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Hydrogen, Deuterium

Mass spectrometry has been used to determine the amount of H2 in complex gas mixtures (247), including those resulting from hydrocarbon pyrolysis (68). Mass spectrometry can also be used to measure hydrogen as water from hydrocarbon combustion (224,248). Moreover, this technique is also excellent for determining the deuterium hydrogen ratio in a sample (249,250). [Pg.431]

Hypoxanthine, 7-ethyl-synthesis, 5, 584 Hypoxanthine, 1-methyl-deuterium-hydrogen exchange, 5, 527 synthesis, 5, 594 Hypoxanthine, 2-methyl-methylation, 5, 532 synthesis, 5, 587 Hypoxanthine, 3-methyl-free radical methylation, 5, 544 irradiation, 5, 543 synthesis, 5, 584 Hypoxanthine, 8-methyl-synthesis, 5, 584 Hypoxanthine, 9-methyl-methylation, 5, 532... [Pg.647]

Purine, 6-iodo-alkylation, 5, 530 synthesis, 5, 563, 597 Purine, 6-iodo-9- -D-(2,3,5-tri-0-acetyl)ribofuranosyl-synthesis, 5, 598 Purine, 9-isopropyl-deuterium-hydrogen exchange, 5, 527 Purine, 9-(2,3-0-isopropylidene-/3-D-ribofuranosyl)-6-methoxy-synthesis, 5, 584 Purine, 6-mercapto-biological activity, 5, 604 metabolism, 1, 237 as pharmaceutical, 1, 159 tautomerism, 5, 509 Purine, 2-methoxy-synthesis, 5, 596 Purine, 6-methoxy-irradiation, 5, 543 riboside... [Pg.759]

Tetrazole, 5-phenoxy-l -phenyl-mass spectra, 5, 801 photolysis, 5, 811 Tetrazole, 1-phenyl-deuterium-hydrogen exchange, 5, 806 mercuration, 5, 59 NMR, 5, 798 tautomerism, 5, 804 UV spectra, 5, 798 Tetrazole, 2-phenyl-NMR, 5, 798 tautomerism, 5, 804 UV spectra, 5, 798 Tetrazole, 5-phenyl-alkylation, 5, 818 anti-inflammatory activity, 5, 835 blowing agent, 1, 410 reactions... [Pg.854]

Xanthine, 8-ethyl-synthesis, 5, 574 Xanthine, 9-hydroxy-8-methyl-synthesis, S, 596 Xanthine, 1-methyl-deuterium-hydrogen exchange, S, 527 methylation, S, 533 occurrence, S, 598 reduction, 5, 541 synthesis, S, 589 Xanthine, 3-methyl-deuterium-hydrogen exchange, S, 528 methylation, S, 533 reduction, S, 541 synthesis, S, 595 Xanthine, 7-methyl-deuterium-hydrogen exchange alkylation, S, 527 reduction, S, 541 synthesis, S, 587 Xanthine, 8-methyl-synthesis, S, 574 Xanthine, 9-methyl-methylation, S, 533 nitration, 5, 538... [Pg.923]

Using a selected ion flow tube (SIFT) technique, DePuy and coworkers studied such rates of deuterium-hydrogen exchange for a series of neutral carbon acids10. Table 1 contains some selected rates of exchange with DO- from DePuy s work these rates are approximate measures of relative acidity in the gas phase. [Pg.735]

Studies in deuterated water have shown that the hydroxyl proton does not end up in the ethanal formed. The decomposition of the 2-hydroxyethyl is not a simple P-elimination to palladium hydride and vinyl alcohol, which then isomerises to ethanal. Instead, the four protons stemming from ethene are all present in the initial ethanal product [6] (measured at 5 °C in order to suppress deuterium/hydrogen exchange in the product) and most authors have therefore accepted an intramolecular hydride shift as the key-step of the mechanism (see Figure 15.2). There remains some doubt as to how the hydride shift takes place. [Pg.322]

Examples 28 and 29 are for deuterium-hydrogen exchange reactions. The reaction in Example 28 was carried out at a temperature low enough so that the only reaction after adsorption was that of CgHj (ads) with D (ads), followed by desorption. Sarkany, Guczi, and Tetenyi (54) suggested for their reaction that the rate-determining step was cyclohexane adsorption. The log L values indicate that dissociative adsorption of cyclohexane (Step 2, cyclohexane), for which log L = 19, is possible. But some surface freedom of cyclohexane is required. Dissociative adsorption of D2, for which log L = 15, seems more likely. [Pg.146]

Scheme 15.4 Deuterium/hydrogen (D/H) exchange reaction in ionic liquids promoted by lr(0) nanoparticles. Scheme 15.4 Deuterium/hydrogen (D/H) exchange reaction in ionic liquids promoted by lr(0) nanoparticles.
As already reported in Section II,A, the amination of 6-bromo-5-deuterio-4-phenylpyrimidine with potassium amide in liquid ammonia provides a produet in which deuterium is no longer present. Based on the work deseribed previously, it seems reasonable to conclude that this easily occurring deuterium-hydrogen exchange takes place in the intermediary imidoyl bromide (17a, X = Br) (Scheme 11.18) and not in the cyanoazadiene (17b). In the strong basie medium a fast equilibrium can be formulated between these open-ehain intermediates (17a, X = Br, 29, and 30) (Scheme 11.18). [Pg.28]


See other pages where Hydrogen, Deuterium is mentioned: [Pg.198]    [Pg.511]    [Pg.512]    [Pg.573]    [Pg.674]    [Pg.683]    [Pg.760]    [Pg.854]    [Pg.854]    [Pg.857]    [Pg.858]    [Pg.923]    [Pg.924]    [Pg.141]    [Pg.143]    [Pg.145]    [Pg.147]    [Pg.149]    [Pg.151]    [Pg.153]    [Pg.155]    [Pg.157]    [Pg.159]    [Pg.161]    [Pg.133]    [Pg.439]    [Pg.65]    [Pg.229]    [Pg.119]    [Pg.451]    [Pg.186]    [Pg.18]    [Pg.9]    [Pg.11]    [Pg.11]    [Pg.12]   
See also in sourсe #XX -- [ Pg.23 , Pg.94 , Pg.175 , Pg.177 , Pg.178 , Pg.185 , Pg.193 , Pg.219 , Pg.222 ]

See also in sourсe #XX -- [ Pg.394 , Pg.395 , Pg.408 , Pg.409 , Pg.416 ]




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Alcohols hydrogen deuterium exchange

Arenes, hydrogen-deuterium exchange

Aromatic positions, deuterium-hydrogen

Asymmetric hydrogenation deuterium isotope effects

Benzylic positions, deuterium-hydrogen

Deuterium (heavy hydrogen

Deuterium exchange during hydrogenation

Deuterium hydrogen selenide

Deuterium hydrogen sulfide

Deuterium hydrogenation with

Deuterium isotope effects hydrogen shifts

Deuterium isotope effects hydrogen tunneling

Deuterium isotope effects, and hydrogen

Deuterium isotope effects, and hydrogen bonding

Deuterium labelling hydrogen bonding

Deuterium replacing hydrogen atoms

Deuterium separation processes hydrogen distillation

Deuterium separation processes water-hydrogen exchange

Deuterium to hydrogen ratio

Deuterium/hydrogen isotope ratio

Diazoalkanes, hydrogen-deuterium

Diazoalkanes, hydrogen-deuterium exchange

Electrolysis deuterium separated from hydrogen

Electrophilic hydrogen-deuterium

Ethene, reaction with deuterium hydrogen exchange

Exchange effects hydrogen-deuterium

Exchange reaction deuterium-hydrogen

Exchange reactions between hydrogen and deuterium

Factors Affecting Hydrogen-Deuterium Exchange of Biological Molecules

Gas Phase Hydrogen-Deuterium Exchange

High-pressure hydrogenated carbon deuterium

Hydrogen Isotopes - Deuterium and Tritium

Hydrogen deuterium exchange

Hydrogen deuterium exchange in alcohols

Hydrogen rapid exchange with deuterium

Hydrogen reacting with deuterium molecule

Hydrogen selenides deuterium

Hydrogen with deuterium, enzymatic

Hydrogen-Deuterium Exchange to Study Conformational

Hydrogen-deuterium equilibration

Hydrogen-deuterium exchang

Hydrogen-deuterium exchange amino acids

Hydrogen-deuterium exchange applications

Hydrogen-deuterium exchange carboxylic acids

Hydrogen-deuterium exchange cytochrome

Hydrogen-deuterium exchange enzymes

Hydrogen-deuterium exchange experimental techniques

Hydrogen-deuterium exchange insulin

Hydrogen-deuterium exchange mass spectroscopy

Hydrogen-deuterium exchange polypeptides

Hydrogen-deuterium exchange proteins (

Hydrogen-deuterium exchange random coil structure

Hydrogen-deuterium exchange rate constant

Hydrogen-deuterium exchange rate equations

Hydrogen-deuterium exchange reaction experimental data

Hydrogen-deuterium exchange reaction mechanism

Hydrogen-deuterium exchange relationship

Hydrogen-deuterium exchange structures

Hydrogen-deuterium exchange theory

Hydrogen-deuterium exchange, base

Hydrogen-deuterium exchange, base catalyzed

Hydrogen-deuterium exchange, catalyzed

Hydrogen-deuterium exchange, rate

Hydrogen-deuterium exchange, with

Hydrogen-deuterium exchange, with hydrocarbons

Hydrogen-deuterium isotope electronic states

Hydrogen-deuterium kinetic isotope effect

Hydrogen-deuterium separation

Hydrogen-deuterium-tritium exchange

Hydrogen/deuterium (H/D exchange

Hydrogen/deuterium exchange experiment

Hydrogen/deuterium exchange mass

Hydrogen/deuterium exchange mass spectrometry

Hydrogen/deuterium exchange mass spectrometry technique

Hydrogen/deuterium isotope effects

Hydrogen/deuterium oxide exchange

Hydrogen/deuterium reaction with

Hydrogen/deuterium reaction with aluminum

Hydrogen/deuterium reaction with cobalt

Hydrogen/deuterium reaction with kinetic isotope effect

Hydrogen/deuterium reaction with nickel

Hydrogen/deuterium reaction with platinum

Hydrogen/deuterium reaction with rhodium

Hydrogen/deuterium scrambling

Hydrogen/deuterium surface pool

Hydrogenation deuterium

Hydrogenation deuterium

Hydrogenation deuterium scrambling, mechanism

Hydrogenation of alkadienes (cont reaction with deuterium

Hydrogen—deuterium kinetic data

Intramolecular hydrogen-deuterium

Intramolecular hydrogen-deuterium exchange

Isotope hydrogen-deuterium

Kinetic isotope effects primary hydrogen-deuterium

Kinetic isotope effects secondary alpha hydrogen-deuterium

Kinetic isotope effects secondary hydrogen-deuterium

Naphthalene, hydrogenation exchange with deuterium

Nickel hydrogen-deuterium exchange

Platinum complexes hydrogen-deuterium exchange

Protein dynamics hydrogen-deuterium exchange mass

Pyrazine hydrogen-deuterium exchange

Silanes hydrogen-deuterium exchange

The Hydrogen-Deuterium Exchange on Defect Zinc Oxide

The Reaction of Hydrogen-Deuterium Exchange

Toluene, hydrogen-deuterium exchange

Toluene, hydrogen-deuterium exchange reactions

Transition metal complexes hydrogen-deuterium exchange

Zinc oxide hydrogen-deuterium exchange

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