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Benzene aryl amines from

A one-pot procedure was developed for the preparation of aromatic amines from phenols via a one-pot Smiles rearrangement by N.P. Peet et al.° This new approach can be considered as an alternative of the Bucherer reaction which only works well for naphthalene derivatives and gives very poor yields for substituted benzene derivatives. In the current procedure, the phenol was reacted with 2-bromo-2-methylpropionamide to give 2-aryloxy-2-methylpropionamide which upon treatment with base underwent the Smiles rearrangement. The hydrolysis of the resulting A/-aryl-2-hydroxypropionamide afforded the aromatic amine. [Pg.417]

Aryl amine intermediates for azo and triphenylmethane dyes, as well as a number of vat dye (anthraquinone) intermediates, are made from compounds such as benzene, alkyl benzenes (toluene and higher homologues), phenol and naphthalene. A limited number of reactions are used to produce the most important dye intermediates, including nitration, reduction, halogenation, sulfonation, /V-alkylation, /V-acylation and alkali fusion33,34. [Pg.726]

According to Teppema and Sebrell [357], the preparation of benzo-thiazoline-2-thiones from aryl amines, sulfur and carbon disulfide is not generally applicable. This has been confirmed by several other authors. Another synthesis, method C, has been worked out starting with o-nitro chloro benzenes. On warming these products in a solution of sodium hydrogen sulfide with slow addition of hydrogen sulfide in the presence of carbon disulfide, near 90% yields of benzothiazoline-2-thiones are obtained. [Pg.132]

Aryl amines, such as aniline, can be prepared from benzene using the following approach ... [Pg.1102]

This chapter covers recent developments in the title area published during 2014. As last year, little work has appeared in the literature apart from the preparation of novel pentacoordinated compounds. For instance, a chemoselective synthesis of 2,2,2-trichloro-4(5)-(dichloro-phosphoryloxy)-l,3,2X -benzodioxaphospholes which were obtained in a multi-step reaction starting from 1,2,3- and l,2,4-tris(trimethyl-siloxy)benzenes has been reported. Of note also are investigations describing intramolecular N-H cleavage of ammonia, allg lamines and aryl amines by tricoordinate phosphorus compounds furnishing pentacoordinated adducts. [Pg.354]

In non-polar solvents many aminolysis reactions show a third-order dependence on the amine, B. This may be explained by catalysis of leaving-group departure by hydrogen-bonded homoconjugates, BH+B. Evidence for this pathway has been adduced from studies of the reactions of some nitro-activated (9-aryl oximes (7) with pyrrolidine in benzene, chlorobenzene, and dioxane, and with piperidine and hexylamine in cyclohexane. The third-order dependence on amine of the reaction of 2,6-dinitroanisole with butylamine in toluene and toluene-octanol mixtures has been interpreted in terms of a mechanism involving attack by dimers of the nucleophile. ... [Pg.277]

There is direct evidence, from ir and nmr spectra, that the f-butyl cation is quantitatively formed when f-butyl chloride reacts with A1CI3 in anhydrous liquid HCI.246 In the case of olefins, Markovnikov s rule (p. 750) is followed. Carbocation formation is particularly easy from some reagents, because of the stability of the cations. Triphenylmethyl chloride247 and 1-chloroadamantane248 alkylate activated aromatic rings (e.g., phenols, amines) with no catalyst or solvent. Ions as stable as this are less reactive than other carbocations and often attack only active substrates. The tropylium ion, for example, alkylates anisole but not benzene.249 It was noted on p. 337 that relatively stable vinylic cations can be generated from certain vinylic compounds. These have been used to introduce vinylic groups into aryl substrates.250... [Pg.538]

The formation of a-naphthols of type 189 from 1-alkyl-substituted salts 30, on heating with dimethylamine hydrochloride in ethanol, occurs by another mechanism and will be explained in Section III,C,4,b,i. The interaction of l-aryl-3-carboxy-substituted salts 62 with secondary amines in benzene is initiated probably as in the reaction of these salts with primary amines, and the attack by the secondary amine on position 3 is the primary step of this reaction. However, since protonation of the intermediate anion 190, a masked acyl anion, becomes difficult, an interaction of this anion with the carbonyl group of the benzophenone fragment occurs (86KGS125). The enamines 191 thus formed are usually hydrolyzed on purification, yielding five-membered cyclic acyloins 192. [Pg.206]

Fig. 5. Back electron transfer rates in photogenerated radical ion pairs in acetonitrile (a) 9,10-Dicyanoanthracene in its excited state served as the acceptor. Aryl, alkyl, methoxy and amino benzene derivatives as well as aliphatic amines served as donors [62] (V = 23 cm-1, 2, = 0.97 eV, Aj = 0.64 eV). (b) Perylene, pyrene, benzperylene, and aromatic amines served as donors. Tetracyanoethylene (TCNE), pyromellitic dianhydride (PMDA), phthalic anhydride (PA), maleic anhydride, pyrene and perylene served as electron acceptors [63], Various combinations of donors or acceptors were excited (V = 20 cm , As = 1.45 eV, A, = 0.07 eV). The parabolas drawn are different from those offered in the original analysis. The parameters that were used were selected to emphasize the similarity to Fig. 4 (in all cases v = 1500 cm-1)... Fig. 5. Back electron transfer rates in photogenerated radical ion pairs in acetonitrile (a) 9,10-Dicyanoanthracene in its excited state served as the acceptor. Aryl, alkyl, methoxy and amino benzene derivatives as well as aliphatic amines served as donors [62] (V = 23 cm-1, 2, = 0.97 eV, Aj = 0.64 eV). (b) Perylene, pyrene, benzperylene, and aromatic amines served as donors. Tetracyanoethylene (TCNE), pyromellitic dianhydride (PMDA), phthalic anhydride (PA), maleic anhydride, pyrene and perylene served as electron acceptors [63], Various combinations of donors or acceptors were excited (V = 20 cm , As = 1.45 eV, A, = 0.07 eV). The parabolas drawn are different from those offered in the original analysis. The parameters that were used were selected to emphasize the similarity to Fig. 4 (in all cases v = 1500 cm-1)...
Bacchetti et have investigated the kinetics of the nucleophilic substitution of 2-aryl-5-chloro-l,3,4-thiadiazoles with piperidine in ethanol and benzene. In ethanol, the reaction was first order in both components, whereas in benzene it was pseudo-first order in thiadia-zole, but intermediate between first and second order in piperidine, indicating intervention of associated amine molecules in the substitution. The logarithms of the rate constants from ethanol gave an excellent Hammett plot against the a values for the para substituents in the phenyl ring. [Pg.198]

Organophosphorus compounds find wide use in the chemical industry as catalysts, intermediates, complexes, and end-use products. Arylphosphines and phosphine oxides are often produced by the reaction of a preformed Grignard reagent with a halophosphine or phosphine oxide. Yields are reduced by the production of unwanted side-reaction products such as biaryls. These unwanted products are reduced when the reaction is conducted under Barbier conditions. When alkyl and aryl halides are reacted with magnesium metal, a trihalophosphine or phosphine oxide, a metal halide or amine catalyst, in THE benzene mixtures, at reflux, good yields of phosphines or phosphine oxides are obtained [74]. For example, triphenylphosphine can be prepared in a 97.2% yield from the reaction of bromobenzene, trichlorophosphine, magnesium metal, aluminum chloride, and sodium chloride in THF-benzene at 70 80 C. [Pg.418]


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See also in sourсe #XX -- [ Pg.1101 ]




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Amination benzene

Amination, aryl

Amines arylation

Aryl aminations

Aryl amines

Arylation benzene

From aminals

From amines

From aryl amines

From benzene

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