Camphorated phenol

Naphthol Antipyrine, camphor, phenol, iron(III) salts, menthol, oxidizing materials, permanganates, urethane... 

Methyl methacrylate 4-Methylnitrobenzene 2- Methylpyridine Methylsodium Molybdenum trioxide Naphthalene 2-Naphthol Air, benzoyl peroxide Sulfuric acid, tetranitromethane Hydrogen peroxide, iron(II) sulfate, sulfuric acid 4-Chloronitrobenzene Chlorine trifluoride, interhalogens, metals Chromium trioxide, dinitrogen pentaoxide Antipyrine, camphor, phenol, iron(III) salts, menthol, oxidizing materials, permanganates, urethane... 

B) Gunther, P., Peiser, M., Z. physik. Chem., 128, 189 (1927). Camphor-Phenol. 

Jncompal Butylchloral hydrate, camphor, phenol, chloral hydrate, Exalgine, betanaphthol, resorcinol or thymol in triturations potassium permanganate, chromium trioxide, pyrogaUol. 

Incompat. Bromine water, ferric salts camphor, mono-bromated camphor, phenol, chloral hydrate, thymol or ure-tltan in trituration. 

White, odorless Crystals, mp 131-133. Becomes grayish on exposure to air and light. Poisonous d 1.45 bp 309. Sublimes when slowly heated. One gram dissolves in 1.7 ml water, 1.3 ml ale, 1.6 ml ether slightly sol in benzene, chloroform, carbon disulfide. The aq soln darkens on exposure to air, quite rapidly when alkaline. Keep well closed and protected from tight. Incompat. Alkalies, ammonium hydroxide. antipyrine. camphor, phenol, menthol. LDH orally in rabbits 1.6 g/kg (Dollahite). 

Yellow, visdd, fluorescent, oily liquid, bp above 280r. Insol in water sol in ether, oil turpentine and other oils. It dissolves phosphorus, sulfur, camphor, phenols, and many other organic compds. 

Systemic toxins Camphor, phenol, halogenated, or aromatic compounds High High Observe for pneumonia perform gastric lavage or give activated charcoal or do both. 

A. Bystrom, R. Claesson, G. Sundqvist, The antibacterial effect of camphorated para-monochlorophenol, camphorated phenol and calcium hydroxide in treatment of infected root canals, Endod. Dent. Traumatol. 1 (1985) 170-175. 

Camphorated Phenol Organic volatile impurities. Method V < 467 > Assay P... 

The first plastic was celluloid, made of nitrocellulose softened by vegetable oils and camphor. It was used for car windshields and for movie film. The first completely synthetic plastic was bakelite (1910) produced from phenol and formaldehyde for use in the electrical industry. 

Solids. —It may Idc a hydrocM bon (c .g., paraffin wa, naphthalene) highei alcohol eg., cetyl alcohol) aldehyde e.g., z5-hydroxybenzaldehyde) ketone and qiiinonc e.g., benzo-phenone, camphor) acid (higher fatty, e.g., palmitic acid or aromatic acid) ester (of glycerol, phenols or aromatic alcohols) phenol e.g., thymol),... 

It is soinble in about 1 volumes of IQ 24 volumes of "0 per cent, alcohol. I /H-piuene and tracea ot salicylic aud honicol was cousidered probable, but Phellaudrecc was not present, and u aldehydes or ketones, phenols or camphor. The chief conatitnent pinene, a mixture of the dextro-aud laevo-rotatory vatielief... 

Essential oils are known to have detrimental effects on plants. The inhibitory components have not been identified, but both alde-hydic (benzol-, citrol-, cinnamal-aldehyde) and phenolic (thymol, carvacol, apiol, safrol) constituents are suspected. Muller et al. (104) demonstrated that volatile toxic materials localized in the leaves of Salvia leucophylla, Salvia apiana, and Arthemisia californica inhibited the root growth of cucumber and oat seedlings. They speculated that in the field, toxic substances from the leaves of these plants might be deposited in dew droplets on adjacent annual plants. In a subsequent paper, Muller and Muller (105) reported that the leaves of S. leucophylla contained several volatile terpenes, and growth inhibition was attributed to camphor and cineole. 

Uses A mixture of cis and trans isomers is used as a solvent for fats, phenols, camphor ingredient in perfumes low temperature solvent for sensitive substances such as caffeine refrigerant organic synthesis. 

Indenopyrene, see Indeno[l,2,3-crf pyrene l//-Indole, see Indole Indolene, see Indoline Inexit, see Lindane Inhibisol, see 1,1,1-Trichloroethane Insecticide 497, see Dieldrin Insecticide 4049, see Malathion Insectophene, see a-Endosulfan, p-Endosulfan Intox 8, see Chlordane Inverton 245, see 2,4,5-T lodomethane, see Methyl iodide IP, see Indeno[l,2,3-crf pyrene IP3, see Isoamyl alcohol Ipaner, see 2,4-D IPE, see Isopropyl ether IPH, see Phenol Ipersan, see Trifluralin Iphanon, see Camphor Isceon 11, see Trichlorofluoromethane Isceon 122, see Dichlorodifluoromethane Iscobrome, see Methyl bromide Iscobrome D, see Ethylene dibromide Isoacetophorone, see Isophorone a-Isoamylene, see 3-Methyl-l-butene Isoamyl ethanoate, see Isoamyl acetate Isoamylhydride, see 2-Methylbutane Isoamylol, see Isoamyl alcohol Isobac, see 2,4-Dichlorophenol Isobenzofuran-l,3-dione, see Phthalic anhydride 1,3-Isobenzofurandione, see Phthalic anhydride IsoBuAc, see Isobutyl acetate IsoBuBz, see Isobutylbenzene Isobutane, see 2-Methylpropane Isobutanol, see Isobutyl alcohol Isobutene, see 2-Methylpropene Isobutenyl methyl ketone, see Mesityl oxide Isobutyl carbinol, see Isoamyl alcohol Isobutylene, see 2-Methylpropene Isobutylethylene, see 4-Methyl-l-pentene Isobutyl ketone, see Diisobutyl ketone Isobutyl methyl ketone, see 4-Methyl-2-pentanone Isobutyltrimethylmethane, see 2,2,4-Trimethylpentane Isocumene, see Propylbenzene Isocyanatomethane, see Methyl isocyanate Isocyanic acid, methyl ester, see Methyl isocyanate Isocyanic acid, methylphenylene ester, see 2,4-Toluene-diisocyanate... 

Oxitol, see 2-Ethoxyethanol Oxitol acetate, see 2-Ethoxyethyl acetate 2-Oxobornane, see Camphor Oxocyclohexane, see Cyclohexanone Oxolane, see Tetrahydrofuran Oxomethane, see Formaldehyde Oxybenzene, see Phenol 1,1 Oxybisbenzene, see Phenyl ether l,l -Oxybis(2-chloroethane), see Bis(2-chloroethyl) ether Oxybis(chloromethane), see s/m-Dichloromethyl ether 2,2 -Oxybis(l-chloropropane), see Bis(2-chloroisopropyl) ether... 

For a ferric hydroxide suspension they obtained an increase in sensitivity on the addition of both isoamyl alcohol and phenol to both univalent and divalent anions, whilst Freundlich and Eona (Bioohem. Zeit lxxxi. 87, 1917) have noted similar effects on this suspension on the addition of many other capillary active nonelectrolytes such as the urethanes, camphor and thymol. 

Terpenes are polymers of the 5-carbon compound isoprene (Figure 1.12) and, as such, generally display properties similar to those of hydrocarbons. Terpenoids are substituted terpenes (i.e. contain additional chemical groups, such as an alcohol, phenols, aldehydes, ketones, etc.). Only a few such substances could be regarded as true drugs. Terpenes, such as limonene, menthol and camphor, form components of various essential oils with pseudo-pharmaceutical uses. A number of these molecules, however, exhibit anti-tumour activity, of which taxol is by far the most important. 

Synonym Liquid Hydrogen Liquid Impure Camphor Liquid Nitrogen Liquid Nitrogen Dioxide Liquid Oxygen Liquid Petrolatum Liquified Phenol Litharge... 

Phenol Antimicrobial preservative disinfectant (not oral) Camphor, menthol, thymol, acetaminophen, phenacetin, chloral hydrate, phenazone, ethyl aminobenzoate, methenamine, phenyl salicylate, resorcinol, terpin hydrate, sodium phosphate, or other eutectic formers. Phenol also softens cocoa butter in suppository mixtures... 

Menthol 0.003-0.015% in suspensions, and syrups Cooling effect Sublimes easily above 25° C and composition of natural oil may vary with source Incompatible with thymol, phenol, camphor, and other excipients Slightly soluble in glycerin very soluble in alcohol... 

Tor a viseosimetrio examination of the influence of certain organic substances ( .transformation temperature, see Mondain-Monval and Schneider, Cornet, rend., 1928, 186, 751. 

Many aromatic hydrocarbons, for example, benzene, ethylbenzene, toluene, cymene and tetrahydronaphthalene, yield additive compounds.5 Such are also formed with liquid cyclic hydrocarbons in the absence of moisture and phenols, and use has been made of this fact to remove sulphur dioxide from a dry gas containing it.6 Additive compounds are also formed with methyl alcohol, thus CH30H.S02 and 2CH30H.S02, the existence of which has been demonstrated definitely by means of the freezing-point curve.7 The additive compound with camphor has already been mentioned (p. 109). 

Wynberg studied stereochemistry of the McMurry reductive dimerization of camphor in detail (64). In Scheme 37, A and B are homochiral dimerization products derived by the low-valence Ti-promoted reduction, while C and D are achiral heterochiral dimers. The reaction of racemic camphor prefers homochiral dimerization (total 64.9%) over the diastereomeric heterochiral coupling (total 35.1 %). Similarly, as illustrated in Scheme 38, oxidative dimerization of the chiral phenol A can afford the chiral dimers B and C (and the enantiomers) or the meso dimer D. In fact, a significant difference is seen in diastereoselectivity between the enaritiomerically pure and racemic phenol as starting materials. The enantiomerically pure S substrate produces (S,S)-B exclusively, while the dimerization of the racemic substrate is not stereoselective. In the latter case, some indirect enantiomer effect assists the production of C, which is absent in the former reaction. Thus, it appears that, even though the reagents and reaction conditions are identical, the chirality of the substrate profoundly affects the stability of the transition state. 

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