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Transition metals ground-state configuration

The electronic structure of SO2 has been the subject of several theoretical studies which have provided a basis for interpretations of UV and photoelectron spectroscopic measurements These will not be reviewed in detail here since they all agree on those features which are important for a qualitative understanding of transition metal complex formation. The ground state configuration obtained from the extended Hiickel approach, for example, is (Iai) (lb2) (2ai) (lbi) (3ai) (2b2) (la2) (3b2) (4ai) (2bi) (4b2) (5ai) using 2 s, 2 p oxygen orbitals and 3 s, 3 p sulfur orbitals as a basis. The salient features from the M-SO2 bonding standpoint are the HOMO (4ai) and the LUMO (2bi), depicted in Fig. 2. These two orbitals can be described qualitatively as follows ... [Pg.49]

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See also in sourсe #XX -- [ Pg.237 ]



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Ground state configurations

Metal states

Metallic state

Transition metals configuration

Transition-state configuration

Transitional configuration

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