Diethyl thiourea

S- and Se-donor ligands. The e.s.r. and electronic spectra of [Co(sacsac)2] and [Co(sacsac)2L] (sacsac = dithioacetylacetonate, L = py or piperidine) have been studied, and a polarographic study of [Co(sacsac)J (n = 2 or 3) in acetone has shown the complexes to have a well-defined capacity to accept one or two electrons in a reversible stepwise manner. The magnitude of the potentials and their reversible nature suggest that isolation of cobalt-sacsac complexes of low formal oxidation states should be possible." Co complexes of l,5-bis-(2-methylmercaptoethylthio)pentane are both hydrated and polymeric, and thermal decomposition in air or nitrogen leads to oxida tion to Co . Ethylenethiourea (etu) and tetramethylthiourea (tmtu) form the complexes [Co(etu) ](N03)2 and [Co(tmtu) ](C10 )2, which are tetrahedral, and [Co(etu)2(N03)2] and [Co(tmtu)2(N03)2] which have distorted octahedral co-ordination. 3-Diphenylphosphinothioyl-l-phenylthiourea, -1,1-diethyl-thiourea, and -1,1-dimethylthiourea form complexes with Co in which the ligands are bidentate. ... 

Diethyl maicatc N,N-Diethyl-2-methyl-l,4-phcny]encdiamine MCI Diethyl thiourea N,N-DimethylainmoetKyl methacrylat ... 

The radioactive effluent piped from the 116-N-2 storage tank was internal decontamination solution from cleaning the primary coolant loop in N Reactor and various waste decontamination solutions from small decontamination Jobs. The primary loop was decontaminated every 3 to 5 years. The radioactive wastewater resulting from this procedure contained phosphoric acid and diethyl thiourea. The wastewater was neutralized in the 116-N-2 facility. 

The silo routed the acidic decontamination solutions Into the 116-N-2 storage tank for neutralization. The dangerous wastes in the decontamination solution Included approximately 80,000 L (21,000 gal) of 70 percent phosphoric acid and 140 to 180 kg (300 to 400 lb) of diethyl thiourea. The primary loop of the reactor was decontaminated every 3 to 5 years. Approximately 2,300,000 L (600,000 gal) of solution were generated during each decontamination event. 

The decontamination solution generally contained phosphoric acid and diethyl thiourea, but small-scale decontaminations occurred that contained a variety of cleaning solutions. Generally, the 3.8-cm (1.5-in.) chemical decontamination waste drainline transported these smaller scale decontamination solutions to the 116-N-2 facility. 

UN-100-N-26 Valve Pit at 1314-N Loading Station 1,000 gal of spent reactor decontamination solution containing phosphoric acid and diethyl thiourea backflowed while being pumped into a tank car. Rail car overflow. 

As an organic accelerator, ethylene thiourea (ETU), which is preferably used in non-dusty forms, is widely used. Different derivatives of thiourea, such as diethyl thiourea (DETU) and diphenyl thiourea (DPTU), are typical ultrafast accelerators, especially suitable for continuous cure. 

CT I. Cellulose triaeetate (DIN) see also DETU Diethyl thiourea (WTR)... 

Compression set resistance can be improved considerably in all types of polychloroprene by effecting a very tight cure. Thus, long cure times, high curing temperatures and high accelerator concentrations are beneficial. While acceleration with ethylene thiourea (1 phr) or diethyl thiourea (1 phr) for fast continuous vulcanisation will meet most requirements, for the most demanding specifications it may be necessary to use trimethyl thiourea (2 phr) and epoxy resin (1 phr) or tributyl thiourea (3-4 phr). 

Barbituric acid and 2-thiobarbituric acid are readily prepared by the condensation of diethylmalonate with urea and thiourea respectively, in the presence of sodium ethoxide. The use of substituted derivatives of urea and thiourea and of diethyl malonate will clearly lead to a wide range of barbituric and thiobarbituric acids having substituents in the i, 3, or 5 positions. 

Thiourea (H2NCNH2) reacts with diethyl malonate and its alkyl derivatives in the same way that urea does Give the structure of the product obtained when thiourea is used instead of urea in the synthesis of pentobarbital The anesthetic thiopental (Pentothal) sodium is the sodium salt of this product yWhat IS the structure of this compound ... 

The primary synthesis of alkoxypyrimidines is exemplified in the condensation of dimethyl malonate with O-methylurea in methanolic sodium methoxide at room temperature to give the 2-methoxypyrimidine (854) (64M207) in the condensation of diethyl phenoxymalonate with formamidine in ethanolic sodium methoxide to give the 5-phenoxypyrimidine (855) (64ZOB1321) and in the condensation of butyl 2,4-dimethoxyacetoacetate with thiourea to give 5-methoxy-6-methoxymethyl-2-thiouracil (856) (58JA1664). 

Tropolone has been made from 1,2-cycloheptanedione by bromination and reduction, and by reaction with A -bromosuccinimide from cyolo-heptanone by bromination, hydrolysis, and reduction from diethyl pimelate by acyloin condensation and bromination from cyclo-heptatriene by permanganate oxidation from 3,5-dihydroxybenzoic acid by a multistep synthesis from 2,3-dimethoxybenzoic acid by a multistep synthesis from tropone by chlorination and hydrolysis, by amination with hydrazine and hydrolysis, or by photooxidation followed by reduction with thiourea from cyclopentadiene and tetra-fluoroethylene and from cyclopentadiene and dichloroketene. - ... 

Thiourea (H2NCNH2) reacts with diethyl malonate and its alkyl... 

In 450 cc of methanol is added 47 grams of sodium metal and the mixture allowed to completely react to form a methanol solution of sodium methoxide. The methanol solution of sodium methoxide is then cooled to 60°C and 68 grams of thiourea which has been thoroughly dried is added with stirring until a uniform solution is formed. Thereafter, 157 grams of diethyl allyl-(1-methylbutyl)malonate is added to the solution of the sodio derivative of thiourea at a temperature of 55°C and the condensation reaction mixture maintained at the said temperature for 24 hours. Methyl alcohol is removed under vacuum during the course of the reaction while maintaining a temperature of 55°C. 

Cyclohexanol, Cyclopentane, Cyclopentene, 1,2-Dichloroethane, Diethyl phthalate, 1,4-Dioxane, Ethephon. Ethylamine, Ethylene dibromide, Ethylenimine, p-Propiolactone, Tetraethyl pyrophosphate, TCDD, 1,1,1-Trichloroethane, Trichloroethylene, Vinyl chloride Ethylene chlorohydrin, see Bis(2-chloroethyl) ether Ethylenediamine, see Ethylene thiourea. Maneb Ethylene glycol, see Bis(2-chloroethyl) ether, 1,2-Dichloroethane, Ethylene chlorohydrin. Ethylene dibromide... 

The Takemoto group synthesized a series ofdiaminocyclohexane-based thiourea derivatives (e.g., 12, 40, 57, and 58) for catalysis of the Michael addition [149-152] ofmalonates to trons-j3-nitrostyrenes (Figure 6.18) [129, 207]. In the model, Michael addition of diethyl malonate to trons-]3-nitrostyrene at room temperature and in toluene as the solvent tertiary amine-functionalized thiourea 12 (10mol% loading) was identified to be the most efficient catalyst in terms of catalytic activity (86%... 

Figure 6.18 Chiral amine 56 and thiourea derivatives (10mol% loading) screened in the asymmetric Michael addition of diethyl malonate to trcms-P-nitrostyrene in toluene.

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