Gravimetric analysis calculations

Determining the amount of a species by gravimetric analysis Given the amount of a precipitate in a gravimetric analysis, calculate the amount of a related species. (EXAMPLE 4.12)... 

Quantitative Calculations When needed, the relationship between the analyte and the analytical signal is given by the stoichiometry of any relevant reactions. Calculations are simplified, however, by applying the principle of conservation of mass. The most frequently encountered example of a direct volatilization gravimetric analysis is the determination of a compound s elemental composition. 

Precipitation reactions have many applications. One is to make compounds. The strategy is to choose starting solutions that form a precipitate of the desired insoluble compound when they are mixed. Then we can separate the insoluble compound from the reaction mixture by filtration. Another application is in chemical analysis. In qualitative analysis—the determination of the substances present in a sample—the formation of a precipitate is used to confirm the identity of certain ions. In quantitative analysis, the aim is to determine the amount of each substance or element present. In particular, in gravimetric analysis, the amount of substance present is determined by measurements of mass. In this application, an insoluble compound is precipitated, the precipitate is filtered off and weighed, and from its mass the amount of a substance in one of the original solutions is calculated (Fig. 1.6). Gravimetric analysis can be used in environmental monitoring to find out how much of a heavy metal ion, such as lead or mercury, is in a sample of water. 

The NaCl -SOD formed during these reactions can be clearly identified by its IR spectrum, perchlorate sodalite collapse at 1050°C. From the thermo gravimetric analysis it is evident that at this temperature the entire amount of NaCl escapes. The degree of the cage filling by salt molecules can be calculated on the basis of both the oxygen and the NaCl loss. 

Gravimetric analysis methods proceed with the following steps 1) the weight or volume of the prepared sample is obtained, 2) the analyte is either physically separated from the sample matrix or chemically altered and its derivative separated from the sample matrix, and 3) the weight of the separated analyte or its derivative is obtained. The data thus obtained are then used to calculate the desired results. 

The ultimate goal of any titrimetric analysis is to determine the amount of the analyte in a sample. This involves the stoichiometry calculation mentioned in the Work the Data section of the analytical strategy flow chart in Figure 4.1. This amount of analyte is often expressed as a percentage, as it was for the gravimetric analysis examples in Chapter 3. This percentage is calculated via the basic equation for percent used previously for the gravimetric analysis examples ... 

As with gravimetric analysis, the weight of the sample (the denominator in Equation (4.33)) is determined by direct measurement in the laboratory or by weighing by difference. The weight of the analyte in the sample is determined from the titration data via a stoichiometry calculation. As discussed previously, we calculate moles of substance titrated (in this case, the analyte) as in Equation (4.21) ... 

Gravimetric analysis is an unique technique by means of which either an element or a compound is obtained in its purest form through isolation and subsequent weighing. In order to achieve this, the element or compound is first and foremost separated from a specific portion of the pharmaceutical substance being determined and consequently the weight of the constituent in the given sample is calculated on the basis of the weight of the product. 

Calculations In gravimetric analysis the percentage of the desired constituent may be achieved by the following expression ... 

What is the critical role played by common ion effect in gravimetric analysis Explain the theoretical aspect and calculations involved in such an analysis. 

The structural characterization of the resulting diblock copolymers was performed by means of SEC, NMR spectroscopy, thermal gravimetric analysis (TGA), and DSC. In most of the cases the PDI values were found to be lower than 1.3. However, the calculation of the molar masses of the diblock copolymers was not straightforward since the calibration standards (PEG, PS, and PMMA) used in SEC systems do not provide accurate data. Moreover, the folding behavior of the different block copolymers significantly infiuence the hydrodynamic volume and,... 

In gravimetric analysis, the mass of a product is used to calculate the quantity of the original analyte (the species being analyzed). Exceedingly careful gravimetric analysis by T. W. Richards and his colleagues early in the twentieth century determined the atomic masses of... 

If there is introduced into the solution from some other source an ion that is in common with an ion of the insoluble solid, the chemical equilibrium is shifted to the left, and the solubility of that solid will be greatly decreased from what it is in pure water. This is called the 11 common-ion effect." This effect is important in gravimetric analysis, where one wishes to precipitate essentially all of the ion being analyzed for, by adding an excess of the "common-ion" precipitating reagent. There is a practical limit to the excess, however, which involves such factors as purity of precipitate and possibility of complex formation. You can calculate the solubility under a variety of conditions, as illustrated in the following problem. 

Gravimetric analysis is one of classical analytical methods. It is based on chemical transformation of the sample using excess of a reagent to a substance, which is weighed after processing. The weight of the substance obtained serves as a base for calculation of amount of substance. 

Thermal gravimetric analysis of the t-BOC protected copolymers shows a precipitous loss of 25% of the sample mass between 150 and 180 C then a plateau followed by slow decomposition above 300°C (Figure 4). These results mirror the DSC results. The first weight loss agrees well with that calculated for loss of CO2 and isobutene (25.4%) and occurs coincident with loss of the 1755 crrr carbonate absorbance in the infrared and the appearance of the broad phenolic OH absorbance (Figure 5). 

Gravimetric analysis is the process of converting an element into a definitive compound, isolating this compound from other constituents in a sample and then weighing the compound (Box 20.1). The weight of the element can then be calculated from the formula of the compound and the relative atomic masses of the elements involved. You need to be able to weigh accurately, by difference, a substance to four decimal places (see p. 23). 

When chemists are faced with problems that require them to determine the quantity of a substance by mass, they often use a technique called gravimetric analysis. In this technique, a small sample of the material undergoes a reaction with an excess of another reactant. The chosen reaction is one that almost always provides a yield near 100%. If the mass of the product is carefully measured, you can use stoichiometry calculations to determine how much of the reactant of unknown amount was involved in the reaction. Then by comparing the size of the analysis sample with the size of the original material, you can determine exactly how much of the substance is present. 

Gravimetric analysis is a highly accurate technique, since the mass of a sample can be measured accurately. However, this procedure is applicable only to reactions that go to completion, or have nearly 100 percent yield. Thus, if AgCl were slightly soluble instead of being insoluble, it would not be possible to remove all the Cl ions from the NaCl solution and the subsequent calculation would be in error. 

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