Fibers chromatography

Paperboard materials PAPERCHEM Paper chromatography Pap er-co a ting pigmen t Paper colorants Paper coloring Paper electrophoresis Paper fiber Paper formation aids Paper grades Paper industry... 

Polyester composition can be determined by hydrolytic depolymerization followed by gas chromatography (28) to analyze for monomers, comonomers, oligomers, and other components including side-reaction products (ie, DEG, vinyl groups, aldehydes), plasticizers, and finishes. Mass spectroscopy and infrared spectroscopy can provide valuable composition information, including end group analysis (47,101,102). X-ray fluorescence is commonly used to determine metals content of polymers, from sources including catalysts, delusterants, or tracer materials added for fiber identification purposes (28,102,103). 

Solid-phase microextraction (SPME) was used for headspace sampling. The FFA were extracted from the headspace with PA, Car/PDMS, and CW/DVB fibers. It was examined whether addition of salt (NaCl) and decreasing the pH by addition of sulphuric acid (H SO ) increased the sensitivity. FFA were analyzed using gas chromatography coupled to mass spectrometry in selected ion monitoring. 

Gellation catalysts, 224, 227-236 Gel permeation chromatography (GPC), 385-386, 490 Gels, urethane, 205 Glass-fiber-filled polyamides, 136 Glass transition temperature (7)), 3, 266, 267... 

The concept of SPME was first introduced by Belardi and Pawliszyn in 1989. A fiber (usually fused silica) which has been coated on the outside with a suitable polymer sorbent (e.g., polydimethylsiloxane) is dipped into the headspace above the sample or directly into the liquid sample. The pesticides are partitioned from the sample into the sorbent and an equilibrium between the gas or liquid and the sorbent is established. The analytes are thermally desorbed in a GC injector or liquid desorbed in a liquid chromatography (LC) injector. The autosampler has to be specially modified for SPME but otherwise the technique is simple to use, rapid, inexpensive and solvent free. Optimization of the procedure will involve the correct choice of phase, extraction time, ionic strength of the extraction step, temperature and the time and temperature of the desorption step. According to the chemical characteristics of the pesticides determined, the extraction efficiency is often influenced by the sample matrix and pH. 

The development of new fiber coatings in the near future should further improve the specificity of SPME and overcome some of the observed matrix effects. Quantification by stable isotope dilution gas chromatography/mass spectrometry (GC/MS) may assist in improving analytical performance. Along with the possible application of micro LC and capillary LC columns to in-tube SPME, the development of novel derivatization methods and the potential for the analysis of fumigant pesticides, SPME appears to be a technique with a future in the analysis of pesticide residues in food. 

Air is sampled through a glass-fiber filter disk for 6 h at a rate of 2 L min. The filter is placed in a vial containing acetonitrile and the vial is heated at 70 °C for 40 min. After cooling, the vial is ultrasonicated for 15 min. An aliquot of the acetonitrile is filtered and analysed by gas chromatography/mass spectrometry (GC/MS). 

Chromatography columns 100 x 15-mm i.d. with Teflon stopcock Glass-fiber filter (Whatman GF/D, 11-cm)... 

Svensson, L. M. and Markides, K. E., Fiber optic-based UV-absorption detector cell for high-temperature open tubular column liquid chromatography,... 

Figure 1 Electrochemical detection of catechol, acetaminophen, and 4-methyl catechol, demonstrating the selectivity of differential pulse detection vs. constant potential detection. (A) Catechol, (B) acetaminophen, and (C) 4-methylcatechol were separated by reversed phase liquid chromatography and detected by amperometry on a carbon fiber electrode. In the upper trace, a constant potential of +0.6 V was used. In the lower trace, a base potential of +425 mV and a pulse amplitude of +50 mV were used. An Ag/AgCl reference electrode was employed. Note that acetaminophen responds much more strongly than catechol or 4-methylcatechol under the differential pulse conditions, allowing highly selective detection. (Reproduced with permission from St. Claire, III, R. L. and Jorgenson, J. W., J. Chromatogr. Sci. 23, 186, 1985. Preston Publications, A Division of Preston Industries, Inc.)...

Both polymers 10 and 11 are soluble in common organic solvents, melt without decomposition, and can be drawn into the fibers. Molecular weights of the polymers 10 and 11, determined by gel permeation chromatography with tetrahydrofuran as the eluant after purification by reprecipitation from benzene-ethanol, showed a broad monomodal molecular weight distribution. The degree of polymerization depends on particle size of sodium metal. Polymers with molecular weights of 23,000-34,000 are always obtained, if fine sodium particles are used. 

Tourino S, Fuguet E, Jauregui O, Saura-Calixto F, Cascante M and Torres JL. 2008. High-resolution liquid chromatography/electrospray ionization tandem mass spectrometry to identify polyphenols from grape antioxidant dietary fiber. Rapid Commun Mass Spectrom 22 3489-3500. 

Hemodialysis machine, 26 814 Hemodialysis potting, 16 17 Hemodialysis prescription, 26 817-818 Hemodynamic chromatography, 6 722 Hemofiltration, 16 20 fibers for, 16 22... 

High-pressure gas separation, hollow-fiber membrane modules for, 15 823 High pressure liquid chromatography (hplc), 9 234 21 275 in herbicide analysis, 13 312 polymer analysis using, 19 566 High-pressure methanol, production process, 16 300-301 High pressure methods, specialized, 13 430-431... 

---