Electrical properties, specific conductivity

The bulk (or volume)-specific resistance is one of the most useful general electrical properties. Specific resistance is a physical quantity that may vary more than 10 in readily available materials. This unusually wide range of conductivity allows wide variety of electrical applications. Conductive materials, such as copper, have specific resistance values of about 10 fl-cm, whereas good insulators such as polytetrafluoroethylene and LDPE have values of about 10 fl-cm. Specific resistance is calculated from the following equation where R is the resistance in ohms, a is the pellet area in square centimeters, t is the pellet thickness in centimeter, and P is the specific resistance in ohm-centimeter ... 

Standard test method for rubber property-volume resistivity of electrically conductive and antistatic products Specification for electrical properties of conducting and antistatic products made from flexible polymeric material... 

T/6-Arene ruthenium and osmium offer specific properties for the reactivity of arene ligand. The activation toward nucleophiles or electrophiles is controlled mainly by the oxidation state of the metal (II or 0). Recently, from classic organometallic arene ruthenium and osmium chemistry has grown an area making significant contributions to the chemistry of cyclo-phanes. These compounds are potential precursors of organometallic polymers which show interesting electrical properties and conductivity. 

In practical terms, the electrical resistance measurements on conductive fibers/yams is always problematic due to their soft, flexible, and poor dimensional stabilities. Very few publications have reported research regarding electrical measurements on fibrous stmctures. Usually, the conventional method, in which crocodile clips are attached with a voltmeter, is used for this purpose. Crocodile clips hold the conductive fibers/yarns of specific length and then electrical resistance is measured on particular voltage values. However, the hard grip of crocodile clips damages any conductive coatings or creates internal cracks in the fibrous stmctures, which cause the permanent loss in electrical properties of conductive threads. Consequently, consistent results with crocodile clips cannot be obtained. 

The selection of a particular adhesive type is for reasons other than modulus and associated stress distrihution. This might be for example, specific adhesion, chemical resistance, setting speed, gap fill capability, durability, heat resistance, fire performance, electrical properties, thermal conductivity, colour, toxicity or price. Low modulus adhesives are used very successfully in low stress applications to accommodate differential thermal expansion in applications like bonding glass to aluminium in double glazing assembly. 

There are many additives employed in the plastics industry. Among the most versatile is carbon black. It is used to provide colour, opacity, protection from ultraviolet light, electrical properties, thermal conductivity, and even reinforcement. Advanced production methods have enabled carbon black suppliers to develop a wide range of carbon black grades that, in turn, provide plastics processors with additive selections geared to specific end-use properties. Selection of the proper carbon black is critical to successful end-use performance. Unlike some plastics additives, carbon black is not simply added to the mix. It must be dispersed into a resin system, and the quality of the dispersion is essential to performance. This chapter discusses the fundamentals of carbon black, its selection in plastics applications, and dispersion equipment and techniques. 

Rowell and co-workers [62-64] have developed an electrophoretic fingerprint to uniquely characterize the properties of charged colloidal particles. They present contour diagrams of the electrophoretic mobility as a function of the suspension pH and specific conductance, pX. These fingerprints illustrate anomalies and specific characteristics of the charged colloidal surface. A more sophisticated electroacoustic measurement provides the particle size distribution and potential in a polydisperse suspension. Not limited to dilute suspensions, in this experiment, one characterizes the sonic waves generated by the motion of particles in an alternating electric field. O Brien and co-workers have an excellent review of this technique [65]. 

Physical Properties. Most of the physical properties discussed herein depend on the direction of measurement as compared to the bedding plane of the coal. Additionally, these properties vary according to the history of the piece of coal. Properties also vary between pieces because of coal s britde nature and the crack and pore stmcture. One example concerns electrical conductivity. Absolute values of coal sample specific conductivity are not easy to determine. A more characteristic value is the energy gap for transfer of electrons between molecules, which is deterrnined by a series of measurements over a range of temperatures and is unaffected by the presence of cracks. The velocity of sound is also dependent on continuity in the coal. 

The specific electrical conductivity of dry coals is very low, specific resistance 10 ° - ohm-cm, although it increases with rank. Coal has semiconducting properties. The conductivity tends to increase exponentially with increasing temperatures (4,6). As coals are heated to above ca 600°C the conductivity rises especially rapidly owing to rearrangements in the carbon stmcture, although thermal decomposition contributes somewhat below this temperature. Moisture increases conductivity of coal samples through the water film. 

To design the optimal diffusion layer for a specific fuel cell system, it is important to be able to measure and understand all the parameters and characteristics that have a direct influence on the performance of the diffusion layers. This section will discuss in detail some of the most important properties that affect the diffusion layers, such as thickness, hydrophobicity and hydrophilicity, porosity and permeability (for both gas and liquids), electrical and thermal conductivity, mechanical properties, durability, and flow... 

Insulation Integrity. Insulation integrity is a function of an interlayer dielectric/passivant defined by specific electrical, mechanical and passivation properties. The D.C. electrical property of interest is the I-V characteristic which is used to deduce conductivity and breakdown field strength. The corresponding A.C. electrical property is dissipation factor. The pertinent mechanical and passivation properties are, respectively, pinhole density and performance rating as a diffusion barrier to Na" " and H2O. 

Because electronic and ionic conduction are so structure-sensitive, the simple rule-of-mixtures approach to estimating the conductivity and resistivity of composites is not normally of use. As a result, the conductivity of specific composites for specific applications must be experimentally determined. In the next two sections, we examine two examples of how composites can be used in electrical applications, and we describe the influence of each component on the electrical properties. The first example involves the electrical insulating properties of polymers, and the second one involves enhancing the electrically conducting properties of polymers. 

On the other hand, conductivity (cr) or specific conductance (reciprocal of resistivity p) is a material property that is normalized with respect to area, potential gradient, and time. It is expressed as the ratio of current density j (A cm-2) and electric field E (V cm-1). 

The specific conductance (k) is related to the solution s resistance (R) to the passage of electric current (the measured physical property) by the equation... 

Gallium(III) bromide is a hygroscopic, white solid which sublimes readily and melts at 122.5° to a covalent, dimeric liquid. The solid is ionic and its electrical conductivity at the melting point is twenty-three times that of the liquid.5 The vapor pressure of the liquid at T°K is given by the equation log p(mm.) = 8.554 — 3129/T and the heat of dissociation of the dimer in the gas phase is 18.5 kcal./mol.3 At 125° the liquid has the following properties 5,6 density, 3.1076 dynamic viscosity, 2.780 c.p. surface tension, 34.8 dynes/cm. and specific conductivity, 7.2 X 10-7 ohm-1 cm.-1 Gallium(III) bromide readily hydrolyzes in water and forms addition compounds with ligands such as ammonia, pyridine, and phosphorus oxychloride. 

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