Dyeing dyestuff processing

In producing the developed colours, the direct dyestuff is diazotized on tile fibre, and the diazonium compound couples with a suitable developer. With the coupled dyes the process is reversed. The cotton is dyed with a direct dye containing an amino or hydroxyl group and the dyed fibre is then treated with a solution of a diazotized base. An example is Benzo Para Deep Brown G (C.I. direct brown 152), (24),... 

Benzo[/]quinoxalines have been patented for use as catalysts for the silver dye bleaching process and as dyestuff intermediates. The latter compounds have been derived by nitration, sulfonation, or chlorosulfona-tion of either 2,3-dioxo- or 2,3-dichlorobenzo[/]quinoxaline. 

In the dyestuff industry, anthraquinone still ranks high as an intermediate for the production of dyes and pigments having properties unattainable by any other class of dyes or pigments. Its cost is relatively high and will remain so because of the equipment and operations involved in its manufacture. As of May 1991, anthraquinone sold for 4.4/kg in ton quantities. In the United States and abroad, anthraquinone is manufactured by a few large chemical companies (62). At present, only two processes for its production come into consideration manufacture by the Friedel-Crafts reaction utilizing benzene, phthahc anhydride, and anhydrous aluminum chloride, and by the vapor-phase catalytic oxidation of anthracene the latter method is preferred. 

Textile finishing includes various efforts to improve the properties of textile fabrics, whether for apparel, home, or other end uses. In particular, these processes are directed toward modifying either the fiber characteristics themselves or the gross textile end properties. Such modifications may be chemical or mechanical in nature. One modification that is not covered in this article relates to the dyeing of textiles and the dyestuffs employed for fibers however, areas that involve chemical finishing designed to modify the normal dye receptivity and the growing use of enzyme treatments are included. 

In mordant dyes, phenols, naphthols, and enolizable carbonyl compounds, such as pyrazolones, are generally the couplers. As a rule, 2 1 metal complexes are formed ia the afterchroming process. A typical example of a mordant dye is Eriochrome Black T (18b) which is made from the important dyestuff iatermediate nitro-l,2,4-acid, 4-amiQO-3-hydroxy-7-nitro-l-naphthalenesulfonic acid [6259-63-8]. Eriochrome Red B [3618-63-1] (49) (Cl Mordant Red 7 Cl 18760) (1, 2,4-acid — l-phenyl-3-methyl-5-pyrazolone) is another example. The equiUbrium of the two tautomeric forms depends on the nature of the solvent. 

The IRCA. Solvent Process, Dye 6, Technical Bulletin, Geigy Dyestuffs, Geigy Chemical Corp., Dec. 1960. 

Anthraquinone dyes are derived from several key compounds, ie, dye intermediates. Production of these dye intermediates often requires sophisticated production processes and a large amount of investment in plant constmction. The competitiveness of final products, dyestuffs, depends on that of the intermediates, ie, quaUty, cost, and availabiUty. 

Preparation of Dispersion. The reduction process is a two-phase reaction between soluble reducing agent and insoluble dye particles, and therefore the rate of reduction is influenced by the particle size distribution of the dye dispersion. The smaller the particle size the greater the surface area and hence the more rapid the reduction process. However, if the particles are too small, migration will occur in continuous dyeing. It is therefore extremely important to control the size and range of particle size and this is a closely guarded piece of dyestuff manufacturers know-how. 

There are many completely automated computer-controUed exhaust dyehouses. Some firms have a no-add procedure in the dyehouse by which the dyer loads the fabric or yam, weighs the dye, punches a button, and lets the computer take over the entire process. This procedure ensures a constant dyeing cycle and the only variables are the dye index of the fiber or the quaHty of the dyestuff. 

Paper may be colored by dyeing the fibers in a water suspension by batch or continuous methods. The classic process is by batch dyeing in the beater, pulper, or stock chest. Continuous dyeing of the fibers in a water suspension is adaptive to modem paper machine processes with high production speeds in modem mills. Solutions of dyestuffs can be metered into the high density or low density pulp suspensions in continuous operation. 

Paper may also be colored by surface appHcation of dyestuff solutions after the paper has been formed and dried or partially dried by utilizing size-press addition, calendar staining, or coating operations on the paper machine. In addition, paper may be colored in off-machine processes by dip dyeings or absorption of dyestuff solution and subsequent drying, such as for decorative crepe papers. 

The metering and addition of dyestuff solutions is critical to successhil operation of continuous dyeing. It is also just as critical to meter other components of the process including pulp, broke, fiUers, size, alum, fixing agents, retention aids, wet-strength resins, and other additions that affect dyeing. 

In 1980, approximately 111,000 t of synthetic organic dyestuffs were produced in the United States alone. In addition, another 13,000 t were imported. The largest consumer of these dyes is the textile industry accounting for two-thirds of the market (246). Recent estimates indicate 12% of the synthetic textile dyes used yearly are lost to waste streams during dyestuff manufacturing and textile processing operations. Approximately 20% of these losses enter the environment through effluents from wastewater treatment plants (3). 

After the second World War, German firms manufacturing indigotin faced serious competition from Knglish and American dyestuff companies. To counteract this, the Germans developed continuous operations for manufacturing the dye. However, because of the complexity of the equipment and the operations (126), the batch process is still the preferred manufacturing method. 

Extraction or rather leaching of colourants is the first and a very important step in the analytical procedure for the analysis of natural dyes. The chemical composition of extracts from historical materials depends on many factors, such as the source of natural dyes, the technological procedure of their production, storage conditions over the centuries, ageing processes and extraction conditions. The choice of the extraction method depends on the properties of the components and the matrix from which they are isolated, as well as on the mechanism of dyeing with the particular dyestuff. In this regard, they are usually divided into three groups direct, vat and mordant dyestuffs. 

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