Bode

Introducing the complex notation enables the impedance relationships to be presented as Argand diagrams in both Cartesian and polar co-ordinates (r,rp). The fomier leads to the Nyquist impedance spectrum, where the real impedance is plotted against the imaginary and the latter to the Bode spectrum, where both the modulus of impedance, r, and the phase angle are plotted as a fiinction of the frequency. In AC impedance tire cell is essentially replaced by a suitable model system in which the properties of the interface and the electrolyte are represented by appropriate electrical analogues and the impedance of the cell is then measured over a wide... 

Bode, W., Papamokos, E., Musil, D. The high-resolution X-ray crystal structure of the complex formed between subtilisin Carlsberg and eglin c, an elastase inhibitor from the leech Hirudo medicinalis. Eur. J. Biochem. 166 (1987) 673-692... 

D, H W Hoeffken, D Crosse, J Stuerzebecher, P D Martin, B F P Edwards and W Bode 1992. Refined 2.3 Angstroms X-Ray Crystal Structure of Bovine Thrombin Complexes Formed witli he 3 Benzamidine and Arginine-Based Thrombin Inhibitors NAPAP, 4-TAPAP and MQPA A Starting Point for Improving Antithrombotics. Journal of Molecular Biology 226 1085-1099. 

Because of the chemical inertness of the paraffin hydrocarbons and of the closely related cycZoparaffins, no satisfactory crystalline derivatives can be prepared. Reliance is therefore placed upon the physical properties (boding point, density, and refractive index) of the redistilled samples. These are collected together in Table III,6. 

The low reactivity of aliphatic ethers renders the problem of the preparation of suitable crystalline derivatives a somewhat difficult one. Increased importance is therefore attached to the physical properties (boding point, density and refractive index) as a means for providing preliminary information. There are, however, two reactions based upon the cleavage of the ethers which are useful for characterisation. 

Maleic acid may be prepared by warming malic acid with acetyl chloride, distilling the mixture under atmospheric pressure to isolate maleic anhydride, and hydrolysing the latter by boding with water. 

For certain substituted amines, a higher temperature (e.g., boding 40-60 per cent, sulphuric acid) is necessary to decompose the diazonium salt completely, for example ... 

Concurrently with the preparation of the phenyldiazonium chloride solution, prepare a cold suspension of sodium arsenite. Place 250 ml. of water in a 3-htre round-bottomed flask equipped with a mechanical stirrer. Heat the water to boding, add 125 g. of anhydrous sodium carbonate, and, as soon as the carbonate has dissolved, introduce 62 5 g. of pure arsenious oxide and 3 g. of crystallised copper sulphate with stirring. When all the solids have dissolved, cool the solution with stirring under a stream of tap water until the temperature has fallen to 15°. 

Treat 0 1 g. of the quinone with dilute sodium hydroxide and zinc powder. Upon boding the mixture a red colour is produced this disappears when the solution is shaken owing to aerial oxidation to the original quinone. 

In a 1 htre round-bottomed flask, provided with an air condenser, place a mixture of 25 g. (26 ml.) of pure dimethylanihne, 10 g. of Michler s ketone (4 4 tetramethyldiaminobenzophenone) and 10 g. (6 ml.) of phosphorus oxychloride. Heat on a boding water bath for 5 hours. Add about 150 ml. of water and sufificient sodium hydroxide solution to render the solution alkaline. Calculate the quantity of sodium hydroxide required upon the basis of the hydrolysis product derived from the phosphorus oxychloride ... 

K. S. Narayanan and R. K. Chaudhuri, ia D. G. Chasia and L. E. Bode, eds., Fmulsifiahle Concentrate Formulationsfor Multiple Mctive Ingredients, Pesticide Formulations and Application Systems, Vol. 11 ASTM STP 1112, American Society of Testing and Materials, Philadelphia, Pa., 1990. 

Processes are usually carried out at atmospheric pressure, but use of temperatures higher than 25—75°C above that of the lowest boding component and at higher pressures can be carried out continuously at 0.5 MPa (5 bar) (166). 

H. Bode, LeadPladBattenes, John Wiley Sons, Inc., New York, 1976. 

H. Bode, K. Behmelt, and]. Witte, Crystal Structures of Nickel Hydroxides, ClTCE Meeting, Strashourg, France, 1965. 

H. Bode, Eead—Acid Batteries (translated by R. J. Brodd and K. V. Kordesch), John Wiley Sons, Inc., New York, 1977. 

Fig. 6. Temperatures for a three-mash method. The soHd line shows the temperature in the three-mashes that are boded. The dashed line shows the temperature in the rest or whole mash, as the temperature is brought from mashing-on to mashing-off...

Boric acid crystals are usually separated from aqueous slurries by centrifugation and dried in rotary driers heated indirecdy by warm air. To avoid overdrying, the product temperature should not exceed 50°C. Powdered and impalpable bode acid are produced by milling the crystalline matedal. 

The principal impurities ia technical-grade bode acid are the by-product sulfates, <0.1 wt %, and vadous minor metallic impurities present in the borate ores. A bode acid titer is not an effective measure of purity because overdrying may result in partial conversion to metabotic acid and lead to B(0H)2 assays above 100%. High putity bode acid is prepared by recrystallization of technical-grade matedal. 

Three grades of granular and powdered bode acid are manufactured in the United States. In July 1990, cadoad (ca 91 metric ton) prices per metric ton of granular boric acid were technical-grade, 805 NF-grade, 1562 and special quaHty-grade, 1892. AH prices are fob plant for matedal packed in 45.4-kg multiwaH sacks (33). 

Bode acid catalyzes the air oxidation of hydrocarbons and increases the yield of alcohols by forming esters that prevent further oxidation of hydroxyl groups to ketones and carboxyHc acids (see Hydrocarbon oxidation). 

The bactetiostatic and fungicidal properties of bode acid have led to its use as a preservative in natural products such as lumber, mbber latex emulsions, leather, and starch products. 

Inorganic boron compounds are generaHy good fire retardants (59). Bode acid, alone or in mixtures with sodium borates, is particularly effective in reducing the flammabHity of ceUulosic matetials. AppHcations include treatment of wood products, ceUulose insulation, and cotton batting used in mattresses (see Flame retardants). 

Because boron compounds are good absorbers of thermal neutrons, owing to isotope B, the nuclear industry has developed many appHcations. High putity bode acid is added to the cooling water used in high pressure water reactors (see Nuclearreactors). 

Polyborates and pH Behavior. Whereas bode acid is essentiaHy monomeric ia dilute aqueous solutions, polymeric species may form at concentrations above 0.1 M. The conjugate base of bode acid in aqueous systems is the tetrahydroxyborate [15390-83-7] anion sometimes caHed the metaborate anion, B(OH) 4. This species is also the principal anion in solutions of alkaH metal (1 1) borates such as sodium metaborate,... 

For both polar and nonpolar nonhydrocaihon gaseous mixtui es at low pressui es, the most accurate viscosity prediction method is the method of Brokaw. The method is quite accurate but requires the dipole moment and the Stockmayer energy parameter (e/A ) for polar components as well as pure component viscosities, molecular weights, the normal boding point, and the hq-uid molar volume at the normal boding point. The Technical Data Manual should be consulted for the fidl method. 

The kettle reboiler is shown in Fig. ll-3.5ishell-side, this common design provides adequate dome space for separation of vapor and hquid above the tube bundle and surge capacity beyond the weir near the shell cover. 

Boding water (ca. 150 ml) is poured over about one tablcspoonful of the tea, covered and allowed to draw for 10-15 min., and then passed through a tea strainer. 

Vibration analysis This ineludes an on-line analysis of the vibration signals, FFT speetral analysis, transient analysis, and diagnosties. A wide variety of displays are available ineluding orbits, easeades, bode and nyquist plots, and transient plots. 

Figure 11.14 Schematic diagram of the active site of subtilisin. A region (residues 42-45) of a bound polypeptide inhibitor, eglin, is shown in red. The four essential features of the active site— the catalytic triad, the oxyanion hole, the specificity pocket, and the region for nonspecific binding of substrate—are highlighted in yellow. Important hydrogen bonds between enzyme and inhibitor are striped. This figure should be compared to Figure 11.9, which shows the same features for chymotrypsin. (Adapted from W. Bode et al., EMBO /.

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