Magnesium methanol

See Aluminium Methanol Magnesium Methanol Potassium (Slow oxidation)... 

Lithium tetrahydroaluminate Dioxane, 0075 Magnesium Methanol, 4690 Magnesium perchlorate, 4084 Mercuiy(II) thiocyanate, 0979 Silicon dioxide Hydrochloric acid Sodium Halocarbons (reference 10)... 

Nitrogenous bases Lead(lV) oxide, Carbon black. Chlorinated paraffin Manganese(lV) oxide Magnesium, Methanol Mercury(l) azide... 

Base-catalyzed transformations can be carried out elsewhere on a complex molecule in the presence of such protected -dicarbonyl magnesium chelate. For example, the chelated magnesium enolate of a /3-ketoester such as 71 prevents the carbonyl keto group becoming an acceptor in aldol condensations. However, in the presence of excess of magnesium methanolate, exchange of the acetyl methyl protons can occur via a carbanion 72 stabilized by delocalization into the adjacent chelate system (equation 99). 

Among the metallic reducing systems [42a, b] which have been suggested are magnesium with anhydrous methanol [42a], and an alloy of sodium and lead (sold as Drynap ) in ethanol [43, 44], In the case of the magnesium-methanol reduction, the product mixture usually contains azoxy-, azo-, hydrazo-, amino-, and hydroxylamine products, although approximately 75% of the product consists of a mixture of azoxy and azo compounds. The Dry-nap reduction also seems to lead frequently to mixtures of azoxy and azo compounds. 

Reductions. Magnesium methanol has been used for selective reduction of a,/ -unsaturated nitriles (6, 351) and amides1 and of 1,1- and 1,2-diphenyl-substituted ethylenes.2... 

Desulfonylation Lithium-Ammonia, 158 Lithium triethylborohydride, 168 Magnesium-Methanol, 170 Sodium dithionite, 281 Sodium naphthalenide, 294 Desulfurization Lithium aluminum hydride-Bis(cyclopentadienyl)nickel, 158 Lithium l-(dimethylamino)naph-thalenide, 165 Lithium-Ethylamine, 158 Dethioacetalization (see Hydrolysis of thioacetals and -ketals)... 

Magnesium-Methanol, 170 Miscellaneous reductions Cyanotrimethylsilane, 87 Nickel boride, 197 B -3-Pinany 1-9-borabicy clo[3. 3.1 ]no-nane, 249... 

Magnesium iodide, 171 Magnesium-Methanol, 170 Magnesium methoxide, 352 Methallylmagnesium chloride, 139 Methylmagnesium bromide, 139, 195, 203, 214, 322... 

Aluminum (or Magnesium)-Methanol (or Water) Explosives. According to Shidlovskii (Ref l),mixts of Al and H40(2 3) or Mg and HjO( 1 1) are capable of combustion when subjected to intense heat. The Mg mixture can be detonated with a primer while the Al mixt cannot. The same investigator claimed (Ref 2) that on the basis of theoretical calcns of.heat evoln, mixtsof Mg or Al with H,0 or ales are potentially more powerful expls that the usual military materials, with.Mg-MeOH giving the max gas evoln. The tests were conducted in bombs or lead enclosures with tetryl detonators to set off the mixts of powdered metal and the liquid. All mixts tested were found to be powerful expls with Mg-HjO being most sensitive to shock, while Al-HjO and Mg-MeOH were less sensitive and required a booster... 

See Butanol Methanol both above See Magnesium Methanol... 

Cadmium propionate, 2412 Calcium acetylide Methanol, 0582 Diazomethane Calcium sulfate, 0405 3,5-Dinitrotoluamide, 2936 Lithium tetrahydroaluminate Dioxane, 0075 Magnesium perchlorate, 4078 Magnesium Methanol, 4685 Mercury(II) thiocyanate, 0975 Silicon dioxide Hydrochloric acid, 4833 Sodium azide Heavy metals, 4753 Sodium Halocarbons (reference 10), 4790... 

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