Aluminizing treatment

Proper surface modification can significantly enhance the resistance to high temperature oxidation. For example, aluminizing treatment can effectively decrease the high temperature sulfidation and oxidation rates. 

Sodium aluminate is used in water purification, in the paper industry, for the after treatment of Ti02 pigment, and in the manufacture of aluminum containing catalysts and zeoHte. Worldwide markets are in the range of 125,000 t/yr (19). 

Aluminum based chemicals have been used for many years in wastewater treatment applications for suspended solids removal. These include dry and liquid alum, with sodium aluminate used in activated sludge plants for phosphorus removal. 

Ionic liquids formed by treatment of a halide salt with a Lewis acid (such as chloro-aluminate or chlorostannate melts) generally act both as solvent and as co-catalyst in transition metal catalysis. The reason for this is that the Lewis acidity or basicity, which is always present (at least latently), results in strong interactions with the catalyst complex. In many cases, the Lewis acidity of an ionic liquid is used to convert the neutral catalyst precursor into the corresponding cationic active form. The activation of Cp2TiCl2 [26] and (ligand)2NiCl2 [27] in acidic chloroaluminate melts and the activation of (PR3)2PtCl2 in chlorostannate melts [28] are examples of this land of activation (Eqs. 5.2-1, 5.2-2, and 5.2-3). 

Jones, R. D. and Jones, D. P., Hot-dip Aluminized Steel Strip for Corrosion Resistant Applications , in Surface Treatment for Corrosion and Wear Resistance, Strafford, Datta and Googen (eds), Ellis Horwood, Chichester (1984)... 

A large number of electrolytic treatments of magnesium, anodic or a.c., have been developed, in which adherent white or grey films consisting of fluoride, oxide, hydroxide, aluminate or basic carbonate are deposited from alkaline solutions containing caustic alkali, alkali carbonates, phosphates, pyrophosphates, cyanides, aluminates, oxalates, silicates, borates, etc. Some films are thin, and some are relatively thick. All are more or less absorbent and act as good bases for paint, though none contributes appreciable inhibition. All can, however, absorb chromates with consequent improvement of protective efficiency. 

The Influence of Thermal Treatment on the Activity of Aluminized Dusts , Advisory Council Scientific Research Technical Develt Sub-Committee HE.II., AC 7555/HE.II.284 (Dec 1944) 38) P.A. Briscoe C.F.N. Tipper,... 

High-alumina cement is a rapid-hardening cement made from bauxite and limestone. It is comparatively resistant to chemical attack. Milling retards the setting of aluminous cement [1582]. On the other hand, setting accelerators such as lithium carbonate increase their effect by this treatment. 

Cationic polyacrylamide may be used in the initial treatment stages to promote rapid polymer adsorption (201). Adjustment of the pH may allow deeper penetration of the fluids in an aluminate crosslinking system prior to gelation (202). A process involving injection of alternate slugs of stoichiometrically equivalent amounts of partially hydrolyzed polyacrylamide and Al O ) has been evaluated in the laboratory permeability of sana packs were reduced by more than 96% (203). Mixtures of Al(IIl) and Zr(IV) have also been evaluated as partially hydrolyzed polyacrylamide crosslinkers (204). 

A preformed chitosan-silica composite with 60% weight inorganic part [7] is used as the source of silica for the zeolite synthesis. An alkaline solution of sodium aluminate (Na 2.1 M, Al 1 M) was used in three methods of preparation (A) beads of the chitosan-silica composite were stirred overnight in the aluminate solution, extracted and submitted to a hydrothermal treatment at 80 °C during 48h (B) beads of the chitosan-silica composite were immersed in the aluminate solution and the system underwent a hydrothermal treatment at 80 °C for 48h (C) beads of the chitosan-silica composite were stirred overnight in the aluminate solution, extracted, dried at 80 °C and exposed to water vapour at 80°C during 48h. 

In the X-ray powder diffraction patterns of the composites, the disappearance of the broad band centered at 22 °20, typical of amorphous silica, indicates that the zeolitisation of the mineral fraction of the parent composite was complete. In no diffraction pattern any sign of crystallised chitosan could be found. The two methods in which the silica-polymer beads were extracted from the aluminate solution after impregnation (methods A and C) allowed the formation of the expected zeolite X, with traces of gismondine in the case of the method C. The method B, in which excess aluminate solution was present during the hydrothermal treatment, resulted in the formation of zeolite A. 

Sodium aluminate, 2 345t, 358-359 analysis, 2 275-276 economic aspects, 2 275 health and safety factors, 2 276 manufacture, 2 274-275 neutralization, 2 424 physical and chemical properties of, 2 273-274 uses of, 2 276-277 in water treatment, 26 111 Sodium aluminosilicate gels, synthetic zeolites prepared from, 16 831t Sodium aluminosilicates, 12 578 Sodium aluminum hydride, 13 621, 623-624... 

If a base (e.g. NaOH) is used in the chemical treatment, soluble aluminates are the reaction products. When salts like KF or NaCl are used, the dealuminatin is essentially an ion exchange process, in which K and Na ions are substituted for cationic aluminum species. 

Treatment of lead(n) chloride with aluminum trichloride and o-xylene furnishes bis(o-xylene)lead(ll) bis(tetrachloro-aluminate) 41. According to the results of an X-ray structure determination, 41 consists of a monomeric complex with two arene ligands in a distorted 77-mode of coordination and two bidentate AICI4- ions at the central Pbz+ ion. The interaction of the lead center with the tetrachloroaluminate ligands is presumably highly ionic, suggesting that 41 is a triad of arene-stabilized ions, rather than a molecule.7... 

Subsequent treatment with alkali provides a free base solution in excess amine, which can be separated from the aqueous/alkaline aluminate layer. The thus prepared product is precipitated with acid, possibly converted into the free base with aqueous alkaline solution, and isolated. The dried base or its salt is then sulfonated with concentrated sulfuric acid to form the monosulfonic acid 121. 

Wang, L.K. Wu, B.C. Treatment of groundwater by dissolved air flotation systems using sodium aluminate and lime as flotation aids. OCEESA J. 1984, 1 (5), 5-18 NTIS Report No. PB85-167229/AS. 

Layer, W. Wang, L.K. Water Purification and Wastewater Treatment with Sodium Aluminate, Report PB 85-214-492/AS U.S. Department of Commerce, National Technical Information Service Springfield, VA, 1984. 

The atom-planting method for the preparation of several metallosilicates with MFI structure was studied. By the treatment of silicalite or ZSM-5 type zeolite with metal chloride vapor at elevated temperatures, metal atom could be introduced into the zeolite framework. From the results of alumination of silicalite it is estimated that the metal atoms are inserted into defect sites, such as hydroxyl nests in zeolite framework. The metallosilicate prepared had both Bronsted and Lewis acid sites with specific acid strength corresponding to the kind of metal element. 

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