Borosilicate

Much can be done with such standard apparatus in borosilicate glass as — Round-bottomed flasks 5 ml., 10 ml. and 25 ml. 

Boric acid is also an important boron compound with major markets in textile products. Use of borax as a mild antiseptic is minor in terms of dollars and tons. Boron compounds are also extensively used in the manufacture of borosilicate glasses. Other boron compounds show promise in treating arthritis. 

The best replacement for borosilicate glassware is stainless steel. Stainless steel takes the heat, won t break, and, most importantly, is about as resistant to chemical degradation as the chemist can hope to find. For those items that won t be subjected to direct heat there can be some steel/metal or steel/plastic hybrids. In figure 3 is shown how flasks of any size can be made with two stainless steel mixing bowls welded together. Also shown is the vacuum adaptor and condenser. For the condenser only the inner pipe need be steel. The outside pipe can be copper or something. As for the other components of a distillation set up, well, they are made just as they look. 

These borosilicate glasses may rate differently if subjected to excessive heat treatment. 

Fig. 11. Index of refraction vs dispersion and optical classification of glasses. The shaded area indicates the region of glass formation. BaF = barium flint BaK = barium crown BaLF = light barium flint BaSF = heavy barium flint BK = borosilicate crown F = flint FK = fluorcrown K = crown ...

BSG = borosilicate glass PSG = phosphosilicate glass MOS = metal oxide semiconductor. 

Fractionally distd, then 35mL was sealed with about 7g KOH pellets in a borosilicate glass ampoule and heated at 135° for 48h. The ampoule was cooled and opened, and the liquid was resealed with fresh KOH in another ampoule and heated as before. This process was continued until no further decomposition was observed. The substance was then washed with distilled water, dried (CaS04) and distd. [Grafslein Anal Chem 26 523 1954.]... 

Soda-lime glass Borosilicate glass 70 SiOj, 10 CaO, 15 Na O 80 SiOj, 15 BjOj, 5 NajO Windows, bottles, etc. easily formed and shaped. Pyrex cooking and chemical glassware high-temperature strength, low coefficient of expansion, good thermal shock resistance. 

PVC, polythene and PTFE if moist gas is used Stainless steel, copper, nickel. Monel, brass, aluminium for dry gas <200°C. Borosilicate glass for low pressures. For moist gas, copper and polyvinylidene chloride plastics Monel and nickel Monel and nickel Most common metals so long as gas is dry... 

The carbon bed can be supported by glass wool, wire cloth, etc. Columns and fixtures can be constructed from glass, plastic, reinforced fiberglass, or metal. Borosilicate glass is commonly used. It is essential that all columns used in the pilot system have at least the same internal diameter. 

By virtue of its chemical and thermal resistances, borosilicate glass has superior resistance to thermal stresses and shocks, and is used in the manufacture of a variety of items for process plants. Examples are pipe up to 60 cm in diameter and 300 cm long with wall tliicknesses of 2-10 mm, pipe fittings, valves, distillation column sections, spherical and cylindrical vessels up 400-liter capacity, centrifugal pumps with capacities up to 20,000 liters/hr, tubular heat exchangers with heat transfer areas up to 8 m, maximum working pressure up to 275 kN/m, and heat transfer coefficients of 270 kcal/hz/m C [48,49]. 

Because borosilicate is a brittle material, its design stress is restricted to less than 7 N/mm. Borosilicate glass is attacked by hydrofluoric acid even when a solution contains only a few parts per million of fluoride ions, and at... 

Glass in the form of fibres is relatively inexpensive and is the principal form of reinforcement used in plastics. The fibres are produced by drawing off continuous strands of glass from an orifice in the base of an electrically heated platinum crucible which contains the molten glass. The earliest successful glass reinforcement had a calcium-alumina borosilicate composition developed... 

Four column systems are available from Amersham Pharmacia Biotech that can be used to pack SEC media for various applications at the laboratory scale. These include C, XK, SR, and HR column systems. All of the laboratory-scale columns are constructed with borosilicate glass tubes. Columns for larger scale process applications include INdEX, BPG, EineLINE, BPSS, and Stack columns. The larger scale columns are constructed to meet stringent validation requirements for the production of biopharmaceuticals. Each of the column types are described. 

---