spill experienced burning of the eyes, lacrimation, nausea, vomiting, dyspnea, and cough. Six patients had transient elevation of lactic dehydrogenase. Chest roentgenograms were normal. Pulmonary function tests showed statistically significant decreases in vital capacity and FEVi in direct correlation with distance from the accident and duration of exposure. Of the 17 patients examined 1 month later, pulmonary function tests showed improvement, suggesting that acute effects were due to phosphorus trichloride toxicity. ... 

Bybee, K. (2004). Overview of the mallik gas-hydrate production research well. J. 

Hydrate Production Research Well Program, Mackenzie Delta, Northwest Territories, Canada, Ottawa, Canada, Geological Survey of Canada Bulletin 585, including CD. 

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