Flower origin

The involvement of metal ions in the color of anthocyanins and flavonoids was discovered almost a century ago, whereby the different colors of flowers originated from the same molecules under different conditions . The crystal structure of the pigment complex affords better understanding of the color and the role of metal ions , where Fe(III) and Mg(II) bind anthocyanins via the catechol moiety and Ca(II) binds flavone glycosides through a vicinal diol on the glycone. 

Theissen, G. and Becker, A. (2004). Gymnosperm orthologues of Class B floral homeotic genes and tlieir impact on understanding flower origin. Critical Reviews in Plant Sciences, 23, 129-48. 

Frohlich, M. W. (2002). The Mostly Male theory of flower origins summary and update regarding the Jurassic pteridosperm Pteroma. pp. 85-108 in Cronk, Q. C. B., Bateman, R. M. and Hawkins, J. A. (eds.). Developmental Genetics and Plant Evolution. London Taylor and Francis. 

L v ndin. Lavandin, Lavandula hjbrida as a plant species is of recent origin, unknown until the late 1920s. It is a hybrid of two common lavenders, l vandula officinalis and l vandula latifolia. Lavandin is cultivated mainly ia southern France and has become one of the most produced and used natural perfumery materials. The flowering tops of the shmb are used to produce a concrete, an absolute, and a steam-distilled oil the last is by far the most used. Low cost and refreshing odor quaUty allow lavandin to be employed ia a wide variety of perfume appHcations and at high concentrations. Chemically it is comprised of 30—32% linalool (3) and linalyl acetate (1), along with numerous other substances, mosdy terpenic. 

Thus as in the case of oil of bergamot, esterification is accompanied by a decrease in. the total proportion of linalol and in the proportion of free acid. These facts prove that, here also, the esters originate by the direct action of the acids on the alcohols. Under these conditions, as the plant develops, part of the linalol is esterified whilst another portion is dehydrated. So that not only does the proportion of free alcohol, but also that of the total alcohol decroase. But as the esterification process is completed, which happens when the flower commences to-fade, the total alcohols increase at a fairly rapid rate. 

Both cis- and trans-chrysanthemic nitriles and amides were resolved into highly enantiopure amides and acids by Rhodococcus sp. whole cells [85]. The overall enantioselectivity of reactions of nitriles originated from the combined effects of a higher (lJ )-selective amidase and a (IJ )-selective nitrile hydratase (Figure 6.29). Chrysanthemic acids are related to constituents of pyrethrum flowers and insecticides. 

Takhajan, A. 1969. Flowering Plants Origin and Dispersal. Smithsonian Institution Press, Washington, D.C. 

The carotenoids are the most widespread group of pigments in nature, with an estimated yield of 100 million tonnes per annum. They are present in all photosynthetic organisms and responsible for most of the yellow to red colours of fruits and flowers. The characteristic colours of many birds, insects and marine invertebrates are also due to the presence of carotenoids, which have originated in the diet. Animals are unable to synthesise carotenoids de novo, and so rely upon the diet as the source of these compounds. Carotenoids found in the human diet are primarily derived from crop plants, where the carotenoids are located in roots, leaves, shoots, seeds, fruit and flowers. To a lesser extent, carotenoids are also ingested from eggs, poultry and fish. Commercially, carotenoids are used as food colourants and in nutritional supplements (Table 13.1). Over recent years there has been considerable... 

In apple processing, enzymatic treatment of the crushed fruit leads to a lower degree of degradation of the peel and the core than the rest of the fruit. Figure 1 shows the separate tissue zones in diagrammatic form. Their anatomic origins are different the epidermis and outer parenchyma zones are tissues derived from the fusion of the calyx, corolla and stamens of the flower the inner zones correspond to tissue derived from ovaries and carpels. The characterisation of the cell-wall material, especially pectins, from the different zones of the fruit may provide additional information on the possibility of finding uses for the discarded fractions. 

Jasmine flowers are sometimes added to manufactured green tea in the country of origin and they impart characteristic floral notes. 

Secondary t-p. "THE GOLDEN FLEECE, or, THE FLOWER OF TREASURES In which is succintly and methodically handled, the Stone of the philosophers, his excellent effect admirable Virtues and The better to attain to the Original true means of Perfection. Inriched with Figures representing the Colours to rise as they suooesstvely appear in the Practise of this Blessed Work. By that great Philosopher SOLOMON TRISMOSIN Master to Paracelsus"... 

Then, as suddenly as it had appeared, mauve mania was over and the elegant world whirled on to a new color. A magnificent red never seen before in dyes, the French hue was variously named fuchsia for the flower blossom and magenta for a northern Italian town where the Emperor Napoleon III had defeated Austria that summer. Like Perkin s mauve, magenta was a wildly popular synthetic dye with humble origins in coal tar, that is, in aniline and other similar compounds. 

Only natural dyes were known until the nineteenth century. By trial and error and probably also by chance, humans learned to extract and use a large variety of dyes of vegetable and animal origin. Dyes were extracted from the roots, trunk bark, and branches of trees, the stems, leaves, flowers, and fruits of plants, the bodies of insects and mollusks, and the eggs of insects. All the dyes obtained from natural sources are rather impure, and hence the accurate reproducibility of colors was almost impossible during antiquity. Still, many of the dyes and dyeing techniques used in antiquity were highly developed and remained in use until the discovery of the synthetic dyes in the middle of the nineteenth century (Colombo 1995 Robinson 1969). 

A much explored pathway to simple silenes involves the thermolysis of silacyclobutanes at 400-700°C, the original Gusel nikov-Flowers (155) route. Such temperatures are not readily conducive to the isolation and study of reactive species such as silenes except under special conditions, and flash thermolysis, or low pressure thermolysis, coupled with use of liquid nitrogen or argon traps has frequently been employed if study of the physical properties is desired. Under these high temperature conditions rearrangements of simple silenes to the isomeric silylenes have been observed which can lead to complications in the interpretation of results (53,65). Occasionally phenyl-substituted silacyclobutanes have been photolyzed at 254 nm to yield silenes (113) as has dimethylsilacyclobutane in the vapor phase (147 nm) (162). 

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