Lithium tetrahydroaluminate,

See Dibenzoyl peroxide Lithium tetrahydroaluminate Hydrazine Oxidants REDOX REACTIONS ROCKET PROPELLANTS... 

Presence of carbon dioxide in solutions of the hydride in dimethyl or bis(2-methoxy-ethyl) ether can cause a violent decomposition on warming the residue from evaporation. Presence of aluminium chloride tends to increase the vigour of decomposition to explosion. Lithium tetrahydroaluminate may behave similarly, but is generally more stable. 

Tetrahydro-l-naphthyl hydroperoxide See 1,2,3,4-Tetrahydro-l-naphthyl hydroperoxide Lithium tetrahydroaluminate... 

Addition of nitromethane to ethereal lithium tetrahydroaluminate solution at ambient temperature gave an explosively violent rection [1], and this was confirmed when addition of 0.5 ml of dry nitromethane to 10 ml of reducant solution led, after 30 s, to a violent explosion which pulverised the flask [2]. The violence of the explosion suggests that lithium ad-nitromethanide (or possibly lithium fulminate) may have been involved. 

Lithium tetrahydroaluminate See Lithium tetrahydroaluminate Ethyl acetate... 

Of a series of lithium hydrocuprates Li CuH +i (n = 1-5), only the title compound (when solvated with THF) appeared a more powerful reducant than lithium tetrahydroaluminate. Safety precautions similar to those adopted for the complex aluminium hydride seem appropriate. 

Heptafiuorobutyramide [662-50-0] F7C3CO.NH2 Lithium tetrahydroaluminate See Lithium tetrahydroaluminate Fluoroamides c4h2f7no... 

Tetrahydrofuran is distilled before use, in a nitrogen atmosphere, from lithium tetrahydroaluminate. A 1-1. threenecked flask equipped with a mechanical stirrer, reflux condenser,... 

The use of lithium tetrahydroaluminate for drying ethers can lead to explosions. It is essential that the distillation not be continued to a point where the volume of remaining solvent is low. The distillation must be effected in an inert atmosphere (nitrogen or argon). 

The iron(II) chloride7 is prepared from 1.5 g. (0.0268 mol) of iron powder (hydrogen-reduced, 100-mesh), 6.0 g. (0.370 mol) of anhydrous sublimed iron(III) chloride (Matheson, Coleman and Bell, reagent-grade), and 150 ml. of tetrahydrofuran (THF) freshly distilled under nitrogen from lithium tetrahydroaluminate or preferably calcium hydride. 

The required working time is 3 to 4 hours. All equipment is thoroughly dried prior to use and is flushed with an inert gas (argon or nitrogen). Commercial sodium hydroborate is used without purification. The dimethyl ether of diethylene glycol (diglyme) is refluxed over calcium hydride for 8 hours and subsequently distilled over lithium tetrahydroaluminate (lithium aluminum hydride). Commercial tri-n-butylamine is refluxed with acetic anhydride and distilled at atmospheric pressure. 

Lithium tetradeuteroaluminate, 0069 Lithium tetrahydroaluminate, 0075 Lithium tetrahydroborate, 0145 Lithium tetrahydrogallate, 4407 Magnesium tetrahydroaluminate, 0085 Manganese(II) tetrahydroaluminate, 0086 Potassium hexahydroaluminate(3—), 0077 Potassium tetrahydrozincate, 4516 Potassium trihydomagnesate... 

Lithium tetrahydroaluminate Dioxane, 0075 Magnesium Methanol, 4690 Magnesium perchlorate, 4084 Mercuiy(II) thiocyanate, 0979 Silicon dioxide Hydrochloric acid Sodium Halocarbons (reference 10)... 

Lithium, 1,2-Diaminoethane, Tetralin, 4680 Lithium tetrahydroaluminate, Fluoroamides, 0075 Lithium tetrahydroaluminate, Water, 0075 Magnesium, Barium carbonate, Water, 4690 Maleic anhydride, Bases, or Cations, 1404 Mercaptoacetonitrile, 0767... 

Ammonium acz-nitromethanide, 0504 Dipotassium acz-nitroacetate, 0672 Mercury(II) acz-dinitromethanide, 0707 Nitromethane, Lithium tetrahydroaluminate, 0456... 

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