Colorants weatherability

Accelerated Weathering sunshine weatherometer test black panel without rain 83 20.8 6 AE color change of 3.9 68 103 lupital F20-52 Mitsubishi Gas Chemical Specimen Natural color, weatherable... 

The polymer can be vulcanized to give a rubber with very good chemical (solvent) resistance, excellent resistance to aging and weathering, and good color retention in sunlight. 

FWWMR Finish. The abbreviation for fire, water, weather, and mildew resistance, FWWMR, has been used to describe treatment with a chlorinated organic metal oxide. Plasticizers, coloring pigments, fiUers, stabilizers, or fungicides usuaUy are added. However, hand, drape, flexibUity, and color of the fabric are more affected by this type of finish than by other flame retardants. Add-ons of up to 60% are required in many cases to obtain... 

Uses. Neopentyl glycol is used extensively as a chemical intermediate in the manufacture of polyester resins (see Alkyd resins), polyurethane polyols (see Urethane polymers), synthetic lubricants, polymeric plasticizers (qv), and other polymers. It imparts a combination of desirable properties to properly formulated esterification products, including low color, good weathering and chemical resistance, and improved thermal and hydrolytic stabiUty. 

Quality Control and Testing. Control of inks is done by examining their color strength, hue, tack, rheology, drying rate, stabiHty, and product resistance. Elaborate control equipment and laboratory testing procedures are employed to test the finished inks. Weather-Ometers,... 

The above-mentioned codes contain requirements for accelerated durabiUty tests. In addition, interlayer manufacturers and laminators expose test samples for several years under extreme weather conditions, eg, the Florida coast and Arizona desert. The laminated products weather extremely well, with no change in the plastic interlayer. Occasionally, clouding is noted around the edges when exposed to high humidity for long periods, but this is reversible. Colored areas of PVB laminates may fade while subjected to extensive uv/solar irradiation, which could cause an appearance issue. This has not, however, been shown to alter the laminate s other performance properties. 

The soft weathered granodiorite and pegmatites can vary in color from white to pink, depending on iron content and type of feldspar present. The mica content of these deposits ranges from 6—15% and varies in particle size from tiny (<44 specks to thumbnail size. Large books of mica that weigh several hundred kilograms have been found in these deposits. 

The three classes of PE, designated as A, B, and C, specify the color, amount, and type of antioxidants and other additives. Class A refers to naturally colored PE, Class B includes white or black polymer, and Class C covers weather-resistant black polymer containing no less than 2% carbon black. Typical characteristics of resins used for film manufacture, injection mol ding, and blow mol ding are given in Table 5. 

An important property of a pigment is its ability to maintain its color when exposed to light, weather, heat, and chemicals. This property is seldom measured for pigments alone. Rather it is determined for the dispersion of a pigment in a desired medium, eg, paints or plastics, and in many cases it is compared to the performance of a standard pigment. The observed changes are the result of complex pigment and media reactions and their possible interactions. In aH evaluations, time of exposure plays a role. 

The prime installation method is mechanically fastened but fully adhered and ballasted appHcations can also be used. CSPE exhibits strong resistance not only to weathering but also to a broad range of chemicals and pollutants it is also inherently ozone-resistant. It can be produced in many colors and the sheet widths are typically 5—6.5 ft (1.5—1.65 m). The physical characteristics of a CSPE sheet have been described (17) (see Elastomers, SYNTHETIC-Cm OROSULFONATED POLYETHYLENE). 

The greater portion of PVC is installed in the mechanically fastened roofing system a lesser portion is installed in fully adhered appHcations. Although PVC was once heavily used in ballasted roofing systems, there are only a small number installed in the 1990s. Fleece-back membrane is popular in the PVC constmction for both fully adhered appHcations as well as in appHcations where a separator sheet is needed. PVCs ate resistant to vafious weather conditions, bactefial growth, and industfial chemicals. These membranes ate chemically incompatible with bituminous materials. PVCs ate offered in a variety of colors. The physical characteristics of a PVC membrane have been described (15). 

Weather-resistant mineral granules appHed to the top surface of strip shingles during the manufacturing process make possible a wide range of colors. Sand, talc, or mica is appHed to the back surface. 

Vinyl Acetate—Ethylene Copolymers. In these random copolymers, the ratio of ethylene to vinyl acetate (EVA) is varied from 30—60%. As the vinyl acetate content increases, the oil and heat resistance increases. With higher ethylene content the physical strength, tensile, and tear increases. The polymers are cured with peroxide. The main properties of these elastomers include heat resistance, moderate oil and solvent resistance, low compression set, good weather resistance, high damping, exceUent o2one resistance, and they can be easily colored (see Vinyl polymers, poly(VINYL acetate)). 

Ammonium Sulfamate. A number of flame retardants used for ceUulosic materials, including fabrics and paper products, are based on ammonium sulfamate (56). These products are water-soluble and therefore nondurable if treated fabrics are washed or exposed to weathering conditions. For most fabric and paper constmctions, efficient flame retardancy can be provided with no apparent effect on color or appearance and without stiffening or adverse effects on the feel of the fabrics. A wide variety of materials are treated, including ha2ardous work-area clothing, drapes, curtains, decorative materials, blankets, sheets, and specialty industrial papers (57). 

Golorfastness. A variety of test methods exist for determining the fastness, or color retention, properties of dyed fabric exposed to various conditions of weathering, laundering, or general exposure associated with the end use of the product. The AATCC Technical Manual should be consulted... 

Phosphate. Phosphoms occurs in water primarily as a result of natural weathering, municipal sewage, and agricultural mnoff The most common form in water is the phosphate ion. A sample containing phosphate can react with ammonium molybdate to form molybdophosphoric acid (H2P(Mo202q)4). This compound is reduced with stannous chloride in sulfuric acid to form a colored molybdenum-blue complex, which can be measured colorimetrically. SiUca and arsenic are the chief interferences. 

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