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Characterization tests ethers

The physicochemical nature of the oil phase components in a cosmetic emulsion, the emollients, determines the skin-care effects, such as smoothing, spreading, sensorial appearance. Test methods have been developed to characterize and classify the numerous emollients available on the market, such as silicones, paraffins, and oleochemical-based products. The latter include glycerides, esters, alcohols, ethers, and carbonates with tailor-made structures, depending on the performance needed (Table 4.8). However, especially with regard to additional effects, there is still a demand for new products with unique performance properties. [Pg.95]

Let us consider first lipid-lipid interaction. Urry et al, showed the existence of a positive CD band at 218 m/x and a negative CD band at about 192 m/z in phosphatidyl choline and phosphatidyl ethanolamine dissolved in trifluoroethanol (86). The 192-m/z band was not characterized in detail, but the 218-m/z band is of such position and shape that the addition of lipid and protein CD bands could produce a composite CD band, and hence an ORD Cotton effect, which is red shifted. As noted by Urry, the 218-m/z CD extremum of lecithin must arise from n — 7T transitions in the fatty acid ester groups. Although the optical activities of solutions of deproteinized membrane phospholipids determined at the same concentration as in the intact membrane are negligibly small, in membranes an ordered array of lipids could greatly enhance rotation. Such an effect could yield information on the nature of lipid-lipid association. This can be tested experimentally. Halobacterium cutirubrum offers a unique system since Kates has shown that the lipids in this extreme halophile contain ether bonds rather than ester bonds (43, 44), Hence, the n — tt transition essential to the CD band at 218 m/z in phospholipids does not exist. Nevertheless, we found that the ORD... [Pg.277]

Jones also tested the reactivity of neutral group 13 trihydride reagents toward the 1,3,5-triphosphinine. The reaction of 3equiv [AlH3(NMe3)] with the heterocycle in diethyl ether afforded a mixture of the crystalline compounds 32, 33, and 34. They could not be separated on a preparative scale but crystals of pure 33b and 34 could be selected and characterized by X-ray analyses (Scheme 12). [Pg.702]

Anodic oxidation of graphitic materials in H2SO4 is also used as a test reaction to characterize their degree of orientation and defect concentration" ". Ether-solvated... [Pg.438]

The use of reagents that would reveal the presence of an ether would be useless in this case. Both compounds would give a positive test. Note, however, that diallyl ether contains carbon-carbon double bonds. It is unsaturated. An excellent method for characterizing carbon-carbon double bonds is by using a solution of bromine in carbon tetrachloride, which has a reddish color. The bromine will add across the double bond, thereby decolorizing the solution. Since the diisopropyl ether lacks a double bond, it will not decolorize the Bra/CClij solution. Hence, the two ethers may be distinguished on this basis. [Pg.612]

Polymer Testing 19, No.4, 2000, p.415-7 CHARACTERIZATION OF POLYEPICHLOROHYDRIN AND COPOLYMERS OF EPICHLOROHYDRIN-GYLICIDYL ETHERS BY IR SPECTROSCOPY Glavcheev I Sirashki G Mateva R Sofia,University of Chemical Technology ... [Pg.49]

Ketosteroids may be converted to enol—TBDMS ether derivatives with t-butyidimethyliodosilane as a catalyst [103]. Steroid enol-TBDMS and mixed TBDMS-TMS derivatives have been appiied to the analysis of steroids in rat testes [104]. The enol-TBDMS mass spectra are characterized by the presence of intense M ions. [Pg.312]

Chemical Tests, Qualitative chemical tests can also be used to assist in characterizing this compound as an ether. Perform the ignition test (Table 9.1) to determine whether the material contains an aromatic ring. [Pg.324]

This history clearly shows how the development of flash point test methods and testers was matched to the character of the fluid being tested. Today, D56-18T (or its current embodiment) is used to characterize not volatile hydrocarbons, but mixtures of water and alcohol, HCFCs/ HFCs/HFEs (Ref. 3, Chapter 22) and alcohols/hydrocarbons, multiple HCFCs/HFCs/HFEs, chlorinated and brominated hydrocarbons (Ref. 3, Chapters 20 and 21), mixtures of HCFCs/HFCs/HFEs and chlorinated hydrocarbons, and high-boiling alcohols/glycol ethers (Ref. 3, Chapter 14). All of these materials are separately used to clean parts. [Pg.8]


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