Flame retardancy electronic

HFFREC (The Halogen-Free Flame Retardants Electronics Consortium)... 

Ra.dia.tlon. Use of radiation to affect fixation of some flame retardants is being investigated (110). Electron-beam fixation requires the selection of compounds that can be insolubilized inside or outside of the fiber with high yield in a short time. Polyunsaturated compounds, eg, Fyrol 76, have shown promise (see Radiation curing). 

Electrical Properties. Polysulfones offer excellent electrical insulative capabiUties and other electrical properties as can be seen from the data in Table 7. The resins exhibit low dielectric constants and dissipation factors even in the GH2 (microwave) frequency range. This performance is retained over a wide temperature range and has permitted appHcations such as printed wiring board substrates, electronic connectors, lighting sockets, business machine components, and automotive fuse housings, to name a few. The desirable electrical properties along with the inherent flame retardancy of polysulfones make these polymers prime candidates in many high temperature electrical and electronic appHcations. 

Figure 3.2 Innovation depth in electronic flame retardants. ...

Flame retardants in printed circuit boards partnership. Circuit boards are commonly used in electronics in consumer and industrial products, including computers and cell phones. In order to ensure fire safety, manufacturers commonly produce circuit boards with flame-retardant chemicals. While serving an important performance function, some flame-retardant chemicals can be harmful if released into the environment. To better understand the issues and the full range of options for flame-retarding circuit boards, DfE is engaging with the electronics industry and other stakeholders in a partnership. 

Semimetal that occurs as a tin-type, brittle form and as a yellow, unstable, nonmetallic form. Its main use is in alloys to harden other metals. Without the addition of antimony, lead would have remained the "softy" of the Periodic Table. But with antimony, lead ruled the print world and later found use in the production of rechargeable batteries. It can be found in older ceramic glazing (yellow orange). Everyday encounters antimony sulfide in match heads and red rubber, antimony oxide is used as a flame retardant. Pure antimony is starting to become of interest in the electronics sector. 

In order to accomplish with the aforementioned aim, during the first year of project, an extensive research on the different chemical additives used in six industrial sectors was conducted plastics, textiles, electronics, lubricants, leather, and paper. A list of selected chemical additives was identified for each sector and used as a study basis for the rest of the project. This is the case of the decabromo-diphenyl ether (BDE) used in electronics as a flame retardant or the triclosan used in the textile as a biocide. The results of this investigation were presented in the first volume of this book (Global Risk-Based Management of Chemical Additives I Production, Usage and Environmental Occurrence). This volume also included a section of case studies related to the selected additives in different countries (i.e., Denmark, Vietnam, Brazil, India). The main outcomes of the first part of the project are summarized below ... 

It is expected that soil PBDEs and PCDD/Fs may also have stemmed from other sources than e-waste recycling processes, as only 3% of the global production of flame retardants is used in electronic products [36]. Apparently, only a small portion of BFRs occurring in the environments is derived from e-waste. 

Keywords Brominated flame retardants, E-waste, Substance Flow Analysis SFA, Informal Recycling, Waste Electric and Electronic Equipment WEEE... 

Annex 1 Flame Retardants in Electric and Electronic Equipment Based on Morf et al. [11],... 

PBDEs are a class of brominated flame retardants (BFRs) used in textiles, plastics and electronic products. The effects of BFRs are associated with three commercial mixtures of PBDEs decaBDE, octaBDE and pentaBDE. In laboratory animal experiments, the toxicity of PBDEs was linked to damage to liver function and,... 

HBCD is a brominated aliphatic cyclic hydrocarbon used as a flame retardant in thermal insulation building materials, upholstery textiles, and electronics. In 2001, the world market demand for HBCD was 16,700 tons, from which 9,500 tons was sold in the EU. These figures make HBCD the second highest volume BFR used in Europe [29], HBCD may be used as an alternative for PBDEs in some applications. To date, there are no restrictions on the production or use of HBCD. As a result of their widespread use and their physical and chemical properties, HBCD are now ubiquitous contaminants in the environment and humans [30, 31]. 

Brominated flame retardants (BFRs) are comprised of diverse classes or chemical compounds used in a variety of commercial applications. They are used in plastics, textiles, electronic circuitry, and other materials to prevent fires. The estimated... 

Mirex (dodecachlorooctahydro-l,3,4-metheno-2H-cyclobuta [tv/] pentalene) has been used extensively in pesticidal formulations to control the red imported fire ant (Solenopsis invicta), and as a flame retardant in electronic components, plastics, and fabrics. One environmental consequence of mirex was the severe damage recorded to fish and wildlife in nine southeastern states and the Great Lakes, especially Lake Ontario. In 1978, the U.S. Environmental Protection Agency banned all further use of mirex, partly because of the hazards it imposed on nontarget biota. These included ... 

It is briefly reported that the European Parliament s environment committee has proposed a ban on the use of brominated flame retardants octabromodiphenylether and decabromodiphenylether, used in plastics and textiles, on health and environmental grounds. The two substances are scheduled to be banned from use in electronic and electrical equipment under separate EC draft legislation. The committee s decision has been announced before risk assessments of octa-BDE and deca-BDE for the commission have been completed. 

The move by the European Commission to make three separate pieces of legislation out of an original single draft directive on waste electrical and electronic equipment has probably served to intensify the focus onbrominated flame retardants in these applications. Under the draft, EU countries shall ensure that the use of lead, mercury,... 

The German Environmental Ministry is reported to have attacked European proposals to ban substances such as specific flame retardants in forthcoming regulations for recycling electrical and electronic equipment. Initial proposals from the EU Commission on the disposal of waste electrical and electronic equipment, include a phaseout of PBDEs, despite preliminary findings under EU risk assessment that there is no need for risk reduction from the two types, decaBDE and octaBDE mainly used in such equipment. The Ministry is said to be concerned at the excessively prescriptive and restrictive system being proposed, and that substance restrictions should not be addressed in waste legislation, but should be based on life cycle risk assessments. 

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