Turbulent deposition

For turbulence it is convenient to describe particle flux in terms of an eddy diffusion coefficient, similar to a molecular diffusion coefficient. Unlike a molecular diffusion coefficient, however, the eddy diffusion coefficient is not constant for a given temperature and particle mobility, but decreases as the eddy approaches a surface. As particles are moved closer and closer to a surface by turbulence, the magnitude of their fluctuations to and from that surface diminishes, finally reaching a point where molecular diffusion predominates. As a result, in turbulent deposition, turbulence establishes a uniform aerosol concentration that extends to somewhere within the viscous sublayer. Then molecular diffusion or particle inertia transports the particles the rest of the way to the surface. 

The first form of aerosol modifier is a spray chamber. It is designed to produce turbulent flow in the argon carrier gas and to give time for the larger droplets to coalesce by collision. The result of coalescence, gravity, and turbulence is to deposit the larger droplets onto the walls of the spray chamber, from where the deposited liquid drains away. Since this liquid is all analyte solution, clearly some sample is wasted. Thus when sensitivity of analysis is an issue, it may be necessary to recycle this drained-off liquid back through the nebulizer. 

Depending on the type of nebulizer used and its efficiency, there may be initially a significant proportion of large droplets in the aerosol. Heavier than the very fine droplets, the larger droplets are affected by gravity and by turbulent flow in the argon sweep gas, which cause them to deposit onto the walls of the transfer tube. 

Texturing. The final step in olefin fiber production is texturing the method depends primarily on the appHcation. For carpet and upholstery, the fiber is usually bulked, a procedure in which fiber is deformed by hot air or steam jet turbulence in a no22le and deposited on a moving screen to cool. The fiber takes on a three-dimensional crimp that aids in developing bulk and coverage in the final fabric. Stuffer box crimping, a process in which heated tow is overfed into a restricted oudet box, imparts a two-dimensional sawtooth crimp commonly found in olefin staple used in carded nonwovens and upholstery yams. 

One of the most efficient implementations of the slurry process was developed by Phillips Petroleum Company in 1961 (Eig. 5). Nearly one-third of all HDPE produced in the 1990s is by this process. The reactor consists of a folded loop with four long (- 50 m) vertical mns of a pipe (0.5—1.0 m dia) coimected by short horizontal lengths (around 5 m) (58—60). The entire length of the loop is jacketed for cooling. A slurry of HDPE and catalyst particles in a light solvent (isobutane or isopentane) circulates by a pump at a velocity of 5—12 m/s. This rapid circulation ensures a turbulent flow, removes the heat of polymeriza tion, and prevents polymer deposition on the reactor walls. 

In the Sulser-MWB process the naphthalene fractions produced by the crystallisation process are stored in tanks and fed alternately into the crystalliser. The crystalliser contains around 1100 cooling tubes of 25-mm diameter, through which the naphthalene fraction passes downward in turbulent flow and pardy crystallises out on the tube walls. The residual melt is recycled and pumped into a storage tank at the end of the crystallisation process. The crystals that have been deposited on the tube walls are then pardy melted for further purification. Following the removal of the drained Hquid, the purified naphthalene is melted. Four to six crystallisation stages are required to obtain refined naphthalene with a crystallisation point of 80°C, depending on the quaHty of the feedstock. The yield is typically between 88 and 94%, depending on the concentration of the feedstock fraction. 

Early models used a value for that remained constant throughout the day. However, measurements show that the deposition velocity increases during the day as surface heating increases atmospheric turbulence and hence diffusion, and plant stomatal activity increases (50—52). More recent models take this variation of into account. In one approach, the first step is to estimate the upper limit for in terms of the transport processes alone. This value is then modified to account for surface interaction, because the earth s surface is not a perfect sink for all pollutants. This method has led to what is referred to as the resistance model (52,53) that represents as the analogue of an electrical conductance... 

The mass-transfer coefficients depend on complex functions of diffii-sivity, viscosity, density, interfacial tension, and turbulence. Similarly, the mass-transfer area of the droplets depends on complex functions of viscosity, interfacial tension, density difference, extractor geometry, agitation intensity, agitator design, flow rates, and interfacial rag deposits. Only limited success has been achieved in correlating extractor performance with these basic principles. The lumped parameter deals directly with the ultimate design criterion, which is the height of an extraction tower. 

Indirect attack can also occur because of turbulence associated with flow over and around a deposit. Increased turbulence may initiate attack (see Chap. 11, Erosion-Corrosion and Chap. 12, Cavitation Damage ). 

Shells, clams, wood fragments, and other biological materials can also produce concentration cell corrosion. Additionally, fragments can lodge in heat exchanger inlets, locally increasing turbulence and erosion-corrosion. If deposits are massive, turbulence, air separation, and associated erosion-corrosion can occur downstream (see Case History 11.5). 

Favored locations for erosion-corrosion are areas exposed to high-flow velocities or turbulence. Tees, bends, elbows (Fig. 11.5), pumps, valves (Fig. 11.6), and inlet and outlet tube ends of heat exchangers (Fig. 11.7) can be affected. Turbulence may be created downstream of crevices, ledges (Fig. 11.8), abrupt cross-section changes, deposits, corrosion products, and other obstructions that change laminar flow to turbulent flow. 

Metal loss in these areas had produced a smooth surface, free of deposits and corrosion products. The rest of the internal surface was covered by a thin, uniform layer of soft, black corrosion product. The graphitically corroded surfaces of the pump casing provided soft, friable corrosion products that were relatively easily dislodged by the abrasive effects of high-velocity or turbulent water (erosion-corrosion). 

A situation which is frequently encountered in tire production of microelectronic devices is when vapour deposition must be made into a re-entrant cavity in an otherwise planar surface. Clearly, the gas velocity of the major transporting gas must be reduced in the gas phase entering the cavity, and transport down tire cavity will be mainly by diffusion. If the mainstream gas velocity is high, there exists the possibility of turbulent flow at tire mouth of tire cavity, but since this is rare in vapour deposition processes, the assumption that the gas widrin dre cavity is stagnant is a good approximation. The appropriate solution of dre diffusion equation for the steady-state transport of material tlrrough the stagnant layer in dre cavity is... 

GASFLOW models geometrically complex containments, buildings, and ventilation systems with multiple compartments and internal structures. It calculates gas and aerosol behavior of low-speed buoyancy driven flows, diffusion-dominated flows, and turbulent flows dunng deflagrations. It models condensation in the bulk fluid regions heat transfer to wall and internal stmetures by convection, radiation, and condensation chemical kinetics of combustion of hydrogen or hydrocarbon.s fluid turbulence and the transport, deposition, and entrainment of discrete particles. 

Under higher waterside pressure conditions, consideration of bulk water turbulent flow, the thickness of the steam-water laminar flow sublayer film at the heat transfer surface, and the general waterside physicochemical operating conditions that exist are important issues in reviewing the potential risks of deposition, corrosion, and other problems that may occur within an operating boiler. 

Essentially, except for once-through boilers, steam generation primarily involves two-phase nucleate boiling and convective boiling mechanisms (see Section 1.1). Any deposition at the heat transfer surfaces may disturb the thermal gradient resulting from the initial conduction of heat from the metal surface to the adjacent layer of slower and more laminar flow, inner-wall water and on to the higher velocity and more turbulent flow bulk water. 

The life of equipment subjected to corrosive environments can be increased by proper attention to design details. Equipment should be designed to drain freely and completely. The internal surfaces should be smooth and free from crevasses where corrosion products and other solids can accumulate. Butt joints should be used in preference to lap joints. The use of dissimilar metals in contact should be avoided, or care taken to ensure that they are effectively insulated to avoid galvanic corrosion. Fluid velocities and turbulence should be high enough to avoid the deposition of solids, but not so high as to cause erosion-corrosion. 

First, there is a term to account for turbulent gas-phase mixing between adjacent subchannels. This is accounted for by a term that has the form of a concentration difference between the subchannels multiplied by a mass transfer coefficient and the area available for transfer. This representation was used, as it is similar to the equation used for deposition. 

The accuracy of the measurement of radon concentrations with bare track detectors was found to be unsatisfactory due mainly to the changes of the deposition rate of radon progeny onto the detector as a result of air turbulence. In this work, therefore, a method was developed which can correct the contributions of the deposition to the track densities by classifying the etched tracks according to their appearance, i.e. round or wedge shaped. Using this method, about 30% improvement in the error of measurements was achieved. The calibration coefficient ob tained by experiment was 0.00424 tracks/cm /h/(Bq/m ), which agreed well with the calculated value. Comparison was also made of the present method with other passive methods, charcoal and Terradex, as to their performance under the same atmosphere. 

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