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Aluminum-sodium combination

Temperature. The temperature of the reaction is important, for it is only above 180°C. that all catalysts and catalyst combinations are fully effective. W ith a reaction temperature of 160°C. and the use of an aluminum-sodium combination, for instance, the esterification, as compared to that of the purely thermal procedure, is 4.5 times faster it is 20 times faster at 200°C. In order fully to use the catalytic effectiveness of aluminum hydroxide in case of alcohols with a boiling point below 180°C., it is necessary to work with the appropriate high pressure. [Pg.88]

Sodium combines with hydrogen forming sodium hydride, NaH. The reaction is slow at ambient temperature but proceeds rapidly above 200°C when the metal is dispersed or spread over the surface of an inert solid (such as a hydrocarbon). Sodium and hydrogen react with aluminum powder to form sodium aluminum hydrides. Two such complex hydrides, the tetrahydride, NaAlH4, and the hexahydride, NasAlHe, are produced. The nature of the prod-... [Pg.848]

Both 1- and 2-fluoronaphthalenes are reduced to naphthalene by a mixture of hydrazine and its sodium salt, in 39 and 60% yield, respectively.63 As in the case of other monofluoroarenes, more efficient reduction is achieved by lithium aluminum hydride combined with cerium(III) chloride in refluxing tetrahydrofuran.1011 1,2,3,4-Tetrafluoronaphthalene (6) is monoreduced by lithium aluminum hydride at C2 with complete regioselcctivity to give trifluoronaphthalene... [Pg.316]

X-ray fluorescence spectrometry This technique is extensively used in the industrial analysis of plastics for routine determination of traces of metals and nonmetal elements, i.e., iron, cobalt, nickel, chromium, copper, zinc, chlorine, bromine, titanium, aluminum, sodium, potassium, calcium, magnesium, vanadium, cadmium, and selenium. The main advantages are simple sample preparation and independence on the element state in chemical combination. [Pg.3727]

Ultramarine blue pigment n. A pigment family comprising a complex of double silicates of sodium and aluminum in combination with sodium polysulfide. They produce bright, clean tones even in combination with white pigments, and are resistant to the high-temperatures employed in... [Pg.1020]

Other methods iaclude hydrogen reduction of TiCl to TiCl and TiCl2 reduction above the melting poiat of titanium metal with sodium, which presents a container problem plasma reduction, ia which titanium is collected as a powder, and ionized and vaporized titanium combine with chlorine gas to reform TiCl2 on cool-down and aluminum reduction, which reduces TiCl to lower chlorides (19,20). [Pg.100]

Sodium Aluminum Sulfate (SAS). Sodium aluminum sulfate is a dehydrated double salt of aluminum and sodium sulfate. It does not react with baking soda in cold, but in the heat of oven 1 mol of SAS produces 6 mol of carbon dioxide from reacting with baking soda. Historically, SAS was one of the first materials used to Hberate carbon dioxide from baking soda. Today its primary use is in household baking powder production. It is used either alone or in combination with MCP. SAS is not recommended for use in prepared mixes due to its lack of compatibiHty with other ingredients in a mix. [Pg.469]

Gl ss-Ionomers. Glass-ionomers show fluoride release at levels that are usually higher than those found in composite materials. The fluoride is found within the aluminosihcate glass, which is melted with fluoride fluxes and ground to form powder filler. The fluoride is added as calcium fluoride [7789-75-5] aluminum fluoride [15098-87-0] and sodium fluoride [7681-49-4] in a combined proportion of approximately 20% by weight in the final powder (284,285). [Pg.494]

Sodium aluminum. sulfate. This product is now being successfully calcined in rotary Idlns. In this process, the salt cake is broken up just before it enters the Idln. Calcination is for the purpose of driving off the combined water (45 percent) and sulfuric acid (3 percent). Temperatures employed are approximately 800 K. [Pg.1207]

A solution of 10 g of this compound in 80 ml of tetrahydrofuran is added, with cooling, during 5 min, to a solution of 4.8 g of lithium aluminum hydride in 60 ml of tetrahydrofuran, and the mixture refluxed for 2.25 hr then cooled in an ice bath and treated with 60 ml of acetone, followed by 200 ml of ether and 72 ml of 2 A sodium hydroxide. The mixture is filtered, the cake washed with 50 ml of acetone, and the combined filtrate washed with water, dried over sodium sulfate and evaporated under reduced pressure. The residue is crystallized from acetone to give 6.05 g (68 %) of the enamine. [Pg.195]

Woodward s strychnine synthesis commences with a Fischer indole synthesis using phenylhydrazine (24) and acetoveratrone (25) as starting materials (see Scheme 2). In the presence of polyphosphor-ic acid, intermediates 24 and 25 combine to afford 2-veratrylindole (23) through the reaction processes illustrated in Scheme 2. With its a position suitably masked, 2-veratrylindole (23) reacts smoothly at the ft position with the Schiff base derived from the action of dimethylamine on formaldehyde to give intermediate 22 in 92% yield. TV-Methylation of the dimethylamino substituent in 22 with methyl iodide, followed by exposure of the resultant quaternary ammonium iodide to sodium cyanide in DMF, provides nitrile 26 in an overall yield of 97%. Condensation of 2-veratryl-tryptamine (20), the product of a lithium aluminum hydride reduction of nitrile 26, with ethyl glyoxylate (21) furnishes Schiff base 19 in a yield of 92%. [Pg.27]

Some metals that are chemically combined with oxygen (metal oxides) also dissolve in sodium hydroxide. For example, aluminum ore (known as bauxite) is treated with sodium hydroxide to isolate pure aluminum oxide, from which pure aluminum is obtained. Sand (silicon dioxide) will also dissolve in sodium hydroxide to form a chemical known as sodium silicate or water glass. [Pg.29]

The first production of aluminum was by the chemical reduction of aluminum chloride with sodium. The electrolytic process, based on the fused salt electrolysis of alumina dissolved in cryolite, was independently developed in 1886 by C. M. Hall in America and P. L. Heroult in France. Soon afterwards a chemical process for producing pure alumina from bauxite, the commercial source of aluminum, was developed by Bayer and this led to the commercial production of aluminum by a combination of the Bayer and the Hall-Heroult processes. At present this is the main method which supplies all the world s needs in primary aluminum. However, a few other processes also have been developed for the production of the metal. On account of problems still waiting to be solved none of these alternative methods has seen commercial exploitation. [Pg.709]

A separate continuous DAF operation conducted by Krofta and Wang59 under 33.3% recycle flow pressurization mode demonstrated that aluminum sulfate, sodium aluminate, and polyelectrolyte combination at pH 6.2 also effectively recovered both fibers and titanium dioxide from the same white water containing 500mg/L of titanium dioxide and 1000 mg/L of cotton fibers. [Pg.906]

Titanium (IV) iodide may be prepared by a variety of methods. High-temperature methods include reaction of titanium metal with iodine vapor,1-3 titanium carbide with iodine,4 titanium(IV) oxide with aluminum (III) iodide,5 and titanium (IV) chloride with a mixture of hydrogen and iodine. At lower temperatures, titanium (IV) iodide has been obtained by the combination of titanium and iodine in refluxing carbon tetrachloride7 and in hot benzene or carbon disulfide 8 a titanium-aluminum alloy may be used in place of titanium metal.9 It has been reported that iodine combines directly with titanium at room temperature if the metal is prepared by sodium reduction of titanium (IV) chloride and is heated to a high temperature before iodine is... [Pg.11]

Some of the investigations carried out in the first half of the twentieth century were related to CL associated with thermal decomposition of aromatic cyclic peroxides [75, 76] and the extremely low-level ultraviolet emission produced in different reaction systems such as neutralization and redox reactions involving oxidants (permanganate, halogens, and chromic acid in combination with oxalates, glucose, or bisulfite) [77], In this period some papers appeared in which the bright luminescence emitted when alkali metals were exposed to oxygen was reported. The phenomenon was described for derivatives of zinc [78], boron [79], and sodium, potassium, and aluminum [80]. [Pg.16]

The organic layer is separated and discarded. The acid solution is extracted with three 500-ml. portions of ether (Note 4), which are discarded then it is treated with 50% aqueous sodium hydroxide until the aluminum hydroxide which first forms redissolves (Note 5). After cooling, the organic material is extracted with five 300-ml. portions of chloroform. The combined chloroform extracts are washed with water, the solvent is removed by distillation on the steam bath, and the product is distilled. The yield of 3-benzoylpyridine (Note 6), b.p. 107-110°/0.3 mm. or 141-145°/4 mm., is 165-175 g. (90-96%), 1.6088. [Pg.62]


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