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Dispersion plain

In this chapter, the polymerization methods used for the production of uniform latex particles in the size range of O.I-lOO /Ltm are described. Emulsion, swollen emulsion, and dispersion polymerization techniques and their modified forms for producing plain, functionalized, or porous uniform latex particles are reviewed. The general mechanisms and the kinetics of the polymerization methods, the developed synthesis procedures, the effect of process variables, and the product properties are discussed. [Pg.189]

The factors 4 and 4 accormt for the heterogeneity of the interface. The interfacial flux conditions. Equations (6.56) and (6.57), can be straightforwardly applied at plain interfaces of the PEM with adjacent homogeneous phases of water (either vapor or liquid). However, in PEFCs with ionomer-impregnated catalyst layers, the ionomer interfaces with vapor and liquid water are randomly dispersed inside the porous composite media. This leads to a highly distributed heterogeneous interface. An attempt to incorporate vaporization exchange into models of catalyst layer operation has been made and will be described in Section 6.9.4. [Pg.403]

One-Step Activation Process. In a one-step activation process, the sensitizing and nucleating solutions are combined into one solution. It is assumed that when this solution is made up, it contains various Sn-Pd chloride complexes (24). These complexes may subsequently transform into colloidal particles of metallic Pd or a metallic alloy (Sn/Pd) to form a colloidal dispersion (19,28). This dispersion is unstable. It may be stabilized by addition of an excess of Sn ions. In this case, Pd particles adsorbed on the nonconductor surface are surrounded by Sn ions. The latter must be removed by solubilizing before electroless plating so that the catalytic Pd on the surface will become exposed, freely available, to subsequent plating. An example of such a solubilizing solution is a mixture of fluoroboric and oxalic acids in a dilute solution, or just plain NaOH or HCl. [Pg.155]

Most typically organizational teams comprise a number of people who have agreed to collaborate on a particular task who come together from time to time to plan and co-ordinate their activities. They will all probably have several, perhaps many, other responsibilities or so-called team memberships. This kind of team might be more appropriately called a collaborative network or a dispersed team rather them just plain team which could have misleading connotations. [Pg.191]

Dihydrobenzo[6]thiophene-2-carboxylic acid has been resolved212 the levorotatory enantiomer exhibits a plain negative rotatory dispersion curve which allows it to be assigned a D-configura-tion.218 The corresponding 3-carboxylic acid could not be resolved.212... [Pg.203]

Fig. 2.61 Cross-sectional views of a single drop of a water-dispersible red dye between sections of plain agar from Petri dishes to demonstrate the natural diffusion of nutrients through gels containing major fractions of water... Fig. 2.61 Cross-sectional views of a single drop of a water-dispersible red dye between sections of plain agar from Petri dishes to demonstrate the natural diffusion of nutrients through gels containing major fractions of water...
Ansari, A.A., Singh, I.B., Tobschall, H.J., 2000. Importance of geomorphology and sedimentation processes for metal dispersion in sediments and soils of the Ganga plain identification of geochemical domains. [Pg.476]

Studies of the optical rotatory dispersion of the transferrins and their metal complexes have not only shown important differences between the two forms of the proteins but also have afforded penetrating insight into the possible groups involved in chelation of the metal and in the structure of the complex (128, 129). These authors studied both chicken ovotransferrin and human serum transferrin and obtained essentially identical results with both proteins. Metal-free ovotransferrin had a plain negative rotatory dispersion between 300 and 675 mjj. with a specific rotation,... [Pg.175]

Dramatic change in the ORD occurs upon enzymatic reduction with NADPH and adrenodoxin reductase under anaerobic conditions as shown in Fig. 4. The dispersion displays a fairly plain pattern in the visible range, although the peak of the principal effect appears to shift to shorter wave length, whereas the peak near 350 mp is not affected. [Pg.13]

ABA absorbs ultraviolet with maxima at 240 nm (e 2.1 x 104, a shoulder peak), 260 nm (e 2.6 x 104), and 320 nm (e 50) in an acidic methanol solution.590 Irradiation with UV with a wavelength shorter than 305 nm isomerizes the 2-(Z)-double bond to (E) to give an equilibrium mixture of ABA and its 2-( )-isomer with a ratio of 1 1, and also causes decomposition of ABA to unidentified compounds by the excitation of the 7t-7t transition of the side chain and the enone groups. ABA has a strong optical activity, and its specific optical rotation is +430° in an acidic methanol solution.591 In the optical rotatory dispersion (ORD)591 and the circular dichroism (CD) spectra,558 ABA shows a positive Cotton effect from 300 to 200 nm. Phaseic acid and dihydrophaseic acid and its epimer, which did not have the enone group, show a small specific optical rotation with a minus value and also a negative plain curve in the ORD. [Pg.56]

Polystryrenesulfonates (PSSs) can be analyzed easily by CE in plain silica capillaries, because they do not interact with the surface and are commercially available with low dispersities and different molecular masses. As early as 1992 Poli and Schure [23] showed the advantages of CE separation compared to conventional techniques like SEC. The behavior of PSSs in CE has also been studied by Minarik et al. [24], Cottet et al. [25] and Clos et al. [26]. [Pg.207]

Both soluble dyes and dispersible pigments are employed as colorants in inkjet inks. The choice of colorant type depends somewhat on the application and media to be used. For example, on plain copier paper, light that is reflected off the surface of the ink film... [Pg.132]

We consider the case of a black ink for plain paper, to be apphed by TIJ print head. As mentioned before, black pigments are quite effective at achieving high optical density on porous media, so we pursue a carbon black dispersion as the colorant. An investigation of the patent hterature shows that a charge stabilization level of... [Pg.136]

The negative optical rotation of 5-acetamido-5-deoxy-a-D-xylopyra-nose is in contradiction to its existence as the a-D anomer. As Fig. 2 shows, the methyl D-xylopyranoside that corresponds to the a-D form, according to the Hudson isorotation rule, shows a positive plain curve and the p-D form shows a negative plain curve in optical rotatory dispersion. On the other hand, 5-acylamido-5-deoxy-a-D-xylop)franoses and their glycosides exhibit negative plain curves. Obviously, the... [Pg.191]

If the amide chromophore is removed from methyl 5-[(benzyloxy-carbonyl)amino]-5-deoxy-a-D-xylopyranoside (40), or from its non-glycosidic form (31),a positive plain curve of optical rotatory dispersion is found for 5-amino-5-deoxy-D-xylopyranose (17) and its methyl glycoside (41). Because, at least with the glycoside 41, no reversal of configuration at C-1 is to be expected under these conditions, 5-amino-5-deoxy-D-xylopyranose and its methyl glycoside likewise show a tendency to assume the o-D anomeric form, and show plain curves in agreement with the Hudson isorotation rule. ... [Pg.193]


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See also in sourсe #XX -- [ Pg.5 , Pg.243 ]




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