Condensation Enhanced surfaces

Non-aqueous synthetic methods have recently been used to assemble mesoporous transition metal oxides and sulfides. This approach may afford greater control over the condensation-polymerization chemistry of precursor species and lead to enhanced surface area materials and well ordered structures [38, 39], For the first time, a rational synthesis of mesostructured metal germanium sulfides from the co-assembly of adamantanoid [Ge4S ()]4 cluster precursors was reported [38], Formamide was used as a solvent to co-assemble surfactant and adamantanoid clusters, while M2+/1+ transition metal ions were used to link the clusters (see Fig. 2.2). This produced exceptionally well-ordered mesostructured metal germanium sulfide materials, which could find application in detoxification of heavy metals, sensing of sulfurous vapors and the formation of semiconductor quantum anti-dot devices. 

Planet formation unfolds differently beyond the snowline, where water condensation enhances the surface density. Here massive cores (> 5-10 MEarth) may form rapid enough to accrete directly and retain nebular gas. These massive cores, if formed prior to the dispersal of the gas disk, rapidly reach Jupiter masses, forming giant planets. An alternative mechanism that may be responsible for the formation of some giant planets is gravitational instability in a massive, marginally unstable disk (e.g. Boss 2007 Mayer etal. 2007). 

Enhanced surfaces can often significandy increase the effective heat-transfer coefficient in condensation, especially if the condensing heat-transfer coefficient is the limiting factor in the overall heat-transfer-coefficient equation. Such enhancements include low fins on horizontal tubes, which increase the heat-transfer area, and fluting on vertical tubes and plane surfaces, which thins the condensate film over part of the surface by surface-tension effects. However, these improvements are limited by condensate retention between the fins and flooding of the drainage paths [7, 34],... 

L. L. Vasiliev and V. V. Khrolenok, Heat Transfer Enhancement with Condensation by Surface Rotation, Heat Recovery Sys. and CHP, 13, pp. 547-563,1993. 

High quality MCM-41 silica has been sonochemically synthesized in a relatively short time and characterized by XRD, TEM, Si MAS NMR, nitrogen sorption and hydrothermal treatment. It reveals that ultrasound promotes the condensation of surface silanol groups among micelles and accelerates the formation of MCM-41 framework. The as-synthesized MCM-41 silica, whose pore size shows a very narrow distribution, possesses a thicker wall and enhanced thermal stability as compared to those prepared with conventional methods. 

Ceramic powders and films made by gas-phase techniques and their characterization are discussed by C. L. J. Adkins and D. E. Peebles. Ultrafine ceramic particles with enhanced surface reactivity, such as Si02, can be synthesized through nucleation or condensation reactions in gas-phase aerosols. Ceramic films and... 

Enzymatic techniques can be used to endow proteins with surface-active functionality. An enzymatic technique that has shown promise in enhancing surface properties of proteins is a modified version of the classical plastein reaction. The plastein reaction is known to be a protease-catalyzed reverse process in which a peptide-peptide condensation reaction [11,12] proceeds through the peptidyl-enzyme intermediate formation [13]. It is essentially a two-step process enzymatic hydrolysis of a protein and plastein formation from the hydrolysate peptides. A novel one-step process was developed as a modified type of the plastein reaction by Yamashita et al. [14,15], which... 

As mentioned in Section IX-2A, binary systems are more complicated since the composition of the nuclei differ from that of the bulk. In the case of sulfuric acid and water vapor mixtures only some 10 ° molecules of sulfuric acid are needed for water oplet nucleation that may occur at less than 100% relative humidity [38]. A rather different effect is that of passivation of water nuclei by long-chain alcohols [66] (which would inhibit condensation note Section IV-6). A recent theoretical treatment by Bar-Ziv and Safran [67] of the effect of surface active monolayers, such as alcohols, on surface nucleation of ice shows the link between the inhibition of subcooling (enhanced nucleation) and the strength of the interaction between the monolayer and water. 

The pores in question can represent only a small fraction of the pore system since the amount of enhanced adsorption is invariably small. Plausible models are solids composed of packed spheres, or of plate-like particles. In the former model, pendulate rings of liquid remain around points of contact of the spheres after evaporation of the majority of the condensate if the spheres are small enough this liquid will lie wholly within the range of the surface forces of the solid. In wedge-shaped pores, which are associated with plate-like particles, the residual liquid held in the apex of the wedge will also be under the influence of surface forces. 

Dicylopentadiene Resins. Dicyclopentadiene (DCPD) can be used as a reactive component in polyester resins in two distinct reactions with maleic anhydride (7). The addition reaction of maleic anhydride in the presence of an equivalent of water produces a dicyclopentadiene acid maleate that can condense with ethylene or diethylene glycol to form low molecular weight, highly reactive resins. These resins, introduced commercially in 1980, have largely displaced OfXv o-phthahc resins in marine apphcations because of beneficial shrinkage properties that reduce surface profile. The inherent low viscosity of these polymers also allows for the use of high levels of fillers, such as alumina tfihydrate, to extend the resin-enhancing, fiame-retardant properties for apphcation in bathtub products (Table 4). 

In addition, the development of porous deposits on boiler surfaces often is enhanced by the presence of small amounts of iron or copper oxides (usually originating from contaminated condensate). This increased rate of deposition may then lead to even more serious problems of overheating. 

Kerker, M. and Blatehford, C.G. (1982) Elastic scattering, absorption, and surface-enhanced Raman scattering by concentric spheres comprised of a metaUic and a dielectric region. Physical Remeu> B — Condensed Matter, 26, 4052—4063. 

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