Ammonium chloride phosphate

Plasticity, and hence granulation efficiency, varies considerably with the nature and proportion of feed materials. Pure salts, such as potassium chloride and ammonium sulfate, lend Httle or no plasticity and thus are difficult to granulate. Superphosphates provide good plasticity. The plasticity of ammonium phosphates depends chiefly on the impurity content of iron and aluminum. The higher the impurity the greater the plasticity. In some cases, binders such as clay are added to provide plasticity. 

Copper. Some 15 copper compounds (qv) have been used as micronutrient fertilizers. These include copper sulfates, oxides, chlorides, and cupric ammonium phosphate [15928-74-2] and several copper complexes and chelates. Recommended rates of Cu appHcation range from a low of 0.2 to as much as 14 kg/hm. Both soil and foHar appHcations are used. 

Urea—Phosphate Type. Phosphoric acid imparts flame resistance to ceUulose (16,17), but acid degradation accompanies this process. This degradation can be minimized by iacorporation of urea [57-13-6]. Ph osph oryl a ting agents for ceUulose iaclude ammonium phosphate [7783-28-0] urea—phosphoric acid, phosphoms trichloride [7719-12-2] and oxychloride [10025-87-3] monophenyl phosphate [701-64-4] phosphoms pentoxide [1314-56-3] and the chlorides of partiaUy esterified phosphoric acids (see Cellulose esters, inorganic). 

Portable fire extinguishers are classified according to appHcabiHty Class A for soHd combustibles Class B for flammable Hquids Class C for electrical fires that require a nonconducting agent and Class D for combustible metals. Water frequently is used for Class A extinguishers bicarbonates for Class B and Class BC carbon dioxide or Freon for Class C ammonium phosphate for Class ABC and powdered salt, sodium chloride, for Class D. 

Granulation processes offer a number of important advantages. The most significant are decreased pollution problems and the abiUty to produce granules of almost any reasonable size allowing close size matching with granular ammonium phosphates and potassium chloride in the preparation of NPK fertilizers (26). 

A number of products are being marketed under the trade name POLYON. These include coated basic fertilizer materials, ie, urea, potassium nitrate, potassium sulfate, potassium chloride, ammonium sulfate, ammonium phosphate, and iron sulfate, in various particle sizes. Coatings weights on urea vary from 1.5 to 15%, depending on the release duration desired. Table 6 Hsts typical products. 

AMMO 2.5 EC , cypermetlu-in, 13 Ammonia, 13 Ammonium acetate, 13 Ammonium arsenate, 13 Ammonium benzoate, 13 Ammonium bicarbonate, 13 Ammonium bifluoride, 14 Ammonium bisulfite, 14 Ammonium carbamate, 14 Ammonium carbonate, 14 Ammonium chloride, 14 Ammonium chlorplatmate, 14 Ammonium clu omate, 14 Ammonium citrate, 14 Ammonium diclu omate, 14 Ammonium fluoride, 14 Ammonium fomiate, 15 Ammonium hexafluorosilicate, 15 Ammonium hydroxide, 15 Ammonium metavanadate, 15 Ammonium molybdate, 15 Ammonium nitrate, 15 Ammonium oxalate, 15 Ammonium perfluorooctanoate, 15 Ammonium persulfate, 15 Ammonium phosphate, 15 Ammonium picrate, 16 Ammonium salicylate, 16... 

Ans. (a) Ammonium chloride, (b) ammonium sulfide, and (c) ammonium phosphate. Note that the last two formulas require parentheses around the ammonium ion, but that the first one does not since there is only one ammonium ion per formula unit. 

A basic scientific investigation of fire retardancy, however, remained to be initiated by Gay-Lussac in France at the request of King Louis XVIII in 1821 who was again interested in reducing the flammability of theater curtains. This researcher noted that the ammonium salts of sulfuric, hydrochloric and phosphoric acids were very effective fire retardants on hemp and linen and that the effect could be improved considerably by using mixtures of ammonium chloride, ammonium phosphate and borax. This work has withstood the test of time and remains valid to this day. Thus the basic elements of modern fire retardant chemistry had been defined early in recorded history and remained the state of the art until early in the twentieth century. The most effective treatments for cellulosic materials being concentrated in Groups III, V and VII elements. 

Certain antiseptic and therapeutic agents (such as sodium fluoride, stannous fluoride, strontium chloride, urea, dibasic ammonium phosphate, are used in dentrifrices for their anticarcinogenic, bacteriostatic and bactericidal actions. 

Ammonium Oxalate Ammonium Oxalate Hydrate Ammonium Pentaborate Ammonium Pentaborate Tetrahydrate Ammonium Pentachlorozincate Ammonium Perchlorate Ammonium Peroxydisulfate Ammonium Persulfate Ammonium Phosphate Ammonium Phosphate, Dibasic Ammonium Rhodanate Ammonium Rhodanide Ammonium Silicofluoride Ammonium Stearate Ammonium Sulfamate Ammonium Sulfate Ammonium Sulfhydrate Solution Ammonium Sulfide Ammonium Sulfide Solution Ammonium Sulfite Ammonium Sulfocyanate Ammonium Sulfocyanide Ammonium Tartrate Ammonium Thiocyanate Ammonium Thiosulfate Ammonium Zinc Chloride Amorphous Phosphorus AMS... 

Oils Edible Safflower Potassium Binoxalate Ammonium Chloride Salicylic Acid Ammonium Chloride Lead Acetate Potassium Binoxalate Sodium Silicofluoride Ammonium Carbonate Fluocilicic Acid P-Dichlorobenzene Ammonium Phosphate Sec-Butyl Acetate Sec-Butyl Alcohol Calcium Phosphate Selenium Trioxide Selenium Dioxide Selenium Dioxide Selenium Dioxide Selenium Trioxide Antimony Trioxide Calcium Hypochlorite Carbaryl Cyclohexanone Charcoal... 

In order to fix the iron and prevent its volatilization as chloride, F. C. Calvert recommended mixing the product before sublimation with acid calcium phosphate or ammonium phosphate, and M. Adler recommended superphosphate. Kecrystal-lization after treatment of the soln. with animal charcoal has also been recommended. The iron is also said to be removed by treating the soln. with a little chlorine (not an excess), then with ammonia, and finally crystallizing the filtered soln. In his work on at. wt., J. S. Stas purified ammonium chloride as followrs ... 

Arsenic. — On shaking 1 gm. of powdered ammonium phosphate with 3 cc. of stannous chloride solution, the mixture should not darken within one hour. 

Carbonates and Sulphates. — On adding hydrochloric acid to a solution of 1 gm. of ammonium phosphate in 20 cc. of water, no effervescence should take place and on adding barium chloride solution, no precipitate of barium sulphate should form on standing twelve hours. 

Magnesium. I lisNolve 3 gm. of sodium chloride in 10 cc. uf wiilcr. nod add ft cc. of ammonia water and ammonium phosphate solution. No precipitate should form within three hours. 

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