Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Esters, detection

Unexpectedly strong intermolecular hydrogen bonding has been reported by IR spectroscopic studies for tetrahydro-4,7-phenanthroline-l,10-dione-3,8-dicarboxylic acids, which exist in the oxo-hydroxy form 165 in both solid state and in solution [78JCS(CC)369].Tlie conclusion was based on comparison of B-, C-, and D-type bands for 165 and their dimethyl esters (detection of hydrogen bonding) and on analysis of IR spectra in the 6 /xm region (pyridine- and pyridone-like bands). [Pg.100]

Beagents for the derivatization of alcohols show variable reactivity and those containing an acid chloride or nitrile group require anhydrous conditions. DMOQ-CONj is the only reagent that reacjts to a significant extent with tertiary alcohols. The product of the reaction is a carbamic acid ester. Detection limits for alcohol derivatives are also frequently nc e than modest... [Pg.446]

Other waxes have not been studied to the same extent as beeswax. They derive from a variety of plant, animal and also mineral sources, as described in Chapter 1, where more detailed information on their chemical composition is reported. HTGC/MS analysis after solvent extraction has been successfully used to identify spermaceti, candellila and Japan waxes which have been used in the manufacture of works of art [37]. In particular, in the case of spermaceti wax it has been possible to understand the structure of the various isomers of even-numbered esters ranging from C26 to C34, as well as odd-numbered esters detected in low amounts. The mass spectra obtained demonstrated for the first time that spermaceti esters are mainly composed of hexade-canol and octadecanol moieties associated with a range of FAs containing 10 20 carbon atoms. [Pg.200]

The use of GLC-EC has become a well accepted method for the analysis of ABA as described by Saunders (37). The purity of ABA (methyl ester) detected on this system may be confirmed by forming the trans-ABA isomer methyl ester in sunlight while in acetone and rerunning the sample. We have found that prep-HPLC is useful in the purification of plant extracts for ABA analysis by GLC-ED (45). Another unique identification method takes advantage of the extreme cotton effect that ABA exhibits. The degree of optical rotation can be used for quantification of ABA if the sample is highly purified (37). [Pg.234]

Every organic molecule absorbs infrared light at one wavelength or another. When an IR detector is used, the mobile phase chosen must not be self-absorbent at the required wavelength. Hexane, dichloromethane and acetonitrile are suitable mobile phases for ester detection whereas ethyl acetate is not. The sensitivity is no greater than that of refractive index detectors. The most common wavelengths are given in Table 6.1. [Pg.106]

In general, results from NMR analysis In all media Indicate that the polyester to MDI molar ratio remained roughly constant In aging media which contained water since the degraded polyester Is not extracted. In addition, more change occurred In the molar ratio of polyester to MDI In polymer A than In polymer B during aging. In Table II, the amount of methyl ester (detectable by NMR analysis) Is shown to Increase with methanol content In Isooctane solutions. This provides evidence that the extent of chain scission Is proportional to methanol content. [Pg.185]

Hashizume, K., Nanya, J., Toda, C., Yasui, T., Nagano, H., and Kojima, N., Phthalate esters detected in various water samples and biodegradation of phthalates by microbes isolated from river water, Biol. Pharm. Bull, 25, 209-214, 2002. [Pg.1150]

Originates through microbial activity. The hexakisphosphate and lower esters detected in soils and aquatic sediments. [Pg.403]

B. Narasin methyl ester detected with 3% vanil-lin-0.5% sulfuric acid spray, I00°C... [Pg.245]

All data are expressed as per cent of total fatty acid esters detected in gas chromatography. For the P or y position the values refer to per cent of fatty acids found in that position, whereas for the total fatty acids the values refer to per cent of total fatty acids from the combined P and y positions. [Pg.197]


See other pages where Esters, detection is mentioned: [Pg.194]    [Pg.209]    [Pg.231]    [Pg.22]    [Pg.33]    [Pg.144]    [Pg.239]    [Pg.252]    [Pg.379]    [Pg.238]    [Pg.251]    [Pg.164]    [Pg.96]    [Pg.486]    [Pg.355]    [Pg.120]    [Pg.292]    [Pg.302]    [Pg.45]    [Pg.164]    [Pg.262]   
See also in sourсe #XX -- [ Pg.176 , Pg.664 ]




SEARCH



Esters artificial detection

Esters, detection hydrolysis

Esters, detection identification

Esters, detection paper chromatography

Fatty acid methyl ester detection

Nitro esters, detection

Phosphate esters detection

Simple Esters Occurrence and Detection

© 2024 chempedia.info