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Energy balances with variable

Tran and Mujtaba (1997), Mujtaba et al. (1997) and Mujtaba (1999) have used an extension of the Type IV- CMH model described in Chapter 4 and in Mujtaba and Macchietto (1998) in which few extra equations related to the solvent feed plate are added. The model accounts for detailed mass and energy balances with rigorous thermophysical properties calculations and results to a system of Differential and Algebraic Equations (DAEs). For the solution of the optimisation problem the method outlined in Chapter 5 is used which uses CVP techniques. Mujtaba (1999) used both reflux ratio and solvent feed rate (in semi-continuous feeding mode) as the optimisation variables. Piecewise constant values of these variables over the time intervals concerned are assumed. Both the values of these variables and the interval switching times (including the final time) are optimised in all the SDO problems mentioned in the previous section. [Pg.316]

By combining the total energy balance with simple thermodynamic relations between state variables, a transport equation that must be satisfied by the entropy density field ps is obtained. [Pg.62]

Compute a new set of values of the Vj tear variables one at a time, starting with V3, from an energy-balance equation that is obtained by combining Eqs. (13-72) and (13-74), ehminating Lj-i and Lj to give... [Pg.1284]

In the case of adiabatic flow we use Eqs. (9-1) and (9-3) to eliminate density and temperature from Eq. (9-15). This can be called the locally isentropic approach, because the friction loss is still included in the energy balance. Actual flow conditions are often somewhere between isothermal and adiabatic, in which case the flow behavior can be described by the isentropic equations, with the isentropic constant k replaced by a polytropic constant (or isentropic exponent ) y, where 1 < y < k, as is done for compressors. (The isothermal condition corresponds to y= 1, whereas truly isentropic flow corresponds to y = k.) This same approach can be used for some non-ideal gases by using a variable isentropic exponent for k (e.g., for steam, see Fig. C-l). [Pg.273]

The RNG model provides its own energy balance, which is based on the energy balance of the standard k-e model with similar changes as for the k and e balances. The RNG k-e model energy balance is defined as a transport equation for enthalpy. There are four contributions to the total change in enthalpy the temperature gradient, the total pressure differential, the internal stress, and the source term, including contributions from reaction, etc. In the traditional turbulent heat transfer model, the Prandtl number is fixed and user-defined the RNG model treats it as a variable dependent on the turbulent viscosity. It was found experimentally that the turbulent Prandtl number is indeed a function of the molecular Prandtl number and the viscosity (Kays, 1994). [Pg.321]

If the batch reactor operation is both nonadiabatic and nonisothermal, the complete energy balance of equation 12.3-16 must be used together with the iiaterial balance of equation 2.2-4. These constitute a set of two simultaneous, nonlincmr, first-flijer ordinary differential equations with T and fA as dependent variables and I as Iidependent variable. The two boundary conditions are T = T0 and fA = fAo (usually 0) at I = 0. These two equations usually must be solved by a numerical procedure. (See problem 12-9, which may be solved using the E-Z Solve software.)... [Pg.307]

In principle, any type of process model can be used to predict future values of the controlled outputs. For example, one can use a physical model based on first principles (e.g., mass and energy balances), a linear model (e.g., transfer function, step response model, or state space-model), or a nonlinear model (e.g., neural nets). Because most industrial applications of MPC have relied on linear dynamic models, later on we derive the MPC equations for a single-input/single-output (SISO) model. The SISO model, however, can be easily generalized to the MIMO models that are used in industrial applications (Lee et al., 1994). One model that can be used in MPC is called the step response model, which relates a single controlled variable y with a single manipulated variable u (based on previous changes in u) as follows ... [Pg.569]

There are 12 equations in all (overall material and energy balances side A and B energy balances coil 1 to 8 energy balances) and 36 variables. However, the heat transfer coefficients are not known with any great accuracy. Further, both the side and coil heat transfer coefficients depend on the fire-box temperature. It is therefore necessary to calculate values for the heat transfer coefficients from the data. This effectively reduces the number of independent equations to 11. [Pg.254]

The states of a dynamic system are simply the variables that appear in the time differential. For example, if we have a chemical reactor in which the concentration of reactant Ca and the temperature T change with time, the material balance for component A and the energy balance would give two differential equations ... [Pg.551]

In order to evaluate P2 we need to consider how the governing equations for mass and energy balance themselves vary with changes in the variables. In the case of the present model this means evaluating various partial derivatives of (5.1) and (5.2) with respect to a and 0. Before proceeding, however, we should take a look at the elements of the Jacobian matrix evaluated for Hopf bifurcation conditions ... [Pg.116]

The ordinary differential equations describing a steady-state adiabatic PFR can be written with axial length z as the independent variable. Alternatively the weight of catalyst w can be used as the independent variable. There are three equations a component balance on the product C, an energy balance, and a pressure drop equation based on the Ergun equation. These equations describe how the molar flowrate of component C, temperature T, and the pressure P change down the length of the reactor. Under steady-state conditions, the temperature of the gas and the solid catalyst are equal. This may or may not be true dynamically ... [Pg.255]

Interaction is unavoidable between the material and energy balances in a distillation column. The severity of this interaction is a function of feed composition, product specification, and the pairing of the selected manipulated and controlled variables. It has been found that the composition controller for the component with the shorter residence time should adjust vapor flow, and the composition controller for the component with the longer residence time should adjust the liquid-to-vapor ratio, because severe interaction is likely to occur when the composition controllers of both products are configured to manipulate the energy balance of the column and thereby "fight" each other. [Pg.252]

The temporal change of the molar quantity of the element sulfur in the film on a fluidized-bed particle is caused by inflow and outflow of the material. This mass balance is needed only once, since the fluidized-bed particles and, thus, the liquid films on the particles are regarded as ideally mixed. The condition of the ideal mixing leads to the fact that with the mass and energy balance of the film, the average variables of state of the gas in the respective driving force approximations find the following form... [Pg.469]

As demonstrated in Chapters 3-5, the variables of the material balance of an integrated process system can themselves exhibit a dynamic behavior with up to three time scales. As such, it is intuitive that, when considering both the energy-balance and the material-balance equations, the dynamics of integrated process systems can span several (i.e., more than three) time scales. For clarity this aspect was not directly accounted for in the theoretical analysis presented above. We utilize the following examples to illustrate the concepts developed so far, as well as to confirm this observation. [Pg.151]

A model for transient simulation of radial and axial composition and temperature profiles In pressurized dry ash and slagging moving bed gasifiers Is described. The model Is based on mass and energy balances, thermodynamics, and kinetic and transport rate processes. Particle and gas temperatures are taken to be equal. Computation Is done using orthogonal collocation In the radial variable and exponential collocation In time, with numerical Integration In the axial direction. [Pg.359]

In the present work we will deal with all the above problems and provide a unified framework to deal with the error correction for static or dynamic systems using multicomponent mass and energy balances. The topological character of the complex process is exploited for an easy classification of the measured and unmeasured variable independently of the linearity or nonlinearity of the balance equations. [Pg.155]

Essential relations describing each subsystem are overall equations for mass balance, for energy balance, for performance, and for costing in terms of performance. Presently available cost trends (17) in terms of capacity parameters (e.g. area, mass rate, power,. ..) are suitable costing equations to start with. They may be implemented to include the influence of variables such as pressure, temperature or efficiency whenever sufficient data are available. [Pg.218]

The energy balances are not solved in the same manner as the component or total material balances. With some solution methods, they are simultaneously solved with other MESH equations to get the independent cc umn variables in others they are used in a more limited manner to get a new set of total flow rates or stage temperatures. [Pg.143]

For every side product, a withdrawal factor is added to the independent variables. With it, a specification function joins the energy balances in the independent functions. These and the energy balances are the functions of a Newton-Raphson method, and whenever they are calculated (as in filling the Jacobian), a pass must be made through the calculations of the compositions and temperatures. [Pg.178]

A major limitation of the present work is that it deals only with well-defined (and mostly unidirectional) flow fields and simple homogeneous and catalytic reactor models. In addition, it ignores the coupling between the flow field and the species and energy balances which may be due to physical property variations or dependence of transport coefficients on state variables. Thus, a major and useful extension of the present work is to consider two- or three-dimensional flow fields (through simplified Navier-Stokes or Reynolds averaged equations), include physical property variations and derive lowdimensional models for various types of multi-phase reactors such as gas-liquid, fluid-solid (with diffusion and reaction in the solid phase) and gas-liquid-solid reactors. [Pg.294]


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