Cadmium Amide

In contrast, the number of known structures of homoleptic, monomeric two-coordinate amides of cadmium is currently limited to just one example. The structure of the compound [Cd N(SiMe3)2 2] has been determined by electron diffraction and the data showed that it has a linear NCdN skeleton with a Cd—N bond length of 2.03(2) A. It is clear, however, that several other homoleptic cadmium amides (known and others as yet not synthesized) can be predicted to have monomeric structures in the solid state. For example Cd NMR studies of amides such as [Cd N(SiMe3)2 2] or [Cd N(SiMe2Ph)2 2] indicate that they are... 

Cadmium Amide, CdCNHj) wh powder expl when rapidly heated. Can be prepd by treating Cd iodide or KCd cyanide with a soln of potassamide in liq NHS... 

Cadmium Amide. See Vol l,p A169-L Note According to Jacobson 2(1948),17, Cd(NH2)2expl on rapid heating above its mp(180o)... 

Cadmium Acetylide A71-L Cadmium Amide A169-L Cadmium Azide A526-L Cadmium Azidodithiocarbonate A636-R Cadmium Diazide A526-L Calcium Acetate A28-L Calcium Acetylide A71-L Calcium Azide A527-R Calcium Carbide. See under Acetylides and Carbides A71-R... 

Cadmium amide, 3948 Cadmium azide, 3951 Cadmium, 3943 Cadmium chlorate, 3946... 

CADMIUM AMIDE see CAD325 CADMIUM AZIDE see CAD350 CADMIUM BARIUM STEARATE see BAI800 CADMIUM BIS(N-AMYLDITHIOCARBAMATE) see CAD550... 

CadiTiiuni Acerylide A7I-L Cadmium Amide A169-L Cadmium Azide A52frL... 

Cadmium amide, Cd(NH3)g, is thermally decomposed in a vapor pressure eudiometer (see Part I, p. 102) at 180 °C while repeatedly removing measured amounts of NH3. The evolution of NH3 ceases after about 36 hours. The Cd3N3 product decomposes if the temperature is raised higher. 

Fig. 283. Preparation of cadmium amide, h and k pinch clamps 1 storage vessel for ammonia m glass slug n glass bulbs.

A series of cadmium amides C(R Si)2H32Cd and their complexes (R Me) with... 

Cadmium amide, Cd(NH3), is a white powder which explodes upon rapid heating. The salt can be prepared by treating cadmium iodide or KCd cyanide with a solution of potassamide in liquid ammonia. When heated to 180°C in vacuo, cadmium amide loses ammonia leaving cadmium nitride, Cd3N2, a black, amorphous powder that explodes when brought in contact with water. 

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