F Chloroethane

Carbon tetrachloride, 0322 Carbon tetrafluoride, 0349 Carbon tetraiodide, 0525 f 1-Chlorobutane, 1637 f 2-Chlorobutane, 1638 f Chlorocyclopentane, 1923 f l-Chloro-l,l-dilluoroethane, 0731 Chlorodilluoromethane, 0369 f Chloroethane, 0848 Chloroform, 0372 f Chloromethane, 0432 f l-Chloro-3-methylbutane, 1986 f 2-Chloro-2-methylbutane, 1987 f Chloromethyl ethyl ether, 1246 f Chloromethyl methyl ether, 0850 f l-Chloro-2-methylpropane, 1639 f 2-Chloro-2-methylpropane, 1640 f 1-Chloropentane, 1988 f 1-Chloropropane, 1243 f 2-Chloropropane, 1244 f l-Chloro-3,3,3-trifluoropropane, 1127 1,2-Dibromoethane, 0785 Dibromomethane, 0395... 

Lane, R.W., Riddle. B.L. Borzelleca, J.F. (1982) Effects of 1,2-dichloroethane and 1,1,1-tri-chloroethane in drinking water on reproduction and development in mice. Toxicol, appl. Pharmacol., 63, 409-421... 

Infante, P.F. Tsongas, T.A. (1982) Mutagenic and oncogenic effects of chloromethanes, chloroethanes, and halogenated analogues of vinyl chloride. Environ. Sci. Res., 25, 301-327... 

Chlorinated ethanes could be divided into two types, those that could carry the chlorine atom chain and those that could not. 1,2-Dichloroethane 1, 1,1,2-trichloroethane 10, 1,1,1-trichloroethane 11, 1,1,2,2-tetrachloroethane 12, 1,1,1,2-tetra-chloroethane 13, and 1,1,1,2,2-pentachloroethane 14 all decomposed with enhanced rates by a chlorine atom chain mechanism. Ethyl chloride and 1,1-dichloroethane 4 did not. The reason for the latter has been explained. Ethyl chloride gave likewise the radical 15 which could not carry the chain. In 1949, in a paper with the late Professor P. F. Onyon,7 the observations made up to that time were correlated and a number of predictions were made (Table 1). In later work all the predictions were shown to be true. 

Under analogous conditions l/f-indole-3-thiol reacts with l-bromo-2-chloroethane to give A, -divinylindole 221 in... 

Garrot B., Couderc G., Simonot-Grange M.-H., and Stoeckli F., Co-adsorption of 1,2-dichloroethane and l-bromo,2-chloroethane on zeolite ZSM-5 ftom the liquid and vapour phases, using the Myers-Prausnitz-Dubinin model, Microporous and Mesoporous Materials 52 (2002) pp. 199-206. 

CHLOROETHANAL (107-20-0) Combustible liquid (flash point 190°F/87°C). Violent reaction with chlorine, bromine, fluorine, ketones, strong oxidizers, strong acids, water. May form a water-soluble polymer in storage. 

CHLOROETHANE (75-00-3) Flammable gas (flash point -58°F/-50°C). Reacts slowly with water, steam, or hot surfaces, producing hydrochloric acid and hydrogen chloride gas. Contact with alkali metals, aluminum, lithium, magnesium, sodium, potassium, zinc may cause fire and explosions. Attacks common metals in the presence of moisture. Attacks some plastics and rubber. Flow or agitation of substance may generate electrostatic charges due to low conductivity. 

Ethylene Dichlorlde. 1,2-Dichloroethane syrn-di -chloroethane ethylene chloride EDO Dutch liquid Bro-tide. C2H,CI2 mol wt 98.96. C 24.27%, H 4.07%, Cl 71.66%. CICHjCHjCl. Made from ethylene and chlorine also from acetylene and HCI Reilstein 1, 4 0918). Manuf Faith, Keyes Clark s Industrial Chemicals, F. A. Lowen-htim, M. K. Moran, Eds. (Wiley -Interscience, New York, 4th ed., 1975) pp 392-396. Toxicity data Smyth el aL, Am. Ind. Hyg. Assoc. J. 30,470 (1969). Review of carcinogenicity studies I ARC Monographs 20, 429-444 (1979). 

In a review of compounds identified in tobacco and tobacco smoke, Philip Morris, Inc. in 1963 (2939) listed seven halogenated compounds Cl, bromomethane, chlo-romethane, chloroethane, bromoethane, Endrin , and TDE. Stedman (3797) in 1968 listed 950 identified compounds in tobacco and tobacco smoke, of these only seventeen compounds were halogen-containing. Cl, F, and I were identified in tobacco, along with tobacco residues of methylene bromide, l,l,l-trichloro-2-(4,4 -dichlorodiphenyl)ethane (DDT), Dieldrin , Dyrene , Endrin , TDE, Telodrin , Thiodan , Toxaphene , Trichlorfon , and Diclone . o-Chloroaniline,... 

Difluoro-2-chloroethane triplet for carbon-1 coupling to two F atoms (V > 180 Hz) triplet for carbon-2 coupling to two F atoms ( J 40 Hz). 

Properties Lt. straw clear to hazy liq. sol. in IPA, ethanol, 1,1,1-chloroethane, xylene, toluene disp. in min. spirits, hydrocarbon and chlorinated hydrocarbon soivs. insol. in water m.w. 11,500 sp.gr. 1.03 dens. 8.5 Ib/ l vise. 6500 cSt f.p. -50 F b.p. > 200 C flash pt. (PMCC) > 93 C nonionic 100% act., 31% silicone Toxicology Essentially nontoxic may cause temper eye discomfort, mild redness, dryness on direct contact no injury likely from relatively short exposure by inh. swallowing Ig. amts, may cause digestive discomfort TSCA listed... 

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