Cadmium Acetylide

Cadmium AcetylIde, CdCj(formula is not definitely established). It was prepd by passing pure dry CjHa over pulverized Cd at ca SOO tRefs 1 2 ).Gebauer (Ref 3 ) prepd twoiderivs, CdCa. QHj. Cdla and CdCj. CjHj, both of which partially decomp d by hot w but were stable in the air even at 200°... [Pg.71]

Cadmium Acetylide A71-L Cadmium Amide A169-L Cadmium Azide A526-L Cadmium Azidodithiocarbonate A636-R Cadmium Diazide A526-L Calcium Acetate A28-L Calcium Acetylide A71-L Calcium Azide A527-R Calcium Carbide. See under Acetylides and Carbides A71-R... [Pg.679]

Organometallics, such as dialkyl zinc or cadmium-alkyl or aryl lithium Alkali acetylides Diels-Alder Arndt-Eistert... [Pg.254]

A novel cadmate complex has been formed by the reaction of Cd(NH2>2 with I C=CH in the presence of acetylene in liquid ammonia.250 The potassium salt, K2Gd(CCH)4-2NH3 191, has been structurally characterized. The cadmium center is tetrahedrally coordinated to four acetylide units with which it forms Cd-C bonds of 2.23-2.25 A (Figure 29). The acetylide ligands are 7r-coordinated to two crystallographically distinct potassium ions whose coordination sphere is completed by two ammonia molecules. [Pg.465]

MOLECULAR SIEVE INCIDENTS ethylene ORGANIC POWDER HANDLING PEROXIDES IN SOLVENTS SOLVATED OXOSALT INCIDENTS Cadmium propionate, 2418 Calcium acetylide Methanol Diazomethane Calcium sulfate, 0406 3,5 -Dinitrotoluamide... [Pg.131]

Cadmium propionate, 2412 Calcium acetylide Methanol, 0582 Diazomethane Calcium sulfate, 0405 3,5-Dinitrotoluamide, 2936 Lithium tetrahydroaluminate Dioxane, 0075 Magnesium perchlorate, 4078 Magnesium Methanol, 4685 Mercury(II) thiocyanate, 0975 Silicon dioxide Hydrochloric acid, 4833 Sodium azide Heavy metals, 4753 Sodium Halocarbons (reference 10), 4790... [Pg.2318]

Bowden and Singh [37,38] irradiated lead, cadmium, silver, and lithium azides and silver acetylide with a-particles but failed to cause explosion in any... [Pg.212]

ESTANO (Spanish) (7440-31-5) Finely divided material is combustible and forms explosive mixture with air. Contact with moisture in air forms tin dioxide. Violent reaction with strong acids, strong oxidizers, ammonium perchlorate, ammonium nitrate, bis-o-azido benzoyl peroxide, bromates, bromine, bromine pentafluoride, bromine trifluoride, bromine azide, cadmium, carbon tetrachloride, chlorine, chlorine monofluoride, chlorine nitrate, chlorine pentafluoride, chlorites, copper(II) nitrate, fluorine, hydriodic acid, dimethylarsinic acid, ni-trosyl fluoride, oxygen difluoride, perchlorates, perchloroethylene, potassium dioxide, phosphorus pentoxide, sulfur, sulfur dichloride. Reacts with alkalis, forming flammable hydrogen gas. Incompatible with arsenic compounds, azochloramide, benzene diazonium-4-sulfonate, benzyl chloride, chloric acid, cobalt chloride, copper oxide, 3,3 -dichloro-4,4 -diamin-odiphenylmethane, hexafluorobenzene, hydrazinium nitrate, glicidol, iodine heptafluoride, iodine monochloride, iodine pentafluoride, lead monoxide, mercuric oxide, nitryl fluoride, peroxyformic acid, phosphorus, phosphorus trichloride, tellurium, turpentine, sodium acetylide, sodium peroxide, titanium dioxide. Contact with acetaldehyde may cause polymerization. May form explosive compounds with hexachloroethane, pentachloroethane, picric acid, potassium iodate, potassium peroxide, 2,4,6-trinitrobenzene-1,3,5-triol. [Pg.503]