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Chemical processing interpreting data

Chemical kinetics deals with quantitative studies of the rates at which chemical processes occur, the factors on which these rates depend, and the molecular acts involved in reaction processes. A description of a reaction in terms of its constituent molecular acts is known as the mechanism of the reaction. Physical and organic chemists are primarily interested in chemical kinetics for the light that it sheds on molecular properties. From interpretations of macroscopic. kinetic data in terms of molecular mechanisms, they can gain insight into the nature of reacting systems, the processes by which chemical bonds are made and broken, and the structure of the resultant product. Although chemical engineers find the concept of a reaction mechanism useful in the correlation, interpolation, and extrapolation of rate data, they are more concerned with applications... [Pg.1]

Once the emission factors and their variability are estimated, dispersion models can be used in order to enable point data to be interpreted in terms of geographical distribution of source contributions, as suggested by the Air Quality Directive (2008/50/EC). This could serve as a basis for calculating the collective exposure of the population living in the area and for assessing air quality with respect to the limit values. Dispersion models are based on the use of meteorological data, modules to account with physico-chemical processes occurring in the atmosphere and EFs. [Pg.180]

Chapters 15 and 16 especially demonstrate the broad range of application of thermodynamics to chemical processes. In the discussions of the Haber cycle, synthesis of diamond, solubility of calcite, and the thermodynamics of metabolism, techniques are used to solve a specific problem for a particular substance. On the other hand, in the discussion of macrocyclic complexes, the description and interpretation involves the comparison of the properties of a number of complexes. This global approach is particularly helpful in the description of the energetics of ternary oxides in Chapter 15 and the stabilities of proteins and DNA in Chapter 16, where useful conclusions are obtained only after the comparison of a large amount of experimental data. [Pg.447]

One of the functions of Global Core Technologies R D is the analytical discipline Reactive Chemicals/ Thermal Analysis/Physical Properties (RC/TA/PP). Some of the capabilities of this discipline are testing and data interpretation for reactive chemicals hazard assessment. It is the responsibility of the owner of any chemical process to use this Dow resource to obtain the information which is necessary to design a safe and efficient operation. Information about the analytical RC Testing discipline including contact names can be obtained on the INTRAnet at Reactive Chemicals/Thermal Analysis/Physical Properties web site. [Pg.231]

Similar to previous structure identification methods described for metabolites, impurities, and degradants, the knowledge of the physiological or chemical process, in this case the adhesive synthesis process, helped in the rapid interpretation of the MS/MS spectra of the unknown components. No user input about the sample composition is needed for the data-dependent analysis scheme thus, these experiments are simple and rapid to perform. The result is a fairly routine approach to structural screening of unknown mixtures during the manufacturing stage. [Pg.176]

Systematic investigation of radiation-induced polymerization was conducted in Leeds by F. S. Dainton and his group (8) and in Paris by M. Magat and co-workers (9). The results of these studies convincingly demonstrated that radiation could initiate polymerization at any desired (low) temperature and led to a fundamental conclusion, viz., radiation-induced polymerizations occurred by conventional free radical mechanisms. This concept was extended to other radiation-chemical processes, and in the 1950 s most radiation chemists used free radical theories for interpreting their experimental data. [Pg.32]

While oxidation has been used extensively to modify and activate macroscopic forms of carbon on an industrial scale, most of the studies reported in literature provide only a qualitative description of the oxidation kinetics, and lack a fundamental understanding of the physical and chemical processes occurring at the nanoscale. The various types of carbon used in these studies were often simply referred to as coke or carbon soot, even though they are characterized by distinct differences in crystal stmcture and surface terminations. Therefore, a comparison of available data is often difficult and interpretation of the results may lead to ambiguous conclusions. [Pg.296]

They have played a pivotal role in both the processing of chemical materials and in quantifying the quality control procedures inherently associated with such operations on an industrial scale. The aim of this overview is to discuss the full range of thermal analysis techniques in terms of the type of measurement involved in each technique, the application range of that technique, and the interpretation of data obtained on using the technique. The applications are chosen with specific reference to the broad concept of chemical processing, so as to align with the overall objectives of this encyclopedia. [Pg.2965]

However, there still remains the fundamental problem of identifying the process chemically. Identification of the process in the chemical sense is ambiguous as there is no direct chemical observation of the system. It is easy to distinguish between chemical processes and physical processes, such as ion-solvent interactions or energy transfer, by the frequencies at which the maxima in the absorption of sound occurs. Identification of the chemical equilibria and the chemical species present are inferred through a fit of theory plus inference with experiment, and the data may be susceptible to more than one interpretation. One clue which has been used is that the frequency at which absorption of... [Pg.26]


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See also in sourсe #XX -- [ Pg.785 , Pg.786 ]




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