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Ground-state configuration

Metals are fiindamentally different from insulators as they possess no gap in the excitation spectra. Under the influence of an external field, electrons can respond by readily changing from one k state to another. The ease by which the ground-state configuration is changed accounts for the high conductivity of metals. [Pg.127]

This air-sensitive complex is epr-active, having a (id- ground-state configuration as opposed to a ground-state (87). [Pg.42]

The self-consistent field function for atoms with 2 to 36 electrons are computed with a minimum basis set of Slater-type orbitals. The orbital exponents of the atomic orbitals are optimized so as to ensure the energy minimum. The analysis of the optimized orbital exponents allows us to obtain simple and accurate rules for the 1 s, 2s, 3s, 4s, 2p, 3p, 4p and 3d electronic screening constants. These rules are compared with those proposed by Slater and reveal the need for the screening due to the outside electrons. The analysis of the screening constants (and orbital exponents) is extended to the excited states of the ground state configuration and the positive ions. [Pg.159]

Consider the electronic ground state of dicarbon C2. Elementary arguments would suggest a ground state configuration... [Pg.187]

The treatment follows my discussion of the it n spectra in Chapter 8, I actually performed a CIS calculation on pyridine within the ZDO scheme. If the ground state configuration is... [Pg.190]

These are ground-state configurations 1s22s 2p2 would be an excited state for boron. [Pg.144]

To sum-up, we can to some extent recover the order of filling by calculating the ground state configurations of a sequence of atoms but nobody has yet deduced the n + rule from the principles of quantum mechanics.13... [Pg.100]

The procedure that we have been using is called the building-up principle. It can be summarized by two rules. To predict the ground-state configuration of a neutral atom of an element with atomic number Z with its Z electrons ... [Pg.159]

Self-Test 1.11A Predict the ground-state configuration of a magnesium atom. [Pg.160]

Self-Test 1.12B Write the ground-state configuration of an arsenic atom. [Pg.161]

How many unpaired electrons are predicted for the ground-state configuration of each of the following atoms ... [Pg.177]

Configuration interaction, which is necessary in treatments of excited states and desirable in calculations of spin densities, is more complex with open-shell systems. This is because more types of configurations are formed by one-electron promotions. These configurations (Figure 5) are designated as A, B, Cq, C(3 G is the symbol for a ground state. Configurations C and Cp have the same orbital part but differ in the spin functions. [Pg.338]

The specified configurations are ground-state configurations except at La (g) and Gd (g) where the ground states are [Xe]5d and [Xe]4F5d respectively. It can be seen that the variations in It, do indeed correspond to the stabihty sequence for the dipositive oxidation state. The correspondence can also be tested quantitatively by using estimated and experimental values of AG (1). These are also plotted in Fig. 1.1. The parallelism between the two is very close. [Pg.2]

The next atoms of the periodic table are beryllium and boron. You should be able to write the three different representations for the ground-state configurations of these elements. The filling principles are the same as we move to higher atomic numbers. Example shows how to apply these principles to aluminum. [Pg.523]

Construct an energy level diagram and the shorthand representation of the ground-state configuration of aluminum. Provide one set of valid quantum numbers for the highest-energy electron. [Pg.523]

According to Hund s mle, the ground-state configuration for carbon atoms is arrangement 2. Example provides practice in the application of Hund s rale. [Pg.527]

From the periodic table, we see that sulfur has 16 electrons and is in the p block. Group 16. To build the ground-state configuration, apply the normal filling rales and then apply Hund s rule if needed. [Pg.527]

Often, an s orbital contains only one electron rather than two. Five of the exceptional ground-state configurations have a common pattern and are easy to remember Cr and Mo are d, and Cu, Ag, and Au are S". The... [Pg.528]

Ti A neutral titanium atom has 22 electrons. The ground-state configuration is (Ar] A 3 cf. The spins of the 4 electrons cancel, but the two electrons in 3 orbitals have the same spin orientation, so... [Pg.532]


See other pages where Ground-state configuration is mentioned: [Pg.2424]    [Pg.52]    [Pg.359]    [Pg.361]    [Pg.28]    [Pg.6]    [Pg.8]    [Pg.15]    [Pg.15]    [Pg.15]    [Pg.98]    [Pg.100]    [Pg.107]    [Pg.145]    [Pg.28]    [Pg.217]    [Pg.220]    [Pg.183]    [Pg.801]    [Pg.803]    [Pg.90]    [Pg.358]    [Pg.116]    [Pg.514]    [Pg.516]    [Pg.528]    [Pg.528]    [Pg.533]   
See also in sourсe #XX -- [ Pg.238 , Pg.245 ]

See also in sourсe #XX -- [ Pg.242 , Pg.244 ]

See also in sourсe #XX -- [ Pg.417 , Pg.423 ]




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Arsenic ground state electronic configuration

Atomic ground state, electronic configuration

Atomic ground-state electron configuration

Atoms ground state configurations

Atoms ground-state electron configuration

Barium ground state electronic configuration

Benzene, ground state configuration

Berkelium ground state electronic configuration

Beryllium ground state electronic configuration, 18

Bismuth ground state electronic configuration

Boron ground state electronic configuration

Bromine ground state electronic configuration

Caesium ground state electronic configuration

Calcium ground state electronic configuration

Carbon ground state electronic configuration

Carbon, ground-state electron configuration

Cerium ground state electronic configuration

Chlorine ground state electronic configuration

Chromium ground state electronic configuration

Cobalt ground state electronic configuration

Condensed ground-state configuration

Copper ground state electronic configuration

Curium ground state electronic configuration

Data tables ground-state electron configurations

Diatomic molecules ground state electronic configurations

Dysprosium ground state electronic configuration

Einsteinium ground state electronic configuration

Electron Configuration and Ionization Ground State

Electron Configurations of Atoms in the Ground State

Electron configuration ground state

Electron configuration, ground state table

Electronic configuration condensed ground state

Electronic structure ground state configurations

Elements ground state electron configurations

Elements ground-state configuration

Erbium ground state electronic configuration

Ethylene ground-state configuration

Europium ground state electronic configuration

Eyring plot ground state electronic configurations

Fermium ground-state electronic configuration

Fluorine ground state electronic configuration

Ground State Electron Configurations of Atoms

Ground state configuration of elements

Ground state configurations, survey

Ground state electron configurations, homonuclear

Ground state electronic configuration 5-block elements

Ground state electronic configuration experimental data

Ground state electronic configuration listed for elements

Ground state electronic configuration notation

Ground state electronic configuration p-block elements

Ground state electronic configurations of the elements and ionization energies

Ground state, factors determining spin-configuration

Ground-state configuration Aufbau principle

Ground-state configuration defined

Ground-state configuration, water molecule

Ground-state electronic configuration

Ground-state electronic configuration molecular

Group ground state electronic configurations

Hafnium ground state electronic configuration

Helium ground state electronic configuration, 17 18

Homonuclear diatomic molecules ground state electronic configurations

Hydrogen ground state electron configuration

Hydrogen ground state electronic configuration

Hydrogen ground-state configuration

Iodine ground state electronic configuration

Iridium ground state electronic configuration

Krypton ground state electronic configuration, 17 18

Lanthanoids ground state electronic configurations

Lanthanum ground state electronic configuration

Lawrencium ground state electronic configuration

Lithium ground state electronic configuration

Lutetium ground state electronic configuration

Magnesium ground state electronic configuration

Manganese ground state electronic configuration

Mendelevium ground state electronic configuration

Mercury ground state electronic configuration

Molecules ground state configurations

Molybdenum ground state electronic configuration

Neptunium ground state electronic configuration

Nickel ground state electronic configuration

Nitrogen ground state electronic configuration

Nobelium ground state electronic configuration

Osmium ground state electronic configuration

Oxidation states ground state configurations

Oxygen ground state electronic configuration

Palladium ground state electronic configuration

Phosphorus ground state electronic configuration, 18

Phosphorus, ground-state electron configuration

Platinum ground state electronic configuration

Plutonium ground state electronic configuration

Polonium ground state electronic configuration

Potassium ground state electronic configuration

Praseodymium ground state electronic configuration

Protactinium ground state electronic configuration

Radium ground state electronic configuration

Radon ground state electronic configuration

Rhenium ground state electronic configuration

Rhodium ground state electronic configuration

Rubidium ground state electronic configuration

Ruthenium ground state electronic configuration

Samarium ground state electronic configuration

Scandium ground state electronic configuration

Selenium ground state electronic configuration

Silicon ground state electronic configuration

Silver ground state electronic configuration

Sodium ground state electronic configuration

Sodium ground-state electron configuration

Strontium ground state electronic configuration

Subshells ground-state configuration

Sulfur ground state electronic configuration

Sulfur ground-state configuration

Tantalum ground state electronic configuration

Technetium ground state electronic configuration

Tellurium ground state electronic configuration

Terbium ground state electronic configuration

Thallium ground state electronic configuration

Thorium ground state electronic configuration

Titanium ground state electronic configuration

Transition metals ground-state configuration

Uranium ground state electronic configuration

Vanadium ground state electronic configuration

Writing condensed ground-state configuration

Writing ground-state configurations

Xenon ground state electronic configuration

Ytterbium ground state electronic configuration

Yttrium ground state electronic configuration

Zirconium ground state electronic configuration

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