Calibration humidity effects

Here the relevant limits of 25 ppm room concentration and 270 ppm in the cleaner before door is opened can easily be detected. Compared with the semiconductor gas sensors, humidity only changes the zero point for the measurements not the slope of the calibration curve. Figure 26 shows the humidity effect on a conductometric ethanol microsensor. Thus any placement of the sensor in... 

False negative alarms occur when instruments fail to respond to targeted chemicals that are present in a sample. These responses are viewed as more problematic than false positive alarms, because failure to produce a necessary alarm may lead to dangerous/disastrous situations. Causes of false negative alarms include changing environmental conditions humidity effects presence of interfering chemicals that mask normal detection capabilities and detector malfunction, such as improper calibration and detection algorithm deviations. 

The detector is designed to serve as an on-the-spot monitor for the presence of CWAs, TICs, or other ohemioals within seconds. The instrument is sensitive to external vibration and humidity effects, and requires calibration in each operating environment immediately before use. 

Series 8 in combination with earlier series was intended to provide data on the effects of total anion concentration. The results are internally consistant with the correlation, having a standard deviation of about 15% around the mean error. However the measured values of PSO2 were about 40% lower than the general correlation. An SO2 analyzer, rather than iodine titration, was used to determine SO2 gas concentration from the saturator. The analyzer was calibrated with dry SO2/N2 span gas. In later experiments it was shown that humid gas gives a lower analyzer response. With constant fraction neutralization increased anionic concentration increases PSO2 because pH decreases faster than effective bisulfite activity. 

The standard conditions are (a) 23°C and 50% relative humidity, and (b) 27°C and 65% humidity, with the latter condition intended for use in tropical countries. Where control of temperature only is required, this is either 23°C or 27°C, and a further atmosphere where neither temperature nor humidity need be controlled is defined as prevailing ambient temperature and humidity. A note drawing attention to the atmosphere 20°C and 65% relative humidity which was used for textiles is no longer included. The normal tolerances are 2°C on temperature and 10% on relative humidity however, provision is made for closer tolerances, if required, of 1 °C and 5% relative humidity. This is a welcome change from previous conditions when the standard humidity tolerances of 5% and 2% were unreasonable in that 2% is virtually impossible to achieve and 5% debatable. It should be noted that 20°C is the usual temperature for calibration laboratories although in most cases the three degree difference will not have a significant effect. 

We select 3% residual humidity as the optimum level for Xj on the basis of tablet hardness and cohesion. Calibration had no effect, so 1.25 mm is chosen. Lubrification time also had little effect and 3 minutes seemed to be optimum for tablet hardness. This value was therefore selected for plotting. We take therefore ... 

Thermal desorption Method development was done with sample amounts of 50-100 mg. The use of larger sample amounts can overload the injection system and the capillary column. Drying of the sample prior to thermal extraction is necessary because problems with humidity content of the soil and other matrix effects can happen. Variations of the parameters desorption time and desorption temperature lead to an optimized method. The calibration curve in the range from 1-100 ppm shows a good linearity with relative standard deviations of about 5-7% (Fig. 11). These values are higher compared to liquid extraction due to the inhomogeneity of the soil samples. An additional homogenization of the samples reduced the relative standard deviation to about 2-3%. 

Polymer films or plates containing certain dyes that change color when irradiated are well known as dosimeters. The thickness of the dosimeters must be taken into account during evaluation, so that the response of each dosimeter is the absorption divided the thickness. In most cases, the radiation-induced response is nonlinear with absorbed dose and it is affected by temperature, humidity, hght, and dose rate. Due to the combined effects of these factors and other environmental factors, careful calibration of these systems preferably using in-plant calibration is needed (Miller et al. 1975 McLaughlin 1978). 

As it was already mentioned above, environmental factors such as humidity and temperature have an effect on the spot size. By conducting a two-point calibration between 5 and 20 mM glucose, the spot size assay can be adjusted to the actual environmental conditions which can be quite extreme in tropical countries. 

We present a quantitative study of frictional properties of pure self-assembled monolayers (SAMs) of alkanethiols as a function of chain length and mixed SAMs of dodecanethiol and 11-mercapto-l-undecanol as a function of surface composition on Au (111) using atomic force/friction force microscopy (AFM/FFM). The lateral and normal forces were calibrated in situ using a combined two-slope and added-mass method. Molecular dynamics simulations were also carried out to interpret the chain length dependence of frictional properties of alkanethiols. We then extended the in situ force calibration method to the mixed SAMs and investigated the effects of chemical nature and relative humidity on the frictional properties. Friction coefficients were plotted as a function of surface composition with different relative humidity. Such a plot could serve as a reference in determining surface composition in a nanoscale domain by measuring its friction coefficient. 

As previously mentioned, the calibration accuracy specification on high-performance instruments applies to the direct readout element of the monochromator, which is usually a counter or a dial. The large-size-chart abscissa scales generally used with these instruments limit the accuracy on the chart itself more severely due to the humidity sensitivity of even high-grade recorder paper, which affects the dimensional stability. Sprocket-driven strip-chart recorders tend to be self-compensating for this effect. For less versatile instruments, the recorder paper itself, usually with a smaller abscissa scale, is used as the abscissa reference. 

The reading on an instrument will be affected by imperfections in components in the instrument. If it is an electromechanical device, these errors will be due to magnetic hysteresis, friction, and tolerances on the sizes, assembly, and purity of the components. Likewise, for an electronic instrument, tolerances on components, assembly, and hysteresis of operation of the various circuits will affect the operation. In both types of instrument, ai r changes in the environment (temperature, humidity, and possibly pressure) will have an effect on the performance. Since many materials change their properties slightly with age (and continual use), it is necessary to consider the effect of age on the performance of an instrument. Since this is difficult to predict, it is essential that instruments be checked (calibrated) at regular intervals, for example, once a year, but preferably every 6 months. From the records (history) of instruments, confidence in the performance of a particular instrument is maintained. 

The effect of humidity on the determination of concentrations is compound specific. To incorporate the humidity factor into the calibration process de Gouw and co-workers [10] have suggested that the ratio... 

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