Gasification continued

Alternative feedstocks for petrochemicals have been the subject of much research and study over the past several decades, but have not yet become economically attractive. Chemical producers are expected to continue to use fossil fuels for energy and feedstock needs for the next 75 years. The most promising sources which have received the most attention include coal, tar sands, oil shale, and biomass. Near-term advances ia coal-gasification technology offer the greatest potential to replace oil- and gas-based feedstocks ia selected appHcations (10) (see Feedstocks, coal chemicals). 

A survey of commercial thermal gasification in the United States shows that few gasifiers have been installed since 1984 (115). Most units in use are retrofitted to small boilers, dryers, and kilns. The majority of existing units operate at 0.14 to 1.0 t/h of wood wastes on updraft moving grates. The results of this survey are summarized in Table 36. Assuming all 35 of these units are operated continuously, extremely unlikely, the maximum amount of LHV gas that can be produced is about 0.003 to 0.006 EJ/yr (222—445 td /d). 

Liquid Fuels. Liquid fuels can be obtained as by-products of low temperature carbonization by pyrolysis, solvent refining, or extraction and gasification followed by catalytic conversion of either the coal or the products from the coal. A continuing iaterest ia Hquid fuels has produced activity ia each of these areas (44—46). However, because cmde oil prices have historically remained below the price at which synthetic fuels can be produced, commercialization awaits an economic reversal. 

The high cost of coal handling and preparation and treatment of effluents, compounded by continuing low prices for cmde oil and natural gas, has precluded significant exploitation of coal as a feedstock for methanol. A small amount of methanol is made from coal in South Africa for local strategic reasons. Tennessee Eastman operates a 195,000-t/yr methanol plant in Tennessee based on the Texaco coal gasification process to make the methyl acetate intermediate for acetic anhydride production (15). 

The economics of coal gasification are influenced by the availabiHty of oil and natural gas, but coal is expected to continue to play an ever-increasing role as a significant resource base for both energy and chemicals. 

Matsumura, Y. Minowa, T., Fundamental design of a continuous biomass gasification process using a supercritical water fluidized bed. Journal of Hydrogen Energy 2004, 29, 701. 

Table 2.5 (continued) Summary of Key Characteristics of Gasification Technologies... 

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