Feedstock oxygenated

The partial oxidation reactor is a refractory lined pressure vessel which contains a specially designed burner in the top. The feedstock, oxygen and steam enter the reactor through the burner and flow down through the... 

The feedstock, which may range from natural gas to naphtha, is heated and desulfurized (usually in a conventional ZnO/CoMoX bed ) to levels below 1 ppm after which steam is added and the combined feed is introduced into the ATR. The upper part of the reactor basically consists of a burner, mounted on the reactor shell the burner itself is the key item of the autothermal reactor and is critical for the reactor operation. In this part of the reactor, temperatures until 1,400°C are reached. The burner design is a proprietary design of the technology supplier. Flame stability, in combination with a sootless operation, is the key requirement for proper burner operation. This is accomplished with the correct ratio of feedstock, oxygen, and steam. 

Shot Coke. Shot coke is an undesirable product because it is inconsistent and in some cases dangerous. It is produced when the concentration of feedstock asphaltenes and/or coke-drum temperatures are too high. Excessive feedstock oxygen content can also induce its formation. 

Feedstocks come mainly from catalytic cracking. The catalyst system is sensitive to contaminants such as dienes and acetylenes or polar compounds such as water, oxygenates, basic nitrogen, organic sulfur, and chlorinated compounds, which usually require upstream treatment. 

The gasification reactor is a vertical, empty, steel pressure vessel with a refractory lining into which preheated feedstock and steam are introduced premixed with oxygen. Steam-to-oil weight ratio is 0.35 1 the oxygen-to-oil ratio is 1.05 1. 

Synthesis Gas Generation Routes. Any hydrocarbon that can be converted into a synthesis gas by either reforming with steam (eq. 4) or gasification with oxygen (eq. 5) is a potential feedstock for methanol. 

Chemical Processing. The use of oxygen in large-volume chemical and petrochemical manufacture is weU-estabHshed as a result of advantages 3) and 4). Most oxidation reactions are catalytic many begin with a feedstock initially made catalyticaHy from methane or natural gas. 

Oxidation of cumene to cumene hydroperoxide is usually achieved in three to four oxidizers in series, where the fractional conversion is about the same for each reactor. Fresh cumene and recycled cumene are fed to the first reactor. Air is bubbled in at the bottom of the reactor and leaves at the top of each reactor. The oxidizers are operated at low to moderate pressure. Due to the exothermic nature of the oxidation reaction, heat is generated and must be removed by external cooling. A portion of cumene reacts to form dimethylbenzyl alcohol and acetophenone. Methanol is formed in the acetophenone reaction and is further oxidized to formaldehyde and formic acid. A small amount of water is also formed by the various reactions. The selectivity of the oxidation reaction is a function of oxidation conditions temperature, conversion level, residence time, and oxygen partial pressure. Typical commercial yield of cumene hydroperoxide is about 95 mol % in the oxidizers. The reaction effluent is stripped off unreacted cumene which is then recycled as feedstock. Spent air from the oxidizers is treated to recover 99.99% of the cumene and other volatile organic compounds. 

Improved feedstock pretreatment is important to minimize catalyst consumption and reduce subsequent spent-catalyst handling requirements. Selective hydrogenation of dienes can be used to reduce acid consumption, both in HF and H2SO4 alkylation (29). More effective adsorptive treating systems have been appHed to remove oxygen-containing contaminants that are frequently introduced in upstream processing steps. 

Manufacture. Titanium chloride is manufactured by the chlorination of titanium compounds (1,134—138). The feedstocks usually used are mineral or synthetic mtile, beneficiated ilmenite, and leucoxenes. Because these are all oxygen-containing, it is necessary to add carbon as well as coke from either coal or fuel oil during chlorination to act as a reducing agent. The reaction is normally carried out as a continuous process in a fluid-bed reactor (139). The bed consists of a mixture of the feedstock and coke. These are fluidized by a stream of chlorine iatroduced at the base (see Fluidization). The amount of heat generated in the chlorination process depends on the relative proportions of CO2 or CO that are formed (eqs. 1 and 2), and the mechanism that... 

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