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Focus On. .. Green Chemistry

With the focus on green chemistry, it is actually impossible to think on an industrial chemical reaction, which involves transition metal complexes, that is not efficiently catalytic. The chemical industry demands atom economical reactions, that is, those in which substrates are transformed into products with the only aid of catalytic amounts of the rest of reactants. Although really catalytic PKR appeared only in the mid-1990s, developments from recent years allow us to be moderately enthusiastic. The literature gives a good deal of catalytic protocols that use different cobalt and other metal complexes. Still, a lack of scope is generally observed in these reports. In addition there are few examples of intermolecular reactions performed in catalytic conditions [21]. [Pg.214]

In the mid-1990s, Carnegie Mellon University s Environmental Institute began to implement the Environment across the Curriculum initiative (75). The goal was to develop modules that contained environmental themes that could be used in courses in every college in the university... One of the modules, which focused on green chemistry and was specifically designed for the first year chemistry student, will be discussed. [Pg.82]

The next several chapters examine the factors that determine the speed and extent of chemical reactions kinetics (Chapter 14), equilibria (Chapters 15-17), thermodynamics (Chapter 19), and electrochemistry (Chapter 20). Also in this section is a chapter on environmental chemistry (Chapter 18), in which the concepts developed in preceding chapters are apphed to a discussion of the atmosphere and hydrosphere. This chapter has increasingly come to be focused on green chemistry and the impacts of human activities on Earth s water and atmosphere. [Pg.1230]

Like safety, green chemistry makes good business sense. The reader may wonder why all the fuss about green chemistry if it is something that might be done anyway. The answer is one of focus. Just as an increased focus on safety can lead to a decrease in accidents, the increased focus on green chemistry can lead to improvements both from an environmental perspective and from a business perspective. [Pg.247]

Focus On and Focus On Biological Chemistry boxes illustrate applications of organic chemistry to the world around us and to the health sciences, explore topics in more depth, or discuss the history of chemical discoveries. Some topics include DDT-Resistcmt Insects, Biological Alkylations and Poisons, and Environmentally Friendly Chemistry (Green Chemistry). [Pg.1328]

In this review, we have shown the major advances in the growing field of cascade chemistry that have led to regio-, chemo-, and stereoselective formation of several new carbon-carbon and carbon-heteroatom bonds in a stepwise economical fashion by using transition metal-catalyzed reactions. These approaches have already allowed very impressive and rapid construction of unnatural and natural polycyclic compounds of very high molecular complexity. These initial achievements should stimulate the synthetic community to pursue further works notably to develop more efficient and selective strategies that involve new generations of versatile catalysts. Next endeavors will have to focus on green processes as well as asymmetric catalysis. [Pg.291]

Main focus was Green Chemistry , i.e. fundamental research towards the development of new sustainable chemical processes, starting from the idea that pollution and hazards have to be eliminated at the source, thus reducing environmental impact and costs, as opposed to end-of-pipe reme-iation. Green Chemistry incorporates all aspects of chemi si r that reduce impact on human health and on the environment. Its goal is to improve the quality of life and the competitiveness of industry, by developing safer and more eco-friendly chemistry. [Pg.239]

If you have read through the twelve principles of green chemistry, you will likely have realized that the focus of green chemistry rests on minimizing the impact of the development, manufacturing, and use of chemical products on the environment. While these twelve principles may not enumerate every possible method for reducing the impact of chemicals on the environment, they provide a foundation for the outcomes that green chemistry seeks to achieve. [Pg.234]

The other survey was held to clarify the issues related to innovation policy, competitiveness and prospects for enterprise development after Russia joined the World Trade Organization (WTO) in 2012. The questionnaire contained the question section on green chemistry and its role as potential growth area for the Russian chemical industry. One hundred and four companies which participated in the survey are engaged in the production of the wide range of chemicals. Sixty-one per cent of surveyed enterprises had identified themselves as large, while others identified themselves as medium (32%) and small (7%). Eighty-two per cent of surveyed companies manufacture products for industrial use and 18% manufacture consumer products some of them are focused towards the Russian market, the others are export-oriented. [Pg.214]

Green chemistry (Chapter 11 Focus On) The design and implementation of chemical products and processes that reduce waste and minimize or eliminate the generation of hazardous substances. [Pg.1243]

While this works progresses, a part of our attention should be focused on potential industrial applications. In this regard, the path is set, because important principles of green chemistry are inherent to cellulose derivatives, namely the raw material is renewable, and the products are biodegradable. With regard to these principles, consider the following ... [Pg.141]


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