Rheological properties foams

First, a homogeneous suspension of filler must be produced. This suspension should be sedimentation-lfee because it would influence foam properties. Rheological studies are used to select the appropriate dispersion agents which keep the viscosity close to the viscosity of the unfilled formulations. Complete filler wetting and network formation helps to make the stable suspensions. 

Blends of poly (ethylene terephthalate) (PETP) and polypropylene (PP) with different rheological properties were dry blended or compounded, and extrusion foamed using both physical blowing and chemical agents, and the foam properties compared with those of foam produced from the individual components in the absence of compatibilisers and rheology modifiers. The foams were characterised by measurement of density, cell size and thermal properties. Low density foam with a fine cell size was obtained by addition of a compatibiliser and a co-agent, and foamed using carbon dioxide. The presence of PP or a polyolefin-based compatibiliser did not effect... 

In a later investigation, Kraynik and Hansen [62] demonstrated that the shear rate and liquid film viscosity greatly affect the rheological properties of foams. They studied the effect on foam properties and structure with variation of capillary number, Ca, which is the ratio of viscous to surface tension forces in the liquid films, and is given by -... 

Both bulk and interfacial rheological measurements and foaming properties show a large effect of pH on these properties of glycinin dispersions. This is undoubtedly related to the change in conformation of the glycinin molecule with pH as expressed in the presence of different amounts of the 3S, 7S and 11S form at different pH.11-13... 

Foamed fluid rheological properties are very responsive to changes in foam quality. Therefore, in order to achieve the desired treatment goals, accurate metering of the constituents of the foam is essential. The liquid C02 rate is measured using a low-pressure turbine metering device. To determine the volume of C02 required at the downhole conditions, a mass balance across the total system can be accomplished. 

Texture. Foam texture is an important parameter that affects the rheology of the foam fluid. Texture of a foam is a means of classifying a foam according to its bubble size, shape, and distribution within the foam matrix. Texture is a description of the manner in which the gas bubbles are distributed throughout the liquid phase of the foam. This property not only influences the foam s rheology but also its fluid loss, proppant transport, and cleanup properties. The texture of a foam is a qualitative rather than a quantitative value, and therefore a number cannot be used to describe it a physical description will be used. Factors that effect the texture of foams are quality, pressure, foam generating technique, and chemical composition. 

Because protein-ba sed foams depend upon the intrinsic molecular properties (extent and nature of protein-protein interactions) of the protein, foaming properties (formation and stabilization) can vary immensely between different proteins. The intrinsic properties of the protein together with extrinsic factors (temperature, pH, salts, and viscosity of the continuous phase) determine the physical stability of the film. Films with enhanced mechanical strength (greater protein-protein interactions), and better rheological and viscoelastic properties (flexible residual tertiary structure) are more stable (12,15), and this is reflected in more stable foams/emulsions (14,33). Such films have better viscoelastic properties (dilatational modulus) ( ) and can adapt to physical perturbations without rupture. This is illustrated by -lactoglobulin which forms strong viscous films while casein films show limited viscosity due to diminished protein-protein (electrostatic) interactions and lack of bulky structure (steric effects) which apparently improves interactions at the interface (7,13 19). 

These foams can also have complex rheological properties. Specialized methods have been developed to determine foam food rheology (see the references in Reference [55]) and to deal with the pronounced shp that can be exhibited by food foams [31]. Some food foams exhibit strong yield stresses, as in products that have been whipped to the stiff peak stage. Whipping air into egg white is an example. Baking the stiff foam that results produces meringue. 

Good synergy with anionic surfactants Excellent environmental compatibility Improve rheological properties and sebum solubilization Good foaming properties Very mild on skin... 

INTERFACIAL RHEOLOGY OF HEN EGG WHITE LYSOZYME-5-METHYLRESORCINOL MIXTURES AND THEIR FOAMING PROPERTIES... 

For very dry foams, the rheological properties are determined solely by the films separating the bubbles. The rheological properties of a set of randomly oriented films were determined first by Deijaguin (54) and later independently by Stamenovic and Wilson (55). These models set the scale for the elastic modulii of a foam. In the dry limit (when the gas fraction equals 1), the bulk modulus of the foam is dominated by that of the gas in... 

Ipsen, R., Otte, J., Sharma, R., Nielsen, A., Hansen, L. G., Brram Qvist, K. (2001). Effect of limited hydrolysis on the interfacial rheology and foaming properties of p-lactoglobulin A. Colloids and Surfaces B Biointerfaces, 21, 173—178. 

GiUgren,T, Alven,T. and Stading, M. (2010), Impact of melt rheology on zein foam properties. Journal of Materials Science. 45(21) jp. 5762-5768. 

Rheology. The rheology of foam is striking it simultaneously shares the hallmark rheological properties of soHds, Hquids, and gases. Like an ordinary soHd, foams have a finite shear modulus and respond elastically to a small shear stress. However, if the appHed stress is increased beyond the yield stress, the foam flows like a viscous Hquid. In addition, because they contain a large volume fraction of gas, foams are quite compressible, like gases. Thus foams defy classification as soHd, Hquid, or vapor, and their mechanical response to external forces can be very complex. 

One simple rheological model that is often used to describe the behavior of foams is that of a Bingham plastic. This appHes for flows over length scales sufficiently large that the foam can be reasonably considered as a continuous medium. The Bingham plastic model combines the properties of a yield stress like that of a soHd with the viscous flow of a Hquid. In simple Newtonian fluids, the shear stress T is proportional to the strain rate y, with the constant of proportionaHty being the fluid viscosity. In Bingham plastics, by contrast, the relation between stress and strain rate is r = where is... 

Foams have a wide variety of appHcations that exploit their different physical properties. The low density, or high volume fraction of gas, enable foams to float on top of other fluids and to fiU large volumes with relatively Httle fluid material. These features are of particular importance in their use for fire fighting. The very high internal surface area of foams makes them useful in many separation processes. The unique rheology of foams also results in a wide variety of uses, as a foam can behave as a soHd, while stiH being able to flow once its yield stress is exceeded. 

The effect of oxidative irradiation on mechanical properties on the foams of E-plastomers has been investigated. In this study, stress relaxation and dynamic rheological experiments are used to probe the effects of oxidative irradiation on the stmcture and final properties of these polymeric foams. Experiments conducted on irradiated E-plastomer (octene comonomer) foams of two different densities reveal significantly different behavior. Gamma irradiation of the lighter foam causes stmctural degradation due to chain scission reactions. This is manifested in faster stress-relaxation rates and lower values of elastic modulus and gel fraction in the irradiated samples. The incorporation of O2 into the polymer backbone, verified by IR analysis, conftrms the hypothesis of... 

Phospholipids are amphiphilic compoimds with high surface activity. They can significantly influence the physical properties of emulsions and foams used in the food industry. Rodriguez Patino et al. (2007) investigated structural, morphological, and surface rheology of dipalmitoylpho-sphatidylcholine (DPPC) and dioleoyl phosphatidylcholine (DOPC) monolayers at air-water interface. DPPC monolayers showed structural polymorphisms at the air-water interface as a function of surface pressure and the pH of the aqueous phase (Fig. 6.18). DOPC monolayers showed a... 

The numerous previous studies of the flow of foam in porous media and of its application for. improving the displacement of oil from such media, have almost always been conducted under ambient conditions of temperature and pressure there have been very few reports of laboratory studies under reservoir conditions. Although many interfacial properties are known to be temperature dependant, little attention has been paid to the influence of temperature upon the properties of foam. Furthermore, the rheological properties of foams, and their effectiveness for the displacement of oil are strongly dependant upon foam quality, which is in turn... 

Rheological properties, See also Rheology of dry foams, 12 16 of embedding materials, 10 10 of encapsulants, 10 12-13 of linear low density polyethylene,... 

H.M. Princen Rheology of Foams and Highly Concentrated Emulsions I. Elastic Properties and Yield Stress of a Cyhndrical Model System. J. Colloid Interface Sci. 91, 160 (1983). 

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