Electrodeposition drying

Photocurable resins Water-thinnable resins Cathodic electrodeposition Drying oils... 

After the plates have been washed and dried thoroughly, they are pressed ia a preliminary operatioa to the desired thickness. Iadividual electrodes are thea cut from the sheets and a secondary pressing operation to final thickness is done. Often a secondary operation is required to remove sharp edges of electrodeposited 2iac electrodes. 

Germanium In situ STM studies on Ge electrodeposition on gold from an ionic liquid have quite recently been started at our institute [59, 60]. In these studies we used dry [BMIM][PF<3] as a solvent and dissolved Gel4 at estimated concentrations of 0.1-1 mmol 1 the substrate being Au(lll). This ionic liquid has, in its dry state, an electrochemical window of a little more than 4 V on gold, and the bulk deposition of Ge started several hundreds of mV positive from the solvent decomposition. Furthermore, distinct underpotential phenomena were observed. Some insight into the nanoscale processes at the electrode surface is given in Section 6.2.2.3. 

To check the efficacy of grease removal, the alkali solution is rinsed away or neutralised by dipping in dilute acid. If, after removal from the acid, the draining metal surface remains wetted evenly all over for 30-60 s (or until it dries by evaporation), hydrophobic soils have been removed. Traces of grease cause the surface to de-wet, and surface tension draws the water into separate droplets. This is the water-break test. Traces of grease which remain when the work is plated do not prevent electrodeposition, but are detrimental to adhesion and corrosion resistance. 

After rinsing and dry-off, the primer is applied. In most modern plants this means electrodeposition of the primer (Section 14.1). The most widely used primers are cathodic. The body shell is made the cathode and current flows between it and inert anodes in the electropaint bath. The paint is formulated so that the resin is basic and, when neutralised with an acid such as lactic acid, becomes positively charged. The most widely used resins are epoxy-amine adducts ... 

Measurements of " Th in sediment samples (Aller and Cochran 1976 Cochran and Aller 1979) used much the same approach as outlined above. In this case, the dried sediment sample ( 10 g) was leached with strong mineral acid (HCl) in the presence of a yield monitor (generally Th, an artificial Th isotope resulting from the decay of Th that is produced by neutron capture on Th). Thorium was separated from U and purified by ion exchange chromatography, and electrodeposited onto stainless steel planchets. Counting and determination of " Th activity followed the procedure outlined above. 

Air Cellulose filter dry ashed, dissolved in HNO3/HF, H202/HCI04, purified with anion exchange, TRU-spec columns followed by electrodeposition. a -Spectroscopy 0.023 pCi/sample 102% Goldstein et al. 1997... 

Soil Dry ash, digest in HNO3/HCI, anion exchange, Ca-oxalate and Fe (OH)2 coprecipitation, anion exchange, electrodeposition a -Spectroscopy 27 pCi/g 75-92% Sanchez and Singleton 1996... 

Batley [780] found that in situ deposition of lead and cadmium on a mercury-coated tube was the more versatile technique. The mercury film, deposited in the laboratory, is stable on the dried tubes which are used later for field electrodeposition. The deposited metals were then determined by electrothermal AAS. 

Batley [28] examined the techniques available for the in situ electrodeposition of lead and cadmium in estuary water. These included anodic stripping voltammetry at a glass carbon thin film electrode and the hanging drop mercury electrode in the presence of oxygen and in situ electrodeposition on mercury coated graphite tubes. Batley [28] found that in situ deposition of lead and cadmium on a mercury coated tube was the more versatile technique. The mercury film, deposited in the laboratory, is stable on the dried tubes which are used later for field electrodeposition. The deposited metals were then determined by electrothermal atomic absorption spectrometry, Hasle and Abdullah [29] used differential pulse anodic stripping voltammetry in speciation studies on dissolved copper, lead, and cadmium in coastal sea water. 

Hull cell PHYS CHEM An electrodeposition cell that operates within a simultaneous range of known current densities. hoi, sel humectant chem A substance which absorbs or retains moisture examples are glycerol, propylene glycol, and sorbitol used in preparing confectioneries and dried fruit. hyu mek-tont ... 

All paints were electrodeposited on SAE 1010 bare steel paint test panels to yield 20fim dry film thickness, and were baked to yield fully crosslinked, solvent resistant films. 

Bones spiked with tracer dry ashed, Th coprecipitated with Fe-hydrox1de, cleaned up by complexatlon and solvent extracted and electrodeposited. 

Figure 6.2-12 Cyclic voltammogram of 0.1 - 1 mmol dm Geb on gold in dry [BMIMj PFg , starting at-500 mV towards cathodic (a) and anodic (b) regime. Two quasireversible (E, and E2) and two apparently irreversible (E4 and E5) diffusion-controlled processes are observed. E3 is correlated with the growth of two-dimensional islands on the surface, E4 and E5 with the electrodeposition of germanium, Ej with gold step oxidation, and E, probably with the iodine/iodide couple. Surface area 0.5 cm (picture from [59] - with permission of the Peep owner societes).

PTFE aqueous dispersions are applied onto metal substrates by spraying, dipping, flow coating, electrodeposition, or coagulation to provide chemical resistance, nonstick, and low-friction surfaces. Nonstick cookware and bakeware are made from dispersion specifically formulated for that purpose with the use of a primer for the metal. After coating, the parts are dried and sintered. 

A second, equally powerful means to prepare such materials relies on traditional inorganic polymerization tools, most notably sol-gel polymerization.24 25 A number of excellent reviews have appeared on this subject as well.5,12,17 In sol-gel processing, the functional monomer [i.e., an organoalkoxysilane such as 3-aminopropyltrimethox-ysilane (APTMS)] is combined with the cross-linking agent [i.e., a tetrafunctional alkoxysilane such as tetramethoxysilane (TMOS) or tetraethoxysilane (TEOS)], a catalyst (such as hydrochloric acid or ammonia), and the template molecule. The resultant sol can be left to gel to form a monolith, which can then be dried, sieved, and extensively washed to remove the template. Alternatively, the sol can be spin coated, dip coated, or electrodeposited on a surface to yield a thin film, which can be subsequently washed with a solvent to remove the template and yield the imprinted cavities. 

Ge(lll) bilayers can be obtained by electrodeposition in the dry ionic liquid [BMIMJPF6 containing GeT as a source of germanium [94], This ionic liquid has an electrochemical window of a little more than 4 V on Au(lll). However, stable... 

In this chapter we would like to present some plating protocols for the electrodeposition of aluminum, lithium, tantalum and zinc from different ionic liquids. These recipes have been elaborated in our laboratories and should allow the beginner to perform his first electrodeposition experiments. For aluminum we give four different recipes in order to show that the ionic liquid itself can strongly influence the deposition of metals. In the case of tantalum the deposition of the metallic phase is not straightforward as, in unstirred solutions, the more nonstoichiometric tantalum halides form the higher the current density for electrodeposition. Apart from the zinc deposition all experiments should be performed at least under dry air. 

Electrodeposition experiments were carried out in the apparatus described earlier (4). The equipment is illustrated schematically in Figure 2. The circuit also included a strip chart recorder and integrator. A variety of metals were coated at the cathode using the standard condition of 200 V for 2 min. The cathode area was held constant at 7.3 cm, unless otherwise specified. After deposition, the metal test pieces were rinsed with deionized water, dried and weighed to determine the amount of polymer deposited. The number of coulombs was measured simultaneously in order to calculate current efficiencies. Results were analyzed and compiled in a simple computer program. A typical printout is shown below for a system with poor current cutoff (Table V ), and good cutoff (Table VI). The set of metals used as substrate are listed below. 

Bones Spiked sample dry ashed cleanup by coprecipitation, solvent extraction and electrodeposition a-Spectrometry (isotopic quantification) 0.03 pg/ sample 60-93% Singh and Wrenn 1988 Singh et al. 1984... 

Air Spiked air particulate dry and wet ashed dissolution coprecipitation with iron hydroxide and Ca oxalate, purification by solvent extraction and electrodeposition onto platinum a-Spectrometry (isotope quantification) 0.02 dpm/L for in solution No data Singh and Wrenn 1988... 

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