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Aryl ions

Samec, Z., A. R. Brown, L. J. YeUowlees, and H. H. Girault, Photochemical transfer of tetra-aryl ions across the interface between two immiscible electrolyte solutions, J Electroanal Chem, Vol. 288, (1990) p. 245. [Pg.91]

It is a colourless gas which decomposes on heating above 420 K to give metallic tin, often deposited as a mirror, and hydrogen. It is a reducing agent and will reduce silver ions to silver and mercury(II) ions to mercury. SnSn bonding is unknown in hydrides but does exist in alkyl and aryl compounds, for example (CH3)3Sn-Sn(CH3)3. [Pg.177]

The reactant corresponding to retrosynthetic path b in Scheme 2.2 can be obtained by Meerwein arylation of vinyl acetate with o-nitrophcnyldiazonium ions[9], Retrosynthetic path c involves oxidation of a 2-(o-nitrophenyl)ethanol. This transformation has also been realized for 2-(o-aminophenyl)ethanols. For the latter reaction the best catalyst is Ru(PPhj)2Cl2. The reaction proceeds with evolution of hydrogen and has been shown to be applicable to a variety of ring-substituted 2-(o-aminophenyl)ethanols[10]. [Pg.15]

Aryl diazonium ions prepared by nitrous acid diazotization of primary arylamines are substantially more stable than alkyl diazonium ions and are of enormous synthetic value Their use m the synthesis of substituted aromatic compounds is described m the following two sections... [Pg.945]

Primary arylamines like primary alkylammes form diazonium ion salts on nitro sation Aryl diazonium 10ns are considerably more stable than their alkyl counterparts Whereas alkyl diazonium 10ns decompose under the conditions of their formation aryl diazonium salts are stable enough to be stored m aqueous solution at 0-5°C for a rea sonable time Loss of nitrogen from an aryl diazonium ion generates an unstable aryl cation and is much slower than loss of nitrogen from an alkyl diazonium ion... [Pg.945]

An important reaction of aryl diazonium ions is their conversion to phenols by hydrolysis... [Pg.946]

FIGURE 22 6 Flowchart showing the synthetic origin of aryl diazonium ions and their most useful transfer mations... [Pg.946]

Diazonium salt chemistry provides the principal synthetic method for the prepara tion of aryl fluorides through a process known as the Schiemann reaction In this pro cedure the aryl diazonium ion is isolated as its fluoroborate salt which then yields the desired aryl fluoride on being heated... [Pg.947]

A reaction of aryl diazonium salts that does not involve loss of nitrogen takes place when they react with phenols and arylamines Aryl diazonium ions are relatively weak elec trophiles but have sufficient reactivity to attack strongly activated aromatic rings The reaction is known as azo coupling two aryl groups are joined together by an azo (—N=N—) function... [Pg.950]

Synthetically Useful Transformations Involving Aryl Diazonium Ions... [Pg.960]

Synthetically Useful Transformations Involving Aryl Diazonium Ions (Continued) Reaction and comments General equation and specific example... [Pg.961]

Reaction of aryl diazonium salts with iodide ion (Section 22 17) Adding po tassium iodide to a solution of an aryl diazonium ion leads to the formation of an aryl iodide... [Pg.973]

The reaction between an alkoxide ion and an aryl halide can be used to prepare alkyl aryl ethers only when the aryl halide is one that reacts rapidly by the addition-elim mation mechanism of nucleophilic aromatic substitution (Section 23 6)... [Pg.1008]

The first step in the reaction of an alkyl aryl ether with a hydrogen halide is pro tonation of oxygen to form an alkylaryloxonium ion... [Pg.1011]

Quantum (Section 13 1) The energy associated with a photon Quaternary ammonium salt (Section 22 1) Salt of the type R4N X The positively charged ion contains a nitrogen with a total of four organic substituents (any combination of alkyl and aryl groups)... [Pg.1292]

Sandmeyer reaction (Section 22 17) Reaction of an aryl dia zonium ion with CuCl CuBr or CuCN to give respec tively an aryl chloride aryl bromide or aryl cyanide (nitrile)... [Pg.1293]

Schiemann reaction (Section 22 17) Preparation of an aryl fluonde by heating the diazonium fluoroborate formed by addition of tetrafluorobonc acid (HBF4) to a diazonium ion Schiffs base (Section 17 10) Another name for an imine a compound of the type R2C=NR ... [Pg.1293]

In cationic polymerization the active species is the ion which is formed by the addition of a proton from the initiator system to a monomer. For vinyl monomers the type of substituents which promote this type of polymerization are those which are electron supplying, like alkyl, 1,1-dialkyl, aryl, and alkoxy. Isobutylene and a-methyl styrene are examples of monomers which have been polymerized via cationic intermediates. [Pg.411]

Substitution Reactions on Side Chains. Because the benzyl carbon is the most reactive site on the propanoid side chain, many substitution reactions occur at this position. Typically, substitution reactions occur by attack of a nucleophilic reagent on a benzyl carbon present in the form of a carbonium ion or a methine group in a quinonemethide stmeture. In a reversal of the ether cleavage reactions described, benzyl alcohols and ethers may be transformed to alkyl or aryl ethers by acid-catalyzed etherifications or transetherifications with alcohol or phenol. The conversion of a benzyl alcohol or ether to a sulfonic acid group is among the most important side chain modification reactions because it is essential to the solubilization of lignin in the sulfite pulping process (17). [Pg.139]

After inorganic mercuric salts are absorbed and dissociated into the body fluids and in the blood, they are distributed between the plasma and erythrocytes. Aryl mercuric compounds and alkoxy mercuric compounds are decomposed to mercuric ions, which behave similarly. [Pg.116]

In the presence of sulfide or sulfhydryl anions, the quinonemethide is attacked and a benzyl thiol formed. The P-aryl ether linkage to the next phenylpropane unit is broken down as a result of neighboring-group attack by the sulfur, eliminating the aryloxy group which becomes reactive phenolate ion (eq. 2). If sulfide is not present, a principal reaction is the formation of the stable aryl enol ether, ArCH=CHOAr. A smaller amount of this product also forms in the presence of sulfhydryl anion. [Pg.261]


See other pages where Aryl ions is mentioned: [Pg.404]    [Pg.249]    [Pg.135]    [Pg.135]    [Pg.23]    [Pg.249]    [Pg.27]    [Pg.23]    [Pg.119]    [Pg.404]    [Pg.249]    [Pg.135]    [Pg.135]    [Pg.23]    [Pg.249]    [Pg.27]    [Pg.23]    [Pg.119]    [Pg.181]    [Pg.199]    [Pg.413]    [Pg.89]    [Pg.5]    [Pg.139]    [Pg.130]    [Pg.809]    [Pg.867]    [Pg.946]    [Pg.946]    [Pg.948]    [Pg.1016]    [Pg.139]    [Pg.103]    [Pg.230]    [Pg.47]    [Pg.39]    [Pg.267]   
See also in sourсe #XX -- [ Pg.583 ]




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Alkenes arylation by diazonium ions

Aryl diazonium ions

Aryl halides with halide ions

Carboxylate ions, aryl

Carboxylate ions, aryl reactions

Carboxylate ions, aryl rearrangements

Copper salts reactions with aryl diazonium ions

Diazonium ions conversion to aryl azides

Diazonium ions conversion to aryl halides

Halides preparation from aryl diazonium ions

Halides, aryl reaction with halide ions

Phenols reaction with aryl diazonium ions

Reduction of aryl diazonium ions

Silylium ions aryl-substituted

Sodium borohydride aryl diazonium ions

Sodium borohydride of aryl diazonium ions

Tertiary Alkyl(Aryl)Sulfonium Ions

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