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Cyclical Hydrocarbons

The formula for cyclic hydrocarbons has been established from data on hydrocarbons whose molecular weights are lower than 140 and must not be used for higher molecular weights. [Pg.135]

Sheppard N and De La Cruz C 1998 Vibrational spectra of hydrocarbons adsorbed on metals. Part II. Adsorbed acyclic alkynes and alkanes, cyclic hydrocarbons including aromatics and surface hydrocarbon groups derived from the decomposition of alkyl halides, etc Adv. Catal. 42 181-313... [Pg.1795]

Hetero)cyclic hydrocarbons Ln.J T.n.J L beginning of a carbocyclic ring T beginning of a heterocydic ring n number of atoms of the ring system f termination of the ring system... [Pg.24]

Group VI. Concentrated sulphuric acid provides a simple test for the diflferentiation inter alia between (a) saturated paraffin and cyclic hydrocarbons and also simple aromatic hydrocarbons and (b) unsaturated hydrocarbons. [Pg.1053]

Mercaptoselenazoies with Q to C,o cyclic hydrocarbon substituents in the 4-position have been mentioned as giving negative images from photosolubie emulsions (38. 39). Equally cited are other heterocycles such as thiazole. oxazole, or imidazole. [Pg.237]

Cyclic hydrocarbons can contain more than one ring Spirocyclic hydro carbons are characterized by the presence of a single carbon that is com mon to two rings Bicyclic alkanes contain two rings that share two or more atoms... [Pg.136]

The general term annulene has been coined to apply to completely conjugated mono cyclic hydrocarbons with more than six carbons Cyclobutadiene and benzene retain then-names but higher members of the group are named [jcjannulene where x is the number of carbons m the ring Thus cyclooctatetraene becomes [8]annulene cyclodecapentaene becomes [10] annulene and so on... [Pg.454]

Cycloalkene (Section 5 1) A cyclic hydrocarbon characterized by a double bond between two of the nng carbons Cycloalkyne (Section 9 4) A cyclic hydrocarbon characterized by a tnple bond between two of the nng carbons Cyclohexadienyl anion (Section 23 6) The key intermediate in nucleophilic aromatic substitution by the addition-elimination mechanism It is represented by the general structure shown where Y is the nucleophile and X is the leaving group... [Pg.1280]

Cyclic Hydrocarbons with Side Chains. Hydrocarbons composed of cyclic and aliphatic chains are named in a manner that is the simplest permissible or the most appropriate for the chemical intent. Hydrocarbons containing several chains attached to one cyclic nucleus are generally named as derivatives of the cyclic compound, and compounds containing several side chains and/or cyclic radicals attached to one chain are named as derivatives of the acyclic compound. Examples are... [Pg.11]

Cyclic Hydrocarbons. The cyclic hydrocarbon intermediates are derived principally from petroleum and natural gas, though small amounts are derived from coal. Most cycHc intermediates are used in the manufacture of more advanced synthetic organic chemicals and finished products such as dyes, medicinal chemicals, elastomers, pesticides, and plastics and resins. Table 6 details the production and sales of cycHc intermediates in 1991. Benzene (qv) is the largest volume aromatic compound used in the chemical industry. It is extracted from catalytic reformates in refineries, and is produced by the dealkylation of toluene (qv) (see also BTX Processing). [Pg.367]

Cycloaliphatic amines are comprised of a cyclic hydrocarbon stmctural component and an amine functional group external to that ring. Included in an extended cycloaUphatic amine definition ate aminomethyl cycloaUphatics. Although some cycloaUphatic amine and diamine products have direct end use apphcations, their major function is as low cost organic intermediates sold as moderate volume specification products. [Pg.206]

Displacement-purge forms the basis for most simulated continuous countercurrent systems (see hereafter) such as the UOP Sorbex processes. UOP has licensed close to one hundred Sorbex units for its family of processes Parex to separate p-xylene from C3 aromatics, Molex tor /i-paraffin from branched and cyclic hydrocarbons, Olex for olefins from paraffin, Sarex for fruc tose from dextrose plus polysaccharides, Cymex forp- or m-cymene from cymene isomers, and Cresex for p- or m-cresol from cresol isomers. Toray Industries Aromax process is another for the production of p-xylene [Otani, Chem. Eng., 80(9), 106-107, (1973)]. Illinois Water Treatment [Making Wave.s in Liquid Processing, Illinois Water Treatment Company, IWT Adsep System, Rockford, IL, 6(1), (1984)] and Mitsubishi [Ishikawa, Tanabe, and Usui, U.S. Patent 4,182,633 (1980)] have also commercialized displacement-purge processes for the separation of fructose from dextrose. [Pg.1544]

Fig. 1.6. Charge distributions in strained cyclic hydrocarbons in comparison with cyclohexane. Data are from K. B. Wiherg, R. F. W. Bader, and C. D. H. Lau, J. Am. Chem. Soc. 109 1001 (1987). Fig. 1.6. Charge distributions in strained cyclic hydrocarbons in comparison with cyclohexane. Data are from K. B. Wiherg, R. F. W. Bader, and C. D. H. Lau, J. Am. Chem. Soc. 109 1001 (1987).
Although the Hiickel method has now been supplanted by more complete treatments for theoretical analysis of organic reactions, the pictures of the n orbitals of both linear and cyclic conjugated polyene systems that it provides are correct as to symmetry and the relative energy of the orbitals. In many reactions where the n system is the primary site of reactivity, these orbitals correctly describe the behavior of the systems. For that reason, the reader should develop a familiarity with the qualitative description of the n orbitals of typical linear polyenes and conjugated cyclic hydrocarbons. These orbitals will be the basis for further discussion in Chapters 9 and 11. [Pg.36]

Table I.IS gives total bonding energies in kilocalories per mole for some simple molecules. The B3iyP results are comparable in accuracy to G1 and G2 results. Another comparison was done with a series of cyclic hydrocarbons as the test case. The calculations were done using an isodesmic reaction scheme. The results are given in Table 1.19. Density functional calculations have also been successfully extended to functionalized molecules. ... Table I.IS gives total bonding energies in kilocalories per mole for some simple molecules. The B3iyP results are comparable in accuracy to G1 and G2 results. Another comparison was done with a series of cyclic hydrocarbons as the test case. The calculations were done using an isodesmic reaction scheme. The results are given in Table 1.19. Density functional calculations have also been successfully extended to functionalized molecules. ...
The aromatic hydrocarbons are used mainly as solvents and as feedstock chemicals for chemical processes that produce other valuable chemicals. With regard to cyclical hydrocarbons, the aromatic hydrocarbons are the only compounds discussed. These compounds all have the six-carbon benzene ring as a base, but there are also three-, four-, five-, and seven-carbon rings. These materials will be considered as we examine their occurrence as hazardous materials. After the alkanes, the aromatics are the next most common chemicals shipped and used in commerce. The short-chain olefins (alkenes) such as ethylene and propylene may be shipped in larger quantities because of their use as monomers, but for sheer numbers of different compounds, the aromatics will surpass even the alkanes in number, although not in volume. [Pg.194]

Cycloalkene (Section 5.1) A cyclic hydrocarbon characterized by a double bond between two of the ring carbons. [Pg.1280]

Cyclic Hydrocarbons. These are structures in which the carbon atoms form a ring instead of an open chain. They are also called carbocyclic or homocyclic compounds. They are divided into two classes alicyclic (or cycloaliphatic) and aromatic compounds. [Pg.308]

Selected Examples of Cyclic Hydrocarbons Found in Crude Oils (MW = Molecular Weight, NBP = Boiling Point at 760 mm Hg, MP = Melting Point) [Source of Data Reference 63]... [Pg.318]

Saturated cyclic hydrocarbons, normally known as naphthenes, are also part of the hydrocarbon constituents of crude oils. Their ratio, however, depends on the crude type. The lower members of naphthenes are cyclopentane, cyclohexane, and their mono-substituted compounds. They are normally present in the light and the heavy naphtha fractions. Cyclohexanes, substituted cyclopentanes, and substituted cyclohexanes are important precursors for aromatic hydrocarbons. [Pg.13]

We JI look in the next chapter at cycloalkanes—saturated cyclic hydrocarbons— and we ll see that the molecules generally adopt puckered, nonplanar conformations. Cyclohexane, for instance, has a puckered shape like a lounge chair rather than a flat shape. Why ... [Pg.106]

Saturated cyclic hydrocarbons are called cycloalkanes, or alicyclic compounds (aliphatic cyclic). Because cycloalkanes consist of rings of -CH2- units, they have the general formula (CH2) , or and can be represented by polygons... [Pg.108]

A cycloalkane is a saturated cyclic hydrocarbon with the general formula C H2 . In contrast to open-chain alkanes, where nearly free rotation occurs around C, -C bonds, rotation is greatly reduced in cycloalkanes. Disubstituted cycloalkanes can therefore exist as cis-trans isomers. The cis isomer has both substituents on the same face of the ring the trans isomer has substituents on opposite faces. Cis-trans isomers are just one kind of stereoisomers—isomers... [Pg.131]


See other pages where Cyclical Hydrocarbons is mentioned: [Pg.121]    [Pg.208]    [Pg.4]    [Pg.135]    [Pg.2790]    [Pg.175]    [Pg.55]    [Pg.1058]    [Pg.131]    [Pg.4]    [Pg.99]    [Pg.329]    [Pg.557]    [Pg.367]    [Pg.412]    [Pg.8]    [Pg.28]    [Pg.193]    [Pg.194]    [Pg.195]    [Pg.657]    [Pg.99]    [Pg.66]   
See also in sourсe #XX -- [ Pg.163 , Pg.164 ]

See also in sourсe #XX -- [ Pg.176 ]




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Aliphatic and Cyclic Hydrocarbons

Aliphatic cyclic hydrocarbons (

Aromatic compounds from cyclic hydrocarbons

Aromatic hydrocarbons with cyclic ethers

C6 cyclic hydrocarbons

Cyclic hydrocarbon systems

Cyclic hydrocarbons aromatic

Cyclic hydrocarbons as sensitizers

Cyclic hydrocarbons saturated

Cyclic hydrocarbons with side chains

Cyclic hydrocarbons, reactivities

Cyclic hydrocarbons, resonances

Cyclic hydrocarbons, synthesis

Cycloalkanes Cyclic saturated hydrocarbons

Diastereoselectivity cyclic hydrocarbons

Heteroatom substituents, cyclic hydrocarbon

Hydrocarbons Organic compounds that cyclic

Hydrocarbons cyclic

Hydrocarbons cyclic

Hydrocarbons, adsorbed alkenes, cyclic

Hydrocarbons, classification cyclic

Hydrocarbons, cyclic unsaturated

Orbitals of conjugated cyclic hydrocarbons

Pesticide cyclic hydrocarbon

Petrochemical cyclic hydrocarbons

Prefixes cyclic hydrocarbons

Pressure cyclic hydrocarbons

REACTIONS OF CYCLIC HYDROCARBONS

Reactions of excited cyclic hydrocarbons

Relative reactivities cyclic hydrocarbons

Singlet oxygen cyclic hydrocarbons

Skeletal transformations of cyclic hydrocarbons

Synthesis, carboxylic acids cyclic hydrocarbons

The Cyclic Hydrocarbons

The origin of strain energy in cyclic hydrocarbon molecules

Transition state cyclic hydrocarbons

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